A5101835903- Catalytic C–H Functionalization Methods
- Catalytic Cross-Coupling Reactions
- Organoboron and organosilicon chemistry
- Synthesis and Catalytic Reactions
- Fullerene Chemistry and Applications
- Oxidative Organic Chemistry Reactions
- Sulfur-Based Synthesis Techniques
- Advanced Synthetic Organic Chemistry
- Radical Photochemical Reactions
- Electrocatalysts for Energy Conversion
- Analytical Chemistry and Chromatography
- Chemical Reactions and Mechanisms
- Graphene research and applications
- Catalytic Processes in Materials Science
- Advanced Chemical Physics Studies
- Cyclopropane Reaction Mechanisms
- Magnetism in coordination complexes
- Chemical Reaction Mechanisms
- Semiconductor materials and devices
- Synthesis and Properties of Aromatic Compounds
- Metalloenzymes and iron-sulfur proteins
- Carbon Nanotubes in Composites
- Nanocluster Synthesis and Applications
- Advanced battery technologies research
- Chemical Synthesis and Reactions
Fujian Institute of Research on the Structure of Matter
2004-2024
Chinese Academy of Sciences
2015-2024
Fujian Normal University
2015-2024
University of Chinese Academy of Sciences
2024
Fuzhou University
2017-2020
Materials Science & Engineering
2019
State Council of the People's Republic of China
2017
Hubei University
2014-2016
Xi'an Shiyou University
2016
Enamine and imine represent two of the most common reaction intermediates in syntheses, containing α-hydrogen often exhibit similar reactivity to enamines due their rapid tautomerization enamine tautomers. Herein, we report that minor structural difference between tautomer derived from results different chemo- regioselectivity cyclohexanones, amines TEMPO: primary furnishes formal oxygen 1,2-migration product, α-amino-enones, while secondary under conditions generates exclusively arylamines...
The Ni-catalyzed decarbonylative borylation of (hetero)aryl carboxylic acids with B2 cat2 has been achieved without recourse to any additives. This method exhibits a broad substrate scope covering poorly reactive non-ortho-substituted acids, and tolerates diverse functional groups including some the active Ni0 catalysts. key achieve this reaction is choice as coupling partner that not only acts borylating reagent, but also chemoselectively activates aryl towards oxidative addition their...
The facile one-step reaction of [60]fullerene with isocyanates/isothiocyanates in the presence ferric perchlorate generates a series novel oxazolidinofullerenes/thiazolidinofullerenes.
Abstract The palladium‐catalyzed cross‐dehydrogenative‐coupling of polyfluoroarenes with alkenes or simple arenes has been developed. approach is characterized by using atmospheric pressure molecular oxygen as the sole oxidant, and provides a straightforward environmentally benign route to functionalized polyfluoroarenes. magnified image
We report that the direct oxidative cross-coupling of carbonyl compounds with simple alkenes is realized to synthesize α-allylated by identifying bisphosphine ligand BINAP enables copper catalyst integrate two different catalytic cycles in a one-pot system.
A convenient synthesis of α-enaminones from cyclic ketones with anilines at room temperature <italic>via</italic> an oxygen-atom-transfer pathway oxoammonium salt.
Abstract A novel strategy for the synthesis of dibenzothiophene derivatives is established through a one‐pot intramolecular cross‐dehydrogenative‐coupling reaction diaryl sulfoxides followed by deoxygenation with Rh/Ag catalytic system. The yields obtained were good to excellent (up 96 %), therefore making described protocol an attractive option building compounds.
Classical organometallic chemistry was used to prepare the dinuclear iron complex 1 with two protected cysteinyl-S ligands. Oxidative addition of thiol [Fe3(CO)12] gave 1, which undergoes an unusual intramolecular nucleophilic cyclization inversion configuration form chiral carbon-bridged diiron 2.
Developing efficient Pd-based multi-functional catalytic materials for formic acid oxidation reaction (FAO), hydrogen evolution (HER), and oxygen reduction (ORR) remains a significant challenge. Transition metal interstitial carbides (TMICs) have emerged as promising candidates electrocatalysis due to their unique structure. Cauliflower-shaped Pd/MoC||Mo2C/C nanostructured heterogeneous composites were prepared using high-temperature pyrolysis ethanol method. The resulting exhibit high...
An unprecedented one-pot C–H olefination/aza-Michael addition tandem process has been developed for the synthesis of pyrrolo[3,2,1-<italic>de</italic>]phenanthridines from 7-phenylindoles and alkenes using a [Cp*RhCl<sub>2</sub>]<sub>2</sub>/AgOAc/Me<sub>4</sub>NOAc catalytic system.
The palladium-catalyzed oxidative C–H olefination of uracils or caffeines with alkenes using an atmospheric pressure molecular oxygen as the sole oxidant has been disclosed.
Tetrahedral copper(I) clusters [Cu4(MBIZ)4(PPh3)2] (2), [Cu4(MBOZ)4(PPh3)4] (6) (MBIZ = 2-mercaptobenzimidazole, MBOZ 2-mercaptobenzoxazole) were prepared by regulation of the copper-thiolate [Cu6(MBIZ)6] (1) and [Cu8(MBOZ)8I]− (5) with PPh3. With presence iodide anion, provided iodide-containing [CuI4(MBIZ)3(PPh3)3I] (3) [CuI4(MBOZ)3(PPh3)3I] (7). The cyclic voltammogram 3 in MeCN (0.1 M nBu4NPF6, 298 K) at a scan rate 100 mV s−1 shows two oxidation processes Epa +0.11 +0.45 V return waves...
Abstract The Rh‐catalyzed ortho ‐C(sp 2 )−H functionalization of 8‐aminoquinoline‐derived benzamides with aliphatic acyl fluorides generated in situ from the corresponding acids has been developed. This reaction initiated 8‐aminoquinoline‐directed acylation, which was accompanied by subsequent intramolecular nucleophilic substitution amide group to produce alkylidene phthalides approach exhibits high stereo‐selectivity for Z ‐isomer products, and tolerates a variety functional groups as well...
Abstract The Ni‐catalyzed decarbonylative borylation of (hetero)aryl carboxylic acids with B 2 cat has been achieved without recourse to any additives. This method exhibits a broad substrate scope covering poorly reactive non‐ ortho ‐substituted acids, and tolerates diverse functional groups including some the active Ni 0 catalysts. key achieve this reaction is choice as coupling partner that not only acts borylating reagent, but also chemoselectively activates aryl towards oxidative...
Abstract The facile one‐step reaction of C 60 with primary amides promoted by cheap and easily available Fe(ClO 4 ) 3 affords a series interesting fullerooxazole derivatives.
Borylierungen Über die Aktivierung von Arylcarbonsäuren durch Dibor-Reagenzien für nickelkatalysierte direkte decarbonylierende Borylierung berichten Xiaotai Wang, Weiping Su et al. im Forschungsartikel auf S. 24715.