A5006086196- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Luminescence Properties of Advanced Materials
- biodegradable polymer synthesis and properties
- Luminescence and Fluorescent Materials
- Advanced Fiber Laser Technologies
- Perovskite Materials and Applications
- Inorganic Fluorides and Related Compounds
- Advanced Polymer Synthesis and Characterization
- Photorefractive and Nonlinear Optics
- Carbon dioxide utilization in catalysis
- Electrocatalysts for Energy Conversion
- Photonic and Optical Devices
- Click Chemistry and Applications
- Synthetic Organic Chemistry Methods
- Organometallic Complex Synthesis and Catalysis
- Semiconductor Lasers and Optical Devices
- Protein Degradation and Inhibitors
- Chemistry and Chemical Engineering
- Solid State Laser Technologies
- Ga2O3 and related materials
- Catalysis and Hydrodesulfurization Studies
- Silicone and Siloxane Chemistry
- Biotin and Related Studies
- Synthesis and Properties of Aromatic Compounds
Jiangsu University
2023-2024
University of Illinois Urbana-Champaign
2016-2019
Urbana University
2016-2019
Shaanxi Normal University
2014-2017
China XD Group (China)
2014-2015
Peking University
2012-2014
Beijing National Laboratory for Molecular Sciences
2014
University of California, Santa Barbara
2002
A straightforward strategy has been used to construct large BN-embedded π-systems simply from azaacenes. BN heterosuperbenzene derivatives, the largest heteroaromatics date, have synthesized in three steps. The molecules exhibit curved π-surfaces, showing two different conformations which are self-organized into a sandwich structure and further packed π-stacking column. assembled microribbons good charge transport properties photoconductivity, representing an important step toward...
The UC fluorescence emission and tuning from Ce<sup>3+</sup> codoped β-NaY(Gd<sub>0.4</sub>)F<sub>4</sub>:Yb<sup>3+</sup>/Ho<sup>3+</sup> nanocrystals.
Well-defined polymers derived from biomass feedstock (e.g., soybean oil, rosin acid, and furfural) were successfully prepared by metal-free atom transfer radical polymerization (ATRP). In the presence of photoredox catalysts UV irradiation, three biomass-based methacrylate monomers efficiently polymerized with good control over molecular weight dispersity. NMR MALDI-TOF MS confirmed high fidelity chain end groups originated initiators. Furthermore, block copolymers these also achieved...
Recently O-carboxyanhydrides (OCAs) have emerged as a class of viable monomers which can undergo ring-opening polymerization (ROP) to prepare poly(α-hydroxyalkanoic acid) with functional groups that are typically difficult achieve by ROP lactones. Organocatalysts for the OCAs, such dimethylaminopyridine (DMAP), may induce undesired epimerization α-carbon atom in polyesters resulting loss isotacticity. Herein, we report use (BDI-IE)Zn(OCH(CH3 )COOCH3 ) ((BDI)Zn-1,...
The upconversion (UC) emission of single LiYF4:Yb3+/Ho3+ microparticle with codoped Ce3+ is investigated. UC tuning from green to red in successfully obtained by codoping ions different concentrations, and the enhancement mechanism discussed detail. results indicate that two efficient cross-relaxations between Ho3+ enhance suppress process. investigation on luminescence property a microcrystal can effectively avoid influence particles around provide more precise information for better...
Rare earth ion-doped upconversion materials show great potential applications in optical and optoelectronic devices due to their novel properties.
Abstract Iron and nitrogen co-doped carbon materials (Fe-N-C) have garnered widespread attention owing to their highly active Fe-N4 sites. Here, we proposed a novel approach for synthesizing bimetallic single-atom catalysts by introducing Cu atoms into Fe-N-C. The resultant Fe-Cu-NC catalyst exhibited large specific surface area. Moreover, it had superior half-wave potential of 0.890 V (vs. RHE) in alkaline media. Density functional theory calculations disclosed that the introduction...
We developed a facile approach to modulate molecular arrangement through dimerizing of π-moieties and tuning alkylene-bridge length. Dimers fluoranthene-fused imide (DFAI-Cns) with various lengths alkylene chains were synthesized by Diels–Alder reaction followed decarbonylation. DFAI-C3 DFAI-C5 odd-carbon display stronger one-dimensional growing tendency better crystallinity than those even-carbon chains. Microwires dimers successfully obtained, their packing was analyzed transmission...
Herein, we present a series of light-triggered porphyrin-based polymeric drug conjugates PSDTD-m for combined chemo-photodynamic therapy cancer. The controlled release through ROS-cleavable linker with photodynamic showed enhanced anticancer efficacy, proving the effectiveness this light triggered smart nanocarrier platform enhancing efficacy.
A simple template strategy was applied to prepare a Fe, N co-doped hollow carbon (Fe-NHC) nanoreactor for the oxygen reduction reaction (ORR) by coating Fe nanoparticles (Fe-NPs) with polydopamine (PDA), followed high temperature pyrolysis and acid-leaching. With this method, Fe-NPs were used as both metal precursor, so that nanoreactors can preserve original spherical morphology embed single atoms on inner walls. The carbonized PDA contained abundant content, offering an ideal coordination...
In this study, we report incorporation of a covalent linker at the anomeric position N-azidoacetylmannosamine (ManNAz) for caging its metabolic process. We synthesized DT-diaphorase-responsive precursor, HQ-NN-AAM, using an optimized linker. The caged metabolite showed responsiveness to DT-diaphorase in vitro, resulting azido sugar into cell surface multiple lines.
A hindered urea bond (HUB), recently reported as a new type of dynamic chemical bond, can be facilely constructed by mixing an isocyanate and amine. Here, we report the use HUB in design degradable hydrogel materials for applications stem cell encapsulation delivery. Polyethyleneglycol (PEG) diamine was end-capped with allyl group one-pot synthesis. The resulting polymer cross-linked to form under UV addition 4-arm PEG thiol photoinitiator. degradation properties hydrogels were confirmed...
The changeable matrix under different calcination temperatures leads to tunable luminescence properties.
Abstract Recently O ‐carboxyanhydrides (OCAs) have emerged as a class of viable monomers which can undergo ring‐opening polymerization (ROP) to prepare poly(α‐hydroxyalkanoic acid) with functional groups that are typically difficult achieve by ROP lactones. Organocatalysts for the OCAs, such dimethylaminopyridine (DMAP), may induce undesired epimerization α‐carbon atom in polyesters resulting loss isotacticity. Herein, we report use (BDI‐IE)Zn(OCH(CH 3 )COOCH ) ((BDI)Zn‐1,...
A liquid ROMP based thermosetting resin is developed which undergoes slow polymerization at room temperature and rapid elevated temperatures.
Abstract Atomically dispersed iron and nitrogen co‐doped carbon materials (Fe−N−C) represent promising non‐precious metal catalysts for the oxygen reduction reaction (ORR), offering potential alternatives to noble metal‐based benchmarks. In our study, we investigated influence of phosphorus doping on catalytic activity Fe−N−C. The experimental research demonstrate that significantly enhances ORR activity. Specifically, resulting Fe‐NPC exhibits high loading excellent in 0.1 M KOH with an...
Yb 3+ /Ho doped hexagonal NaGdF 4 nanocrystals are synthesized through solvothermal method, for which pure phased nanorods presented. The concentration influence of ions on the sample morphology and fluorescence emission Ho is investigated. It found that size changed from 25 nm to 125 upconversion tuned green yellow when increased 5.0 mol% 50.0 mol%. possible mechanism improvement crystallinity carefully suggested cross-relaxation process between promotes red quenches emission.