A5100381354- Luminescence Properties of Advanced Materials
- Inorganic Fluorides and Related Compounds
- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Perovskite Materials and Applications
- Solid State Laser Technologies
- Glass properties and applications
- Electronic and Structural Properties of Oxides
- Luminescence and Fluorescent Materials
- Radiation Detection and Scintillator Technologies
- Catalytic Processes in Materials Science
- Advanced Nanomaterials in Catalysis
- Photonic Crystals and Applications
- Semiconductor materials and devices
- Nanoplatforms for cancer theranostics
- Optical properties and cooling technologies in crystalline materials
- Molecular Sensors and Ion Detection
- Liquid Crystal Research Advancements
- Surface and Thin Film Phenomena
- Fluid Dynamics and Thin Films
- Microwave Dielectric Ceramics Synthesis
- Nanocluster Synthesis and Applications
- Porphyrin and Phthalocyanine Chemistry
- Ammonia Synthesis and Nitrogen Reduction
- Lanthanide and Transition Metal Complexes
Ningbo Institute of Industrial Technology
2024-2025
Chinese Academy of Sciences
2009-2025
China Jiliang University
2015-2024
Henan Provincial Chest Hospital
2024
Wenzhou Medical University
2021
Fujian Institute of Research on the Structure of Matter
2012-2016
Hangzhou Xixi hospital
2015-2016
State Key Laboratory of Structural Chemistry
2016
Chongqing University of Technology
2015
Chongqing University
2015
Monodisperse Er(3+):NaGdF(4)@Ho(3+):NaGdF(4)@NaGdF(4) active-core/active-shell/inert-shell nanocrystals, which can extend the near-infrared wavelength excitable range for upconversion (UC) emissions, were successfully fabricated first time. Importantly, doping of Er(3+) and Ho(3+) into core shell respectively suppresses adverse energy transfers between them, resulting in intense UC emissions both dopants.
Novel Yb/Er(Tm):Na3MF7 (M = Zr, Hf) nanocrystals with intrinsic single-band upconversion emission, in contrast to the routine lanthanide-doped fluoride which show typical multi-band emissions, are reported for first time. Specifically, red intensity of Yb/Er:Na3ZrF7 is about 5 times as high that hexagonal Yb/Er:NaYF4 ones a similar crystal size.
NaGdF4 is regarded as an ideal upconversion (UC) host material for lanthanide (Ln3+) activators because of its unique crystal structure, high Ln3+ solubility, low phonon energy and photochemical stability, Ln3+-doped UC nanocrystals (NCs) have been widely investigated bio-imaging magnetic resonance imaging agents recently. To realize their practical applications, controlling the size uniformity monodisperse NCs highly desired. Unlike routine routes by finely adjusting multiple experimental...
Abstract Upon introducing Ca 2+ dopants into the grain lattices by substituting Gd 3+ ions, irregular Yb/Er:NaGdF 4 nanocrystals prepared through a simple solvothermal route convert highly uniform nanorods. Meanwhile, their upconversion luminescence intensifies about 200 times, probably due to modification of crystal structure NaGdF and an improvement in crystallinity nanophase.
Abstract Recently, dual‐atom alloy (DAA, also named diatomic alloy) catalysts with active metal dimers supported by a less host have attracted considerable interest owing to their distinctive geometric and electrical configurations. Despite developing many ways for synthesizing DAA catalysts, most contemporary methods depend on high‐temperature pyrolysis, costly apparatus, intricate procedures. This study presents, the first time, one‐step laser solid‐phase synthesis of (PtRu) 1 Co DAAs...
Efficient near-infrared quantum-cutting luminescence has been realized in Pr/Yb co-doped monodisperse core–shell nanoparticles and the active-core/active-shell structure leads to a much intensified emission.
A series of Er(3+)-doped (1 - x)CaF(2)-xYbF(3) (0 ≤ x 0.6) disordered solid-solution nanocrystals with various mean sizes were successfully prepared by a facile solvothermal route. Interestingly, abnormal size-dependent upconversion emissions demonstrated in these for the first time. With increasing grain size, an obvious enhancement red to green emission ratio was observed Er(3+) (2 mol%): 0.4CaF(2)-0.6YbF(3) nanocrystals, which is opposite routine behavior reported previously. Taking...
Background: Preserving nephrons while avoiding tumor recurrence during the treatment of renal cell carcinoma remains as a challenge in clinic.To achieve desired therapeutic outcome, we developed specific nanozymes based on microenvironment and evaluated its efficacy combination with radiotherapy.Methods: Herein, hybrid nanozyme CeO 2 @Au-PEG nanocomposite nanoparticle (NPs) was for tumor.It composed gold decorated nanorods exhibited both glucose-oxidase like by peroxidaselike catalytic...
Abstract The commonly used automotive head‐up display (HUD) technology is confronted with the problems of poor stability in organic resin counterpart and unsatisfactory effect projection lighting source. To solve these issues, developing state‐of‐the‐art materials designing new HUD schemes a wide color gamut necessity. Herein, series pure red/green/blue (R/G/B) upconverting (UC) nano‐glass‐ceramics (GCs) containing lanthanide‐doped NaLuF 4 nanocrystals (NCs) are synthesized cost‐effective,...
The first example of doped Eu-complex/polymer fluorescent films based on a PVB matrix is reported.
Abstract After coating 20 Yb/2 Er:NaGdF 4 core nanocrystals with a NaYbF shell, upconversion emission of the rare earth ions weakens. So far, exact reason for this phenomenon is still unclear due to lack direct evidence. In report, core@shell@shell sandwich‐like structure designed and fabricated investigate phenomenon. We find that high Yb 3+ concentration in shell has mainly two adverse impacts: it promotes not only deleterious back energy transfer from Er but also shell. To obtain...
Topical ocular drug administration aimed at providing a high concentration the precorneal site accompanied with enhanced corneal permeability to avoid systemic side effects is very important therapeutic goal in disorder therapy. In present study, solubility of poorly soluble celecoxib (CXB) was significantly improved using facile strategy generate payload micellar formulation. By varying drug/polymer feed ratios, mean diameter formed CXB micelles ranged from 21.34 ± 0.23 28.53 0.11 nm, and...
A novel method to modify the size of Yb/Er:KMnF<sub>3</sub> NCs by introducing Zn<sup>2+</sup> in initial solution is presented, and results can provide direct evidence for size-dependent upconversion luminescence.
An overview of the recent progresses in realizing single-band UC emission through different methods and related mechanisms are given for first time. The challenges future perspectives these novel NMs stated.
The stabilization of metal-oxide-bound molecular catalysts is essential for enhancing their lifetime and commercial viability in heterogeneous catalysis. This particularly relevant dye-sensitized photoelectrochemical cells (DSPECs), where the surface-bound chromophores exhibit instability aqueous environments, at elevated pH levels. In this work, we have successfully employed layer deposition (MLD) to stabilize ruthenium-based (RuCP(OH
Abstract Laser‐driven projection displays face a critical challenge in developing laser‐excitable and high‐performance narrowband green emitters. Herein, new Al 2 O 3 ‐LaMgAl 11 19 : Mn 2+ (Al ‐LMA: ) transparent composite ceramics are reported via high‐temperature vacuum sintering, which produces high‐color‐purity (95.4%) emission with full width at half maximum of 24 nm superior thermal moisture laser irradiation stability. These attributed to low electron‐phonon couple, weak crystal‐field...
Abstract Reactions of carboxyl‐functionalized cubane‐like photocyclodimer 2 with a series aromatic amines 3 were investigated for understanding the reactivity this unique system. Spectroscopic and X‐ray crystal structural analyses demonstrate that N , N′ ‐dicyclohexylcarbodiimide (DCC) is reactive toward affording stable 4 well‐retained structure. With assistance DCC, mono‐ diacyl‐substituted photocyclodimers 2‐sustituted naphthalene ( 5 6 ) have also been achieved in reasonable yields...