Xiaojing Yao

ORCID: 0000-0003-4046-657X
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About
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Research Areas
  • Graphene research and applications
  • 2D Materials and Applications
  • MXene and MAX Phase Materials
  • Advanced Battery Materials and Technologies
  • Carbon Nanotubes in Composites
  • Boron and Carbon Nanomaterials Research
  • Topological Materials and Phenomena
  • Molecular Junctions and Nanostructures
  • Advanced battery technologies research
  • Advancements in Battery Materials
  • Crystallization and Solubility Studies
  • Nanopore and Nanochannel Transport Studies
  • X-ray Diffraction in Crystallography
  • Electrocatalysts for Energy Conversion
  • Granular flow and fluidized beds
  • Fuel Cells and Related Materials
  • Perovskite Materials and Applications
  • Mineral Processing and Grinding
  • Quantum and electron transport phenomena
  • Fullerene Chemistry and Applications
  • Electronic and Structural Properties of Oxides
  • Supercapacitor Materials and Fabrication
  • Advanced Photocatalysis Techniques
  • Nanotechnology research and applications
  • Advanced Condensed Matter Physics

Hebei Normal University
2018-2025

Tsinghua University
2015-2025

Tsinghua–Berkeley Shenzhen Institute
2022-2025

Shanghai Normal University
2024

Hebei University of Technology
2024

Chengdu University
2023

First Affiliated Hospital of Xi'an Jiaotong University
2022

Taiyuan University of Science and Technology
2021

South China Normal University
2021

Shijiazhuang University
2019-2020

The sustained water consumption and uncontrollable dendrite growth strongly hamper the practical applications of rechargeable zinc (Zn) metal batteries (ZMBs). Herein, for first time, we demonstrate that trace amount chelate ligand additive can serve as a "molecular sieve-like" interfacial barrier achieve highly efficient Zn plating/stripping. As verified by theoretical modeling experimental investigations, benzenesulfonic acid groups on molecular not only facilitates its solubility...

10.1002/anie.202312193 article EN Angewandte Chemie International Edition 2023-09-29

Two-dimensional (2D) nanofluidic membranes have shown great promise in harvesting osmotic energy from the salinity difference between seawater and fresh water. However, output power densities are strongly hampered by insufficient membrane permselectivity. Herein, we demonstrate that vacancy engineering is an effective strategy to enhance permselectivity of 2D achieve high-efficiency generation. Phosphorus vacancies were facilely created on NbOPO4 (NbP) nanosheets, which remarkably enlarged...

10.1021/jacs.2c12936 article EN Journal of the American Chemical Society 2023-01-18

Abstract Rechargeable halide-ion batteries (HIBs) are good candidates for large-scale due to their appealing energy density, low cost, and dendrite-free features. However, state-of-the-art electrolytes limit the HIBs’ performance cycle life. Here, via experimental measurements modelling approach, we demonstrate that dissolutions in electrolyte of transition metal elemental halogen from positive electrode discharge products negative cause HIBs failure. To circumvent these issues, propose...

10.1038/s41467-023-36622-w article EN cc-by Nature Communications 2023-02-18

Aqueous zinc (Zn) metal batteries (ZMBs) have received great attention due to their safety and environmental friendliness. Although aqueous electrolytes facilitate fast kinetics in oxide cathodes, incompatibility with the Zn anodes triggers severe hydrogen evolution reaction (HER) dendrite growth. Herein, a self-phase separated electrolyte (SPSE) is proposed fulfill contradictory requirements of anode cathode ZMBs. Molecular modeling experimental investigations verify that hydrophobic...

10.1021/jacs.4c15132 article EN Journal of the American Chemical Society 2025-01-08

An effective passivation approach to protect black phosphorus (BP) from degradation based on multi-scale simulations is proposed. The self-assembly of perylene-3,4,9,10-tetracarboxylic dianhydride monolayers via van der Waals epitaxy BP does not break the original electronic properties BP. layer thickness only 2 nm. This study opens up a new pathway toward fine

10.1002/adma.201603990 article EN Advanced Materials 2016-12-14

Rechargeable multivalent metal (e.g., zinc (Zn) and aluminum (Al)) batteries are ideal choices for large-scale energy storage owing to their intrinsic low cost safety. However, the poor compatibility between metallic anodes electrolytes strongly hampers practical applications. Herein, it is demonstrated that confining metals in a biomimetic scaffold (Bio-scaffold) can achieve highly efficient plating/stripping. This Bio-scaffold well-tailored through synergy of parallel-aligned array fractal...

10.1002/adma.202206970 article EN cc-by Advanced Materials 2022-09-20

Rechargeable room-temperature sodium-sulfur (RT Na-S) batteries are a promising energy storage technology, owing to the merits of high density and low cost. However, their electrochemical performance has been severely hindered by poor compatibility between existing electrolytes electrodes. Here, we demonstrate that an all-fluorinated electrolyte, containing 2,2,2-trifluoro-N,N-dimethylacetamide (FDMA) solvent, 1,1,2,2-tetrafluoroethyl methyl ether (MTFE) anti-solvent fluoroethylene carbonate...

10.1002/anie.202205416 article EN publisher-specific-oa Angewandte Chemie International Edition 2022-05-11

Abstract Lithium garnets are considered as promising solid‐state electrolytes for next‐generation Li metal batteries (SSLBs). However, the intrusion driven by external stack pressure triggers premature of batteries. Herein, first time, an in situ constructed interfacial shield is reported to efficiently inhibit pressure‐induced SSLBs. Theoretical modeling and experimental investigations reveal that high‐hardness metallic Mo nanocrystals inside effectively suppress dendrite growth without...

10.1002/adma.202308275 article EN Advanced Materials 2023-10-18

Efficient carrier separation is the key to application of photoelectric device. However, photogenerated electron–hole pairs in simplex semiconductors generally occupy same regions spatially and are easy recombine. Here we design a graphitic zinc-oxide-based (g-ZnO) intrinsic type-II heterostructure, g-ZnO/blue phosphorus (BP), based on first-principles calculations. The band offsets large built-in electric field ensure electrons easily migrating from g-ZnO BP, which significantly enhances...

10.1021/acs.jpcc.6b12613 article EN The Journal of Physical Chemistry C 2017-01-24

Abstract Carbon nanotubes (CNTs) are promising candidates for smart electronic devices. However, it is challenging to mediate their bandgap or chirality from a vapor-liquid-solid growth process. Here, we demonstrate rate-selected semiconducting CNT arrays based on interlocking between the atomic assembly rate and of CNTs. Rate analysis confirms Schulz-Flory distribution which leads various decay rates as length increases in metallic Quantitatively, nearly ten-fold faster CNTs spontaneous...

10.1038/s41467-019-12519-5 article EN cc-by Nature Communications 2019-10-02

As an emerging new type of battery chemistry, the anion shuttle (ASB), based on shuttling and storage anions, is considered a sustainable alternative to gigawatt-scale energy due associated resource abundance, low cost, high safety, density. Although significant progress has been achieved, practical applications ASBs are still hindered by tough challenges, such as short lifetime, limited reversible capacity, Coulombic efficiency. Therefore, it very necessary design explore electrolyte...

10.1016/j.esci.2022.10.003 article EN cc-by-nc-nd eScience 2022-10-21

High-voltage high-nickel low-cobalt lithium layered oxide cathodes show great application prospects for lithium-ion batteries due to their low cost and high capacity. However, deterioration of the bulk structure electrode-electrolyte interface will significantly endanger cycle life thermal stability battery as nickel content voltage increase. We present here a lattice doping strategy greatly improve cell performance by small dose Ti (2 mol %) in LiNi0.6Co0.05Mn0.35O2. Through density...

10.1021/acsami.1c20568 article EN ACS Applied Materials & Interfaces 2021-12-03

Abstract The sustained water consumption and uncontrollable dendrite growth strongly hamper the practical applications of rechargeable zinc (Zn) metal batteries (ZMBs). Herein, for first time, we demonstrate that trace amount chelate ligand additive can serve as a “molecular sieve‐like” interfacial barrier achieve highly efficient Zn plating/stripping. As verified by theoretical modeling experimental investigations, benzenesulfonic acid groups on molecular not only facilitates its solubility...

10.1002/ange.202312193 article EN Angewandte Chemie 2023-09-29

Abstract The crosstalk of transition metal ions between the oxide cathode and Zn anode restricts practical applications aqueous zinc‐ion batteries (ZIBs). Herein, we propose a decoupled electrolyte (DCE) consisting nonaqueous‐phase (N‐phase) anolyte an aqueous‐phase (A‐phase) catholyte to prevent Mn 2+ , thus extending lifespan MnO 2 ‐based ZIBs. Experimental measurements theoretical modelling verify that trimethyl phosphate (TMP) not only synergistically works with NH 4 Cl in N‐phase enable...

10.1002/ange.202421574 article EN Angewandte Chemie 2025-01-04
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