Xin Zhao

ORCID: 0000-0003-3911-0963
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About
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Research Areas
  • Crystal Structures and Properties
  • Nonlinear Optical Materials Research
  • Genetic diversity and population structure
  • Organometallic Compounds Synthesis and Characterization
  • Magnetic confinement fusion research
  • Plasma Diagnostics and Applications
  • Particle accelerators and beam dynamics
  • Genetic and Clinical Aspects of Sex Determination and Chromosomal Abnormalities
  • Solid-state spectroscopy and crystallography
  • Crystal structures of chemical compounds
  • Advanced Computational Techniques and Applications
  • Ferroelectric and Piezoelectric Materials
  • Species Distribution and Climate Change
  • Plant Ecology and Taxonomy Studies
  • Photorefractive and Nonlinear Optics
  • Plant Parasitism and Resistance
  • Maritime Navigation and Safety
  • Evolution and Genetic Dynamics
  • Plant Virus Research Studies
  • Iron-based superconductors research
  • Chromosomal and Genetic Variations
  • Wave and Wind Energy Systems
  • Insect symbiosis and bacterial influences
  • Medical Imaging Techniques and Applications
  • Anodic Oxide Films and Nanostructures

Fujian Institute of Research on the Structure of Matter
2020-2024

University of Chinese Academy of Sciences
2020-2024

Chinese Academy of Sciences
2011-2024

Inner Mongolia Medical University
2024

Shandong University of Technology
2023

Northwest Institute of Eco-Environment and Resources
2019-2023

Beihua University
2023

Tan Kah Kee Innovation Laboratory
2021-2022

Institute of Hydrobiology
2013-2021

Energy Research Institute
2021

Balancing the second-harmonic generation (SHG) coefficient, band gap, and birefringence is a vital but addressable challenge for designing infrared nonlinear optical materials. By applying "rigidity–flexibility coupling" strategy, quaternary diamond-like phosphide, Mg2In3Si2P7, with wurtzite-type superstructure was successfully designed synthesized. Remarkably, it achieved rare coexistence of giant (2 × ZnGeP2 7.1 AgGaS2), suitable gap (2.21 eV), moderate (0.107), wide IR transparent range...

10.1021/jacs.1c03930 article EN Journal of the American Chemical Society 2021-07-01

Ionic organic crystals containing planar π-conjugated units has become one of the hot spots as nonlinear optical (NLO) materials. However, although this type ionic NLO commonly have remarkable second harmonic generation (SHG) responses, they also suffer from overlarge birefringences and relatively small band gaps that be hardly beyond 6.2 eV. Herein, a flexible [C3 H(CH3 )O4 ]2- unit was theoretically revealed, showing great potential for designing with balanced properties. Accordingly,...

10.1002/anie.202304858 article EN Angewandte Chemie International Edition 2023-05-23

Hybrid two-dimensional (2D) halide perovskites have emerged as an important class of high-performance semiconductors because their excellent physical properties and structural diversity. Here, we report a new family hybrid 2D Ge-based that the Dion–Jacobson structure type, with general formula A(MA)n–1GenX3n+1, where A = 2-(aminomethyl)pyridinium (2AMPY), 3-(aminomethyl)pyridinium (3AMPY), 4-(aminomethyl)pyridinium (4AMPY), or 4-(aminomethyl)piperidinium (4AMP), X Br I, n 1 2. Single-crystal...

10.1021/acs.chemmater.3c00278 article EN Chemistry of Materials 2023-04-05

Abstract Polar materials play a crucial role in numerous essential fields; however, efficiently synthesizing them remains significant challenge. In this study, viable approach is proposed to enhance the probability of discovering polar by developing new functional basic units (FBUs) with strong polarity and high configurational entropy. To validate approach, site‐modification strategy applied entropy flexible (C 3 H 2 O 4 ) 2− FBU, resulting development four polar‐enhancing FBUs: (CH , F...

10.1002/adfm.202402295 article EN Advanced Functional Materials 2024-04-15

Polar molecular crystals, with their densely stacked polar nonlinear optical (NLO) active units, are favored for large second harmonic generation (SHG) responses and birefringence. However, potential practical applications as Infrared (IR) NLO materials has historically been underappreciated due to the weak inter-molecular interaction forces that may compromise physicochemical properties. In this study, we propose crystals cages a treasure-house development of superior IR representative...

10.1002/anie.202319424 article EN Angewandte Chemie International Edition 2024-01-25

Abstract Pnictides are superior infrared (IR) nonlinear optical (NLO) material candidates, but the exploration of NLO pnictides is still tardy due to lack rational design strategies. An in‐depth understanding structure–performance relationship urgent for designing novel and eminent pnictide materials. Herein, this work unravels a vital band gap mechanism pnictides, namely P atom with low coordination numbers (2 CN) will cause decrease delocalization non‐bonding electron pairs. Accordingly,...

10.1002/advs.202105787 article EN cc-by Advanced Science 2022-03-31

Abstract As a new spherical tokamak designed to simplify the engineering requirements of possible future fusion power source, EXL-50 experiment features low aspect ratio vacuum vessel (VV), encircling central post assembly containing toroidal field coil conductors without solenoid. Multiple electron cyclotron resonance heating (ECRH) resonances are located within VV improve current drive effectiveness. Copious energetic electrons produced and measured with hard x-ray detectors, carry bulk...

10.1088/1741-4326/ac71b6 article EN cc-by Nuclear Fusion 2022-05-20

Photovoltaic (PV) park construction has a profound impact on the regional microclimate and ecosystem carbon cycle. Meanwhile, biological soil crusts (BSCs) also play crucial role in nitrogen cycles of desert ecosystems. However, response mechanism algal BSC microbial communities to PV panel is still poorly elucidated. In this study, high-throughput sequencing was utilized explore underlying effects Talatan Base. The results showed that predominant bacterial phyla BSCs grassland were...

10.3389/fenvs.2025.1552071 article EN cc-by Frontiers in Environmental Science 2025-04-29

The Yangtze finless porpoise (Neophocaena asiaeorientalis asiaeorientalis) is a highly threatened cetacean endemic to the middle and lower reaches of River that has suffered dramatic decline in recent decades. We characterize quantify distribution patterns porpoises order facilitate strategic management existing situ reserves maximize effective utilization limited conservation resources. calculated relative abundance (encounter rate) using 1-km moving average along main stem based on...

10.1111/acv.12019 article EN Animal Conservation 2013-01-16

Continuously, nitrides are mainly regarded as semiconductors or thermal conductivity materials and applied in photonic devices. In this work, we proposed that may also be a new system for mid-infrared (mid-IR) nonlinear optical (NLO) materials. Meanwhile, first report the halonitrides Zn2NX (X = Cl, Br) mid-IR NLO crystals, which were synthesized by solid–liquid reaction. Both compounds show excellent properties including large band gaps (3.21 3.28 eV), strong second-harmonic generation...

10.1021/acs.chemmater.0c04772 article EN Chemistry of Materials 2021-02-02

Unisexual taxa are commonly considered short-lived as the absence of meiotic recombination is supposed to accumulate deleterious mutations and hinder creation genetic diversity. However, gynogenetic gibel carp ( Carassius gibelio ) with high diversity wide ecological distribution has outlived its predicted extinction time a strict unisexual reproduction population. Unlike other vertebrates, males associated supernumerary microchromosomes have been observed in carp, which provides unique...

10.1371/journal.pgen.1009760 article EN cc-by PLoS Genetics 2021-09-07

Unisexual lineages are commonly considered to be short-lived in the evolutionary process as accumulation of deleterious mutations stated by Muller’s ratchet. However, gynogenetic hexaploid gibel carp ( Carassius gibelio ) with existence over 0.5 million years has wider ecological distribution and higher genetic diversity than its sexual progenitors, which provides an ideal model investigate underlying mechanisms on countering ratchet unisexual taxa. Unlike other lineages, wild populations...

10.3389/fgene.2021.691923 article EN cc-by Frontiers in Genetics 2021-05-28

A non-centrosymmetric metal-free thiophosphate, γ-P 4 S 3 I 2 , was successfully designed and synthesized by polymorphism strategy, featured paralleled (P ) n molecular clusters exhibited promising nonlinear optical (NLO) performances.

10.1039/d2qi02313j article EN Inorganic Chemistry Frontiers 2022-12-19

Searching on the functional building units with ultrawide band gaps, large hyperpolarizabilities, and strong anisotropies is key to finding new deep-ultraviolet (DUV) nonlinear-optical (NLO) materials. In this study, polar covalent tetrahedral unit [SO3(OH)]- studied by theoretical calculation its excellent DUV optical properties are revealed. Moreover, we thoroughly investigate known bisulfates, a promising NLO crystal, NaHSO4·H2O. It exhibits second-harmonic-generation (SHG) response of...

10.1021/acs.inorgchem.2c03743 article EN Inorganic Chemistry 2022-11-30

Abstract Because mid‐ and far‐infrared (IR) nonlinear optical (NLO) materials play an important role in military civil fields, plenty of excellent IR NLO have been discovered recent decades, such as chalcogenides with T2 supertetrahedra. Pnictides supertetrahedra instead MQ 4 (M = II B , III A IV metals; Q P, As) tetrahedra, may favor high second‐harmonic generation (SHG) efficiency due to their large hyperpolarizability, but they rarely reported. Therefore, this study, two pnictides...

10.1002/adom.202200045 article EN Advanced Optical Materials 2022-06-05

Nitrides are an emerging and promising class of nonlinear optical (NLO) crystals, in this review, recently reported potential NLO nitrides summarized categorized into three groups based on their structural features.

10.1039/d3qm00657c article EN cc-by Materials Chemistry Frontiers 2023-01-01

Abstract Polar molecular crystals, with their densely stacked polar nonlinear optical (NLO) active units, are favored for large second harmonic generation (SHG) responses and birefringence. However, potential practical applications as Infrared (IR) NLO materials has historically been underappreciated due to the weak inter‐molecular interaction forces that may compromise physicochemical properties. In this study, we propose crystals cages a treasure‐house development of superior IR...

10.1002/ange.202319424 article EN Angewandte Chemie 2024-01-25
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