A5055397432- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Ovarian function and disorders
- Covalent Organic Framework Applications
- Reproductive Biology and Fertility
- Enhanced Oil Recovery Techniques
- Metaheuristic Optimization Algorithms Research
- Nanocluster Synthesis and Applications
- Advanced Multi-Objective Optimization Algorithms
- Catalytic C–H Functionalization Methods
- Radical Photochemical Reactions
- Control and Dynamics of Mobile Robots
- Lanthanide and Transition Metal Complexes
- Sulfur-Based Synthesis Techniques
- Perovskite Materials and Applications
- Hydrocarbon exploration and reservoir analysis
- Radioactive element chemistry and processing
- Advancements in Battery Materials
- Robotic Path Planning Algorithms
- Quantum Dots Synthesis And Properties
- Assisted Reproductive Technology and Twin Pregnancy
- Estrogen and related hormone effects
Central China Normal University
2023-2025
Peking University
2011-2025
Peking University Third Hospital
2011-2025
Wuhan Institute of Technology
2025
Ministry of Education of the People's Republic of China
2024-2025
Ministry of Education
2025
Shenyang University
2022-2024
Nanchang University
2022-2023
Shandong University of Science and Technology
2023
Collaborative Innovation Center of Chemistry for Energy Materials
2015-2020
Metal–organic frameworks (MOFs) with open metal sites enrich the population of O2 in pores significantly and assist Li–O2 reaction when employed as a cell electrode material. A primary capacity 9420 mA h g−1 is achieved Mn-MOF-74; more than four times higher value obtained without an MOF.
Inorganic functionalization of metal-organic frameworks (MOFs), such as incorporation multiple inorganic building blocks with distinct metals into one structure and further modulation the metal charges, endows porous materials significant properties toward their applications in catalysis. In this work, by an exploration role 4-pyrazolecarboxylic acid (H2PyC) formation trinuclear copper pyrazolate a metalloligand situ, four new MOFs components order were constructed through one-pot synthesis....
Exploring strategies to control the crystallization and modulate interfacial properties for high-quality perovskite film on industry-relevant textured crystalline silicon solar cells is highly valued in perovskite/silicon tandem photovoltaics community. The formation of a 2D/3D heterojunction widely employed passivate defects suppress ion migration surface cells. However, realizing solution-processed heterostructures at buried interface faces solvent incompatibilities with challenge...
Polycystic ovary syndrome (PCOS) is a heterogeneous endocrine disorder accompanied with an increased risk of developing type 2 diabetes mellitus and cardiovascular disease; despite being common condition, the pathogenesis PCOS remains unclear. Our aim was to investigate potential metabolic profiles for different phenotypes PCOS, as well early prognosis complications.A total 217 women 48 healthy normal controls were studied. Plasma samples subjects tested using two analytical platforms...
Vacancies are common in solid materials, but it remains a challenge to introduce them at specific locations with controlled distributions. Here we report the creation of ordered metal vacancies and linker cubic metal–organic framework (MOF) based on Zn(II) pyrazolecarboxylic acid by removing quarter ions half linkers. The MOF shows increased pore size, thus allowing large dye molecules fit pores. Furthermore, filling new metals linkers, eight single-crystalline MOFs multicomponents absolute...
Materials built from multiple constituents have revealed emerging properties that are beyond linear integration of those single components. We report a mesoporous metal-organic framework made three geometrically distinct metal-containing secondary building units (SBUs) as result topological induction. The combinations the Cu-based triangular, Zn-based octahedral, and square pyramidal SBUs created four types cages in network, despite only one organic linker pyrazolecarboxylate was used....
Incorporating supramolecular recognition units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance.
Abstract Positioning a diverse set of building blocks in well‐defined array enables cooperativity amongst them and the systematic programming functional properties. The extension this concept to porous metal–organic frameworks (MOFs) is challenging since installation multiple components well‐ordered framework requires careful design lattice topology, judicious selection blocks, precise control crystallization parameters. Herein, we report how met these challenges prepare first quinary MOF...
The grey wolf optimizer is an effective and well-known meta-heuristic algorithm, but it also has the weaknesses of insufficient population diversity, falling into local optimal solutions easily, unsatisfactory convergence speed. Therefore, we propose a hybrid (HGWO), based mainly on exploitation phase harris hawk optimization. It includes initialization with Latin hypercube sampling, nonlinear factor perturbations, some extended exploration strategies. In HGWO, wolves can have hawks-like...
Allylic amines are prevalent and vital structural components present in many bioactive compounds natural products. Additionally, they serve as valuable intermediates building blocks, with wide-ranging applications organic synthesis. However, direct α-C(sp
Research questionDo endometrial preparation protocols affect pregnancy outcomes in overweight/obese women with a normal ovulatory cycle undergoing their first frozen-thawed embryo transfer (FET)?DesignThis retrospective cohort study analyzed 3713 who underwent FET between January 2018 and October 2023. Patients were divided into two groups based on the protocol: natural (NC) artificial (AC). Propensity score matching (PSM) was employed to match baseline characteristics at 1:1...
Pillared-layer metal–organic frameworks (MOFs) are often encountered to "collapse" upon external stimuli due weak interactions between the layers and pillars. However, detailed local structural change, especially accumulation of defects intricately disordered bond dissociations, is not clear complicated dynamic nature collapse. We report a luminescent pillared-layer MOF structure, FDM-22, using zinc dicarboxylates as dipyridyl ligands pillars, in which three different transformed structures...
MicroRNAs (miRNAs) are small non‐coding RNA that target protein‐coding mRNAs at the post‐transcriptional level. The aim of this study was to define role miR‐492 in cervical squamous cell carcinomas. After microRNA profiling and comparison, we firstly detected expression 104 tumor tissues biopsies derived from advanced staged (FIGO IIB‐IIIB) carcinoma patients before receiving concomitant chemoradiotherapy found significantly higher specimens were sensitive chemoradiotherapy, as compared with...
Two types of rod-shaped building units are arranged periodically with adenine unprecedentedly to generate a metal–organic framework hexagonal one-dimensional channels. The new planar double-metal string blocks in this MOF were obtained by controlling the coordination variation molecules.
When the supramolecular building block packings (face-centered, body-centered, and primitive cubic) with different interactions (hydrogen coordination bonding) were controlled, four new structures based on octahedral MII (M = Zn, Ni, Mn) imidazoledicarboxylate constructed. The interaction modes between blocks affect water stability of structures. Furthermore, uncoordinated carboxylate O atoms in structures, these compounds demonstrate a strong capability capturing metal ions solution.
The supermolecular building block approach is powerful in constructing hierarchically porous metal–organic frameworks (MOFs). However, the structural diversity of these extended built from same blocks has never been explored. Herein, we propose a strategy by synergistically tuning extending direction polyhedra (MOPs) and linker conformation to achieve MOFs with framework isomerism. Six novel (CCNUF-1–6) based on an octahedral MOP different tritopic pyridine-based linkers were successfully...
In this Frontier article, we provide a brief overview of recent progress in the new organic component installation metal-organic frameworks (MOFs) by single-crystal to transformation. We discuss criteria for MOFs which could accessible vacant sites linker installation. highlight three different categories based on nature and roles linkers. The present challenges future opportunities field are also discussed.