A5100417217- Advanced Photocatalysis Techniques
- Catalytic Processes in Materials Science
- Copper-based nanomaterials and applications
- Electrocatalysts for Energy Conversion
- Advanced biosensing and bioanalysis techniques
- Crystallization and Solubility Studies
- Ammonia Synthesis and Nitrogen Reduction
- X-ray Diffraction in Crystallography
- Electrochemical sensors and biosensors
- Nanomaterials for catalytic reactions
- Metal-Organic Frameworks: Synthesis and Applications
- CO2 Reduction Techniques and Catalysts
- Covalent Organic Framework Applications
- Advanced Nanomaterials in Catalysis
- Hydrogen Storage and Materials
- Electrochemical Analysis and Applications
- Mesoporous Materials and Catalysis
- Gas Sensing Nanomaterials and Sensors
- Perovskite Materials and Applications
- MXene and MAX Phase Materials
- Advanced Combustion Engine Technologies
- Combustion and flame dynamics
- Supercapacitor Materials and Fabrication
- Hydrocarbon exploration and reservoir analysis
- Quantum Dots Synthesis And Properties
Beijing Jiaotong University
2015-2025
Chongqing Medical University
2005-2025
Anhui University
2021-2024
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation
2017-2024
Fotile (China)
2022-2023
Beijing Technology and Business University
2023
Xi'an University of Architecture and Technology
2023
Tianjin University
2017-2022
Chengdu University of Technology
2017-2022
State Council of the People's Republic of China
2018-2021
Reinforcing the carrier separation is key issue to maximize photocatalytic hydrogen evolution (PHE) efficiency of graphitic carbon nitride (g-C3 N4 ). By a surface engineering gradual doping graphited rings within g-C3 , suitable energy band structures and built-in electric fields are established. Photoinduced electrons holes impelled into diverse directions, leading 21-fold improvement in PHE rate.
Under visible light irradiation, excited electrons in heterojunction structure of Bi/BiOCl were transferred into oxygen vacancies states, and then to the Bi metal nanoparticles, resulting effective separation electron–hole pairs. The photocatalyst exhibited an extraordinary high activity photodegradation RhB dye persistent organic pollutants, i.e. was completely degraded 2 minutes.
Photocatalysis, which converts natural solar energy into chemical energy, has emerged as one of the most appealing technologies in past decades. However, photocatalytic performances are limited by poor absorption visible light, charge‐carrier recombination during migration, and a high barrier for activating reactants. Oxygen vacancies semiconductive metal oxides reported to be vital improve their efficiency. In this regard, review provides concise overview oxygen transition systems,...
Covalent organic frameworks (COFs) with porphyrins as structural units are a new kind of porous polymers, which have regular and ordered structure, abundant porosity, good stability. In the past, construction porphyrin COFs was generally synthesized by routes such Schiff base reaction. Here, we report COF structure linking triazine ring. Using cyano group-terminated unit precursor, triazine-porphyrin hyperconjugated (TA-Por-sp2-COF) constructed through group's self-polymerization. The...
Inter-site interaction in densely populated single-atom catalysts has been demonstrated to have a crucial role regulating the electronic structure of metal atoms, and consequently their catalytic performances. We herein report general facile strategy for synthesis several catalysts. Taking cobalt as an example, we further produce series Co with varying loadings investigate influence density on performance alkene epoxidation O2. Interestingly, turnover frequency mass-specific activity are...
Rational regulation of active hydrogen (*H) behavior is crucial for advancing electrocatalytic nitrate reduction reaction (NO3RR) to ammonia (NH3), yet in‐depth understanding the *H generation, transfer, and utilization remains ambiguous, explorations dynamic optimization are urgently needed. Herein we engineer a Ni3N nanosheet array intimately decorated with Cu nanoclusters (NF/Ni3N‐Cu) remarkably boosted NO3RR. From comprehensive experimental theoretical investigations, moieties favors...
The bifunctional mechanism, involving multiactive compositions to simultaneously dissociate water molecules and optimize intermediate adsorption, has been widely used in the design of catalysts boost electrolysis for sustainable hydrogen energy production but remains debatable due difficulties accurately identifying reaction process. Here, we proposed concept well-defined Lewis pairs single-atom catalysts, with a unique acid-base nature, comprehensively understand exact role an alkaline...
Photocorrosion is a key factor that greatly hinders the stability of photoanodes. Depositing appropriate cocatalysts can effectively protect semiconductors from photocorrosion as well improve photoelectrochemical (PEC) activity. However, formation occurs mostly under island growth, making partially unprotected, thus leading to poor stability. Herein, we demonstrate complex assembly film composed phenolic ligands (tannic acid) coordinated with Ni and Fe ions (TANF) robust cocatalyst for...
A novel Ni<sub>3</sub>N/graphene nanocomposite has been synthesized as pseudo supercapacitor electrode material with high capacitance and energy density, due to its unique two-step oxidation/reduction reaction mechanism.
Solar-to-chemical energy conversion by photocatalytic hydrogen evolution (PHE) is critical for reduction of the pollution and storage clean energy. To improve solar efficiency, it highly imperative to accelerate photocarrier separation transportation through materials design. Herein, we describe a effective PHE catalyst based on in-plane benzene-ring doped g-C3N4 nanosheets heterostructure thermal co-polymerization urea 4, 4'-sulfonyldiphenol (BPS) followed controlled heat-etching step. The...
With greatly enhanced surface-to-volume ratios, one-dimensional (1D) carbon nanostructures are believed to be able deliver superior performance as room temperature sensors for explosive gases. 1D nanofibers composed of graphitic nanorolls were prepared using a simple electrospinning-assisted solid-phase graphitization method. This method is facile and low cost can allow high-yield production nanofibers. The unique structure the as-prepared different from that conventional nanostructures. It...
An all-carbon aromatic ring substitutionally doped g-C<sub>3</sub>N<sub>4</sub>was synthesized with greatly enhanced light absorption, band structure and carrier separation, achieving a 3 times higher hydrogen evolution rate (HER).
The implementation of low-cost transition-metal complexes in CO2 reduction reaction (CO2RR) is hampered by poor mechanistic understanding. Herein, a carbon-supported copper bis-(terpyridine) complex enabling facile kilogram-scale production the catalyst developed. We directly observe an intriguing baton-relay-like mechanism active sites transfer employing widely accessible operando Raman/Fourier-transform infrared spectroscopy analysis coupled with density functional theory computations. Our...
A core–shell structured mesoporous silica nanosphere with antagonistic acid and basic sites spatially isolated designated diffusion path was fabricated served as an efficient acid–base bifunctional catalyst for one-pot cascade reaction sequences excellent activity selectivity.
A novel electrode constructed by a uniform film of nanosized vanadium nanobelts on nickel foam has been developed, which exhibits excellent electroactivity and durability for HER, OER, overall water splitting.
The proposed electrons transfer mechanism for graphene well-wrapped UiO-66-NH<sub>2</sub> octahedrons.
Ultrathin films: A new molecular layer deposition process for the synthesis of nanoporous nitrogen-doped titanium dioxide films is developed. This based on a four-step ABCB reaction sequence using TiCl4, ethanolamine, and malonyl chloride as precursors (see picture). The obtained N-doped TiO2 exhibits excellent photocatalytic activity upon irradiation with visible light. As service to our authors readers, this journal provides supporting information supplied by authors. Such materials are...
A sandwich-structured CeO<sub>2</sub>/graphene nanocomposite was synthesized with enhanced ORR electrocatalytic activity due to large amounts of Ce(<sc>iii</sc>) in the thin CeO<sub>2</sub>crystalline film.