A5087466506- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Advanced Nanomaterials in Catalysis
- Molecular Sensors and Ion Detection
- Lanthanide and Transition Metal Complexes
- Nanocluster Synthesis and Applications
- Metal complexes synthesis and properties
- Covalent Organic Framework Applications
- Analytical Chemistry and Chromatography
- Hepatitis B Virus Studies
- Crystal structures of chemical compounds
- Nanoplatforms for cancer theranostics
- Porphyrin and Phthalocyanine Chemistry
- Polyoxometalates: Synthesis and Applications
- Advanced biosensing and bioanalysis techniques
- Rare-earth and actinide compounds
- Supramolecular Self-Assembly in Materials
- Inorganic Chemistry and Materials
- TiO2 Photocatalysis and Solar Cells
- Chromatography in Natural Products
- Hepatitis C virus research
- Sulfur Compounds in Biology
Shanghai University
2011-2025
Nanjing Normal University
2017-2024
Shanghai Electric (China)
2024
Tianjin University
2022-2024
Southern University of Science and Technology
2020-2024
Nankai University
2016-2023
Chinese PLA General Hospital
2021-2023
Changhong (China)
2022
Hai Kang Life (China)
2022
State Key Laboratory of Medicinal Chemical Biology
2021
In this work a rigid asymmetrical tricarboxylate ligand p-terphenyl-3,4″,5-tricarboxylic acid (H3L) has been employed, and unique heterometallic alkaline earth–lanthanide microporous luminescent metal–organic framework (MOF) {[Ba3La0.5(μ3-L)2.5(H2O)3(DMF)]·(3DMF)}n (1·3DMF) (DMF = dimethylformamide) isolated under solvothermal conditions. Single-crystal X-ray structural analysis demonstrates that 2D inorganic Ba–O–La connectivity can be observed in 1, which are further bridged via terphenyl...
Sensitivity, selectivity, visible detection, and rapid response are the main concerns for an analytical method. Herein, we reported a metal-organic framework (MOF)-based ratiometric fluorescence detection strategy hypochlorous acid (HClO). The MOF was prepared with dual ligands, 2-aminoterephthalic (BDC-NH2) dipicolinic (DPA) Eu3+ ions as metal node, denoted Eu-BDC-NH2/DPA. dual-ligand realized emission sensing visual adjusted size morphology of MOFs to obtain good dispersion response,...
Abstract Here an excellent trimodality imaging‐guided synergistic photothermal therapy (PTT)/photodynamic (PDT)/chemodynamic (CDT) is proposed. To this end, a mixed‐metal Cu/Zn‐metal‐organic framework (MOF) first assembled at room temperature on nano‐scale. Interestingly, heating the MOF results in Cu +/2+ ‐coexisting hollow porous structure. Subsequent treatment used to integrate Mn 2+ and MnO 2 presence of manganese(II) acetylacetonate. The composite achieves efficient loading...
Abstract Cascade catalytic reaction exhibits simple procedure and high efficiency, such as that from the orderly assembly of different enzymes in biological systems. Mimicking natural cascade becomes critical, but is still challenging. Herein, single Au–Pt nanozyme reported with “three‐in‐one” functions to initiate conversions for O 2 supply mimic catalase, H production its glucose oxidase‐like property, • OH generation peroxidase chemodynamic therapy (CDT). Thus, complex cross‐talk among...
Herein, we revealed the factors that affect emission in mixed-ligand metal-organic frameworks (MOFs) with combination of terephthalic acid (BDC), 2-aminoterephthalic (BDC-NH2), and 2,5-dihydroxylterephthalic [BDC-(OH)2] as models. The -NH2 -(OH)2 groups change π-conjugation luminescence behaviors than BDC, so ligands show different optical behaviors. Zn2+ ion a 3d10 full electronic structure shows little effect on ligand is selected metal node. We found BDC weak incompatible to BDC-NH2, only...
An Abtz–CdI<sub>2</sub>–MOF was developed as an “off–on” fluorescent switch for label-free detection of dopamine without any surface modification or functionalization.
The precise modulation of nanosheet stacking modes introduces unforeseen properties and creates momentous applications but remains a challenge. Herein, we proposed strategy using bipolar molecules as torque wrenches to control the 2-D Zr-1,3,5-(4-carboxylphenyl)-benzene metal-organic framework (2-D Zr-BTB MOF) nanosheets. phenyl-alkanes, phenylmethane (P-C1) phenyl ethane (P-C2), predominantly instigated rotational Zr-BTB-P-C1 Zr-BTB-P-C2, displaying wide angular distribution. This included...
In this work a flexible multi-dentate 1-(4-aminobenzyl)-1,2,4-triazole (abtz) ligand has been employed, unique cationic triazole–Ag(<sc>i</sc>) metal–organic nanotube {[Ag(μ<sub>3</sub>-abtz)]·(NO<sub>3</sub>)·(0.125H<sub>2</sub>O)}<sub>n</sub> (<bold>MONT-1</bold>) isolated under solvo-thermal conditions.
A dual-emissive lanthanide MOF was developed as a self-calibrating fluorescent probe for sensitively and selectively detecting phosphate with the naked eye.
To observe and analyse the clinical effects of entecavir on serum hyaluronic acid (HA), laminin (LN), type IV collagen (IVC) in patients with hepatitis B e-antigen (HBeAG)-positive chronic during treatment. The control group received treatment monotherapy, while those observation underwent thymalfasin + combination therapy. curative immune checkpoint inhibitors at different concentrations diseases were compared from all aspects. There lower levels total bilirubin (TBIL) alanine transaminase...
Recently, luminescent metal–organic framework (MOF) materials have attracted considerable attention in fluorescence sensing. In this essay, we prepared a new cluster-based CaII-MOFs {[Ca1.5(μ8-HL1)(DMF)2]·DMF}n (1) with good water dispersibility, excellent photoluminescence properties (FL quantum yield of 20.37%) and great stability. Further, it was employed to design as an "off–on" sensor for sensitive detection l-cysteine. This proposed strategy that 1 quenched providing low background by...
Abstract The rational design of artificial solid‐state nanopores is great importance in the discovery intriguing ion transport phenomena. 2D metal–organicframework (2D MOF) nanosheets with single crystallinity, aligned nanochannels, ultrathin thickness, and diverse functionalities are highly potential nanopores. An electrophoretic method developed to successfully fabricate MOF supported by SiN x substrate, which confirmed high‐resolution transmission electron microscopy. A giant gap around 4...
The engineering of intermolecular interaction is challenging but critical for magnetically switchable molecules. Here, we prepared two cyanide-bridged [Fe4 Co4 ] cube complexes via the alkynyl- and alcohol-functionalized trispyrazoyl capping ligands. alkynyl-functionalized complex 1 exhibited a thermally-induced incomplete metal-to-metal electron transfer (MMET) behaviour at around 220 K, while mixed alkynyl/alcohol-functionalized 2 showed complete abrupt MMET 232 K. Remarkably, both...
The construction of large and complex supramolecular architectures through self-assembly is at the forefront contemporary coordination chemistry. Notwithstanding great success in various systems using anionic bridges (e.g., O
Conductive hydrogels exhibit tremendous potential for wearable bioelectronics, biosensing, and health monitoring applications, yet concurrently enhancing their biocompatibility antimicrobial properties remains a long-standing challenge. Herein, we report an all-natural conductive supramolecular hydrogel (GT
Six families of new lanthanide coordination polymers, [Ln2(L)6(H2O)2]n·3nH2O (Ln = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho (7), Er (8), Yb (9)), [Pr2(L)2(ox)2(H2O)4]n·9nH2O (10), [Pr2(L)2(glu)2(H2O)2]n (11), [Er2(L)2(glu)2]n (12), [Nd2(L)2(adip)2]n (13), [Ln2(L)2(1,2-bdc)2(H2O)2]n (14), (15), (16)), (HL 4′-(2-carboxyphenyl)-4,2′:6′,4′′-terpyridine, H2ox oxalic acid, H2glu glutaric H2adip adipic H2(1,2-bdc) benzene-1,2-dicarboxylic acid) were synthesized under hydrothermal...
The wrinkles are pervasive in ultrathin two-dimensional (2D) materials, but the regulation of is rarely explored systematically. Here, we employed a series carboxylic acids (from formic acid to octanoic acid) control Zr-BTB (BTB=1, 3, 5-(4-carboxylphenyl)-benzene) metal-organic framework (MOF) nanosheet. at micrometer scale were observed with transmission electron microscopy. Furthermore, high-angle annular dark-field (HAADF) images showed lattice distortion many nanoscale regions, which was...