A5100630132- Asymmetric Synthesis and Catalysis
- Asymmetric Hydrogenation and Catalysis
- Catalytic C–H Functionalization Methods
- Synthesis and Characterization of Heterocyclic Compounds
- Synthesis and Catalytic Reactions
- Microwave-Assisted Synthesis and Applications
- Chemical Reactions and Isotopes
- Organoboron and organosilicon chemistry
- Chemical Synthesis and Analysis
- Synthesis and Biological Evaluation
- Biochemical and Molecular Research
- Chemical Reaction Mechanisms
- Synthetic Organic Chemistry Methods
Dalian University
2019
Dalian Institute of Chemical Physics
2006-2009
Central China Normal University
2009
t-BuOK was found to be an effective promoting reagent for tandem ring-opening/closing reactions of various N-Ts aziridines and aryl propargyl alcohols afford dihydroxazine derivatives in moderate good yields. A plausible reaction mechanism has been proposed.
An efficient Rh-catalyzed arylation of <italic>N</italic>-tosylarylimines has been developed with benzene backbone sulfoxide–olefin ligands, affording chiral diarylmethylamines in high yields (up to 99%) excellent enantioselectivities 99% ee).
With chiral 2-methoxy-1-naphthylsulfinyl-based phenyl backbone sulfoxide-olefin ligands, a highly Rh-catalyzed addition of arylboronic acids to N,N-dimethylsulfamoyl-protected aldimines has been developed afford broad range diarylmethylamines in high yields (up 99%) with excellent enantioselectivities 99% ee). Moreover, efficient enantioselective arylation cyclic N-sulfonylimines was also achieved 98%
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