A5044575891- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Advanced Battery Materials and Technologies
- Advanced biosensing and bioanalysis techniques
- Supramolecular Chemistry and Complexes
- Machine Learning in Materials Science
- Luminescence and Fluorescent Materials
- Perovskite Materials and Applications
- Bladder and Urothelial Cancer Treatments
- Advanced Nanomaterials in Catalysis
- Thermal Expansion and Ionic Conductivity
- Advancements in Battery Materials
- X-ray Diffraction in Crystallography
- Conducting polymers and applications
- Computational Drug Discovery Methods
- Ferroelectric and Piezoelectric Materials
- Biosensors and Analytical Detection
- History and advancements in chemistry
- Extracellular vesicles in disease
- Advanced Battery Technologies Research
- Carbon and Quantum Dots Applications
- Supramolecular Self-Assembly in Materials
- Nanoplatforms for cancer theranostics
- Gold and Silver Nanoparticles Synthesis and Applications
- High-pressure geophysics and materials
ShanghaiTech University
2022-2025
Shenzhen University
2023-2024
Shenzhen University Health Science Center
2023
Durham University
2019
Dynamic 3D covalent organic frameworks (COFs) have shown concerted structural transformation and adaptive gas adsorption due to the conformational diversity of linkers. However, isolation observation COF rotamers constitute undergoing challenges their comparable free energy subtle rotational barrier. Here, we report atomic-level evolution by cryo-3D electron diffraction synchrotron powder X-ray diffraction. Specifically, optimize crystallinity morphology COF-320 manifest its coherent dynamic...
Controllable self-assembly of the DNA-linked gold nanoparticle (AuNP) architecture for in vivo biomedical applications remains a key challenge. Here, we describe use programmed DNA tetrahedral structure to control assembly three different types AuNPs (∼20, 10, and 5 nm) by organizing them into defined positioning arrangement. A DNA-assembled "core-satellite" is built sequencing where satellite (10 surround central core AuNP (20 nm). The density arrangement satellites around were controlled...
The second near-infrared (NIR-II) window laser-activated agents have attracted broad interest in an orthotopic cancer theranostic. However, developing NIR-II photothermal (PTAs) with advanced conversion efficiency (PTCE) and tumor-specific response elevation remains a crucial challenge. Herein, hollow gold nanorod (AuHNR) strong localized surface plasmon resonance (LSPR) peak the was coated MnO2 chitosan to obtain AuHNR@MnO2@CS (termed AuMC) by one-step method. Upon exposure tumor...
Polar organic cocrystals hold great promise for various advanced technological applications. However, their relatively low prevalence highlights the challenges of achieving desired polar packing arrangements, making discovery complex and demanding. Here, we present a data-driven approach that integrates machine learning (ML) with high-throughput (HT) automation to accelerate cocrystals. Using ML methodologies, identified key parameters governing cocrystal formation, enabling targeted...
The development of new organic ferroelectrics has encountered some challenges and opportunities. In this perspective, we have summarised synthetic computational design principles for high-performance ferroelectrics.
Porous organic cage templates for Pd nanoparticle catalysts – a new porous, solution processable and fully soluble, recrystallisable support heterogeneous catalysts.
Metal-organic frameworks (MOFs) are promising nanoporous materials with diverse applications. Traditional material discovery based on intensive manual experiments has certain limitations efficiency and effectiveness when faced nearly infinite space. The current situation offers an opportunity for high-throughput (HT) machine learning (ML) approaches, including computational experimental methods, as they have greatly improved the of MOF screening capacity to deal enormous growth data. In this...
In pursuit of environmental sustainability and energy efficiency, assorted macrocyclic compounds have recently emerged as crystalline adsorbents for the efficient molecular sieving various chemical commodities. Herein, we delve into conformational characteristics solid-state packing modes tiara[5]arenes (T[5]), a rim-differentiated pillar[5]arene derivative. By meticulously exploring space, successfully identified multitude distinct T[5] conformers within relatively narrow range 22 kJ/mol....
The structural characterization of new materials often poses immense challenges, especially when obtaining single-crystal structures is difficult, which a common difficulty with covalent organic frameworks (COFs). Despite this, understanding the atomic structure crucial as it provides insights into arrangement and connectivity building blocks, offering opportunity to establish correlation structure–function relationships unravel material properties. In this study, we present an approach for...
There has been significant recent interest in exploiting the large dimension changes that can occur molecular materials as a function of temperature, stress, or under optical illumination. Here, we report remarkable thermal expansion properties chloranilic acid pyrazine co-crystals. We show compound shows uniaxial negative over wide temperature range with linear contraction coefficient low (−)1500 × 10–6 K–1 at 250 K. The corresponding 10% between 200 and 300 K is an order magnitude larger...