A5062113076- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Metal-Organic Frameworks: Synthesis and Applications
- Advanced Photocatalysis Techniques
- Metal complexes synthesis and properties
- CO2 Reduction Techniques and Catalysts
- Crystallography and molecular interactions
- Lung Cancer Treatments and Mutations
- Carbon dioxide utilization in catalysis
- Cancer-related gene regulation
- Covalent Organic Framework Applications
- Electron Spin Resonance Studies
- Advanced NMR Techniques and Applications
- Synthesis and Characterization of Heterocyclic Compounds
- Porphyrin and Phthalocyanine Chemistry
- Ferroptosis and cancer prognosis
- Epigenetics and DNA Methylation
- Nanocluster Synthesis and Applications
- Radioactive element chemistry and processing
- Heat Transfer and Boiling Studies
- Metal-Catalyzed Oxygenation Mechanisms
- Heat Transfer and Optimization
- Hepatitis B Virus Studies
Guangxi Normal University
2015-2025
Jinan University
2020-2024
Southern University of Science and Technology
2020-2024
Wuhan University of Technology
2023-2024
ShenZhen People’s Hospital
2019-2023
University of Macau
2021-2022
China Electronics Technology Group Corporation
2021
Wuxi People's Hospital
2020-2021
Tianjin University of Technology
2018-2020
Nanjing Medical University
2020
Identification of potential novel targets for reversing resistance to Epidermal Growth Factor Receptor (EGFR)-tyrosine kinase inhibitors (EGFR-TKIs) holds great promise the treatment relapsed lung adenocarcinoma (LUAD). In present study, we aim investigate role methyltransferase-like 7B (METTL7B) in inducing EGFR-TKIs LUAD and whether it could be a therapeutic target resistance.METTL7B-overexpressed cell lines, gefitinib osimertinib-resistant Cell-Derived tumor Xenograft (CDX)...
Engineering efficient and cost-effective electrocatalysts for the oxygen evolution reaction (OER) is an essential part of electrochemical water splitting.
Abstract Using solar energy to convert CO 2 into valuable fuels or chemicals offers a powerful solution urgent and environmental problems. However, the development of efficient selective catalysts remains considerable scientific challenge. To address this, catalytically active Co II centers can be anchored porous matrix metal–organic frameworks (MOFs) by utilizing robust Zr‐based MOF (Zr‐DMBD) functionalized with freestanding thiol groups enable post‐synthetic metal insertion. The...
To develop new lanthanide single-molecule magnets (SMMs), two complexes of [Dy2(MeOH)2(HL1)2(NO3)2]·2MeOH (1) and [Dy6(μ3-OH)2(L2)2(HL2)2(H2L2)2Cl2(EtOH)2]Cl2·3EtOH·CH3CN (2) were obtained by reacting Dy(NO)3·6H2O with 3-amino-1,2-propanediol in the presence 2-hydroxynaphthaldehyde for 1 DyCl3·6H2O 1,1-di(hydroxymethyl)ethylamine 2, respectively, which Schiff base ligands 3-(((2-hydroxynaphthaen-1-yl)methylene)amino)-propane-1,2-diol (H3L1)...
Drug resistance and tumor recurrence remain clinical challenges in the treatment of urothelial carcinoma (UC). However, underlying mechanism is not fully understood. Here, we performed single-cell RNA sequencing identified a subset cells with epithelial-mesenchymal transition (EMT) features (EMT-UC), which significantly correlated chemotherapy cancer recurrence. To validate significance EMT-UC, constructed EMT-UC like by introducing overexpression two markers, Zinc Finger E-Box Binding...
ABSTRACT The leakage of quinolone antibiotics may bring serious hazards to plants, animals, and human; thus, the detection is great urgent yet remains challenging issue. Herein, two isostructural metal–organic frameworks {[(CH 3 ) 2 NH ] [M ( μ ‐O)(BPDC) (TPP)]· x MeCN· y DMF} n (M = Co, 8, 1, NS‐13 ; M Ni, 7, NS‐14 H BPDC 4,4′‐biphenyldicarboxylic acid; TPP 2,4,6‐tris(4‐pyridyl)pyridine), have been successfully prepared through solvothermal method. were three‐dimensional networks built form...
ABSTRACT The catalytic conversion of carbon dioxide (CO 2 ) into valuable energy under light sources is one the effective ways to achieve cycle. reported nonprecious metal complex catalysts still show shortcomings low activity and selectivity in visible‐light–driven CO reduction, especially aqueous systems. Herein, we report three dinuclear mixed‐valence Co (II)/Co (III) complexes 1 – 3 bearing macrocyclic ligands that exhibit high for photocatalytic reduction an system. Moreover, TON reach...
A Co-based cryptate exhibits highly efficient and selective photocatalytic CO<sub>2</sub>-to-CO conversion under either pure CO<sub>2</sub> or 10% in a water-containing system.
The photocatalytic conversion of CO2 to valuable fuels or chemicals has displayed the promise solve urgent energy and environmental problems. Photocatalytic systems for reduction in water usually suffer from low efficiency selectivity due competitive proton relatively concentration. In this work, we report a CoII–ZnII heterometallic dinuclear complex [CoZn(bpbp)(CH3COO)2](CH3COO) (CoZn), which shows high activity CO2-to-CO water/acetonitrile solution. values TONCO CO reach as 6680 98%,...
Heterometallic metal-organic framework (MOF) as a kind of porous material is very important because its excellent properties in catalysis, magnetic, sensor, and adsorption fields, but the reasonable design syntheses these are still challenging. Herein, we prepared one heterometallic MOF with formula [Hf6(μ3-OH)8(OH)8][(Cu4I4) (ina)4]2·22DMF (NS-1, ina = isonicotinate). Single-crystal X-ray diffraction analysis revealed that NS-1 three-dimensional network flu topology, constructed from...
The tuning of slow magnetic relaxation six-coordinated Dy( iii ) complexes was achieved through chloride and bis-Schiff bases bearing different spacers.
Three zeolitic imidazolate framework-90 derivatives were synthesized via post-synthetic modification method, which exhibited ultrahigh iodine capture capacities.
Hydrothermal reactions of lanthanide oxides with a rigid ligand (2,3-f)-pyrazino(1,10)phenanthroline-2,3-dicarboxylic acid (H2PPDA) yielded 12 novel coordination polymers formulas [Ln(HPPDA)(PPDA)(H2O)2]·2H2O (Ln = Pr, 1·Pr; Nd, 2·Nd; Sm, 3·Sm; Eu, 4·Eu; Gd, 5·Gd; Tb, 6·Tb; and Dy, 7·Dy) [Ln2 (PPDA)3 (H2O)4]·nH2O n 2, 8·Pr; Ln 3, 9·Nd; 2,10·Sm; 1, 11·Eu; 12·Gd). Single-crystal X-ray diffraction analysis reveals that they present two different structural types. Type I for 1·Pr−7·Dy possesses...
A series of Ln4 clusters, [Ln4L2(μ3-OH)2(μ4-NO3)(NO3)4(OCH3)(H2O)]·xMeCN·yMeOH (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5), Yb (6), L 2-{[2-(2-hydroxy-ethoxy)-ethylimino]-methyl}-6-methoxyphenol), have been synthesized by the reaction Ln(NO)3 and a Schiff-base ligand formed in situ. The six complexes display similar structures, with an overall metal core comprising two edge-sharing triangular Ln3 units linked μ4-NO3(-) bridge. luminescence spectrum complex 2 shows characteristic emission...
Structural modification of a ligand is an effective way to improve the catalytic activity molecular catalysts for photocatalytic CO2 reduction. In this study, we designed and synthesized three tripodal ligands with different conjugate groups (L1 = tris{2-[(9′ - anthrylmethyl)amino)ethyl}amine, L2 tris{2-[(1′-naphthylmethyl)amino]ethyl}amine, L3 tris[2-(benzylamino)ethyl]amine), their corresponding mononuclear cobalt complexes, [CoL1(OH)]ClO4 (1), [CoL2(OH)]ClO4 (2), [CoL3(OH)]ClO4 (3)....