A5034535733- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Conducting polymers and applications
- Advanced Sensor and Energy Harvesting Materials
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Luminescence and Fluorescent Materials
- Photochromic and Fluorescence Chemistry
- Advanced NMR Techniques and Applications
- Tactile and Sensory Interactions
- Selenium in Biological Systems
- Diamond and Carbon-based Materials Research
- Advanced Vision and Imaging
- Quantum and electron transport phenomena
- Molecular Sensors and Ion Detection
- Organic Electronics and Photovoltaics
- Perovskite Materials and Applications
- Knowledge Management and Sharing
- Organic Light-Emitting Diodes Research
- Fullerene Chemistry and Applications
- Organic and Molecular Conductors Research
- Electron Spin Resonance Studies
- Advanced Materials and Mechanics
- Innovative Energy Harvesting Technologies
Guangxi University
2021-2025
Beijing National Laboratory for Molecular Sciences
2020-2025
Peking University
2020-2025
Yuhuangding Hospital
2025
Qingdao University
2025
Nanyang Technological University
2014-2024
BitPlus (United States)
2022-2024
Fuyang Second People's Hospital
2023-2024
King University
2024
State Key Laboratory of Rare Earth Materials Chemistry and Application
2020-2023
Abstract Bistable mechanical systems having two local minima of potential energy can rest in either the stable equilibrium states absence external loadings. A snap‐through action may occur under suitable stimuli and/or loading, during which such exhibit distinct properties from linear structures. Such kinds structures have been widely exploited for designing advanced functional a variety applications. Here, advances bistable are summarized novel systems, including actuators, harvesters,...
Abstract Electronic textiles (e‐textiles) that combine the wearing comfort of and functionality soft electronics are highly demanded in wearable applications. However, fabricating robust high‐performance stretchable e‐textiles with good abrasion resistance high‐resolution aesthetic patterns for high‐throughput manufacturing practical applications remains challenging. Herein, authors report a new multifunctional e‐textile fabricated via screen printing water‐based silver fractal dendrites...
Abstract Triboelectric nanogenerator (TENG) provides a new cost‐effective strategy to harvest water wave energy due the broad options of triboelectric materials and high efficiency in low‐frequency harvesting. Here, triboelectric–electromagnetic hybrid (TEHG) consisting soft ball‐based (SB‐TENG) an electromagnetic generator (EMG) is reported for harvesting energy. The balls are utilized as one layer increase contact area with copper electrodes. critical parameters that may affect performance...
The inspection, maintenance, and repair of pipeline tunnel infrastructure have motivated the increasing research in development suitable robots with high flexibility, good adaptability, large load capacity. Herein, a worm‐inspired soft robot that is capable operating performing variety tasks complicated pipeline/tunnel environment reported. tubular consists elongation pneumatic actuators (EPAs), radial expansion (REPAs), spatial bending actuator (SBPA). A series experiments are performed to...
Recently, stimuli-responsive materials have attracted great attention, while most of them respond to single or two stimuli. Thus, it is essential design multifunctional and develop their applications. The strategy that constructing high-dimensional coordination polymers facilitates the application scope a viologen-based photochromic system put forward confirmed for first time. Herein, novel multistimuli-responsive Zn-MOF with two-dimensional framework has been successfully designed...
Organic semiconductors with high-spin ground states are fascinating because they could enable fundamental understanding on the spin-related phenomenon in light element and provide opportunities for organic magnetic quantum materials. Although have been observed some quinoidal type small molecules or doped semiconductors, semiconducting polymers at their neutral state rarely reported. Here we report three high-mobility different spin states. We show that polymer building blocks...
Quinolone antibiotic residues, norfloxacin (NORF) and ciprofloxacin (CIP), have attracted more attention due to their frequent detection in surface water food field, which seriously threaten the health of animals humans. Rapid efficient NORF CIP is critical for environmental testing ecosystems. Herein, two novel isostructural viologen-functionalized Ln(III) complexes [Ln2L0.5(IPA)3]n (Ln = Eu, 1; Tb, 2; L N,N'-bis (2-carboxyethyl)-4,4'-bipyridridylium dichloride, H2IPA isophthalic acid) with...
The facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue their high Lewis basicity nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show performance one-pot sequential condensation-hydrogenation reaction.
Abstract Multifunctional metamaterials (MFMs) capable of energy harvesting and vibration control are particularly attractive for smart structures, wearable/biointegrated electronics, intelligent robotics. Here, a novel MFM based on triboelectric nanogenerators (TENGs), which can harvest environmental reduce simultaneously, is reported. The unit cells the consist local resonator, an integrated contact‐ separation mode TENG, spiral‐shaped connecting beams. A multiphysics theoretical model...
Stable carbon-based polyradicals exhibiting strong spin-spin coupling and slow depolarization processes are particularly attractive functional materials. A new molecular motif synthesized by a convenient method that allows the integration of stable, high-spin radicals to (hetero)aromatic polycycles has been developed, as illustrated non-Kekulé diradical showing triplet ground state with long persistency (τ1/2 ≈31 h) in air. Compared widely used 1,3-phenylene, newly designed...
Understanding metal-metal bonding involving f-block elements has been a challenging goal in chemistry. Here we report series of mixed-valence di-metallofullerenes, ThDy@C2n (2n = 72, 76, 78, and 80) ThY@C2n 72 78), which feature single electron actinide-lanthanide bonds, characterized by structural, spectroscopic computational methods. Crystallographic characterization unambiguously confirmed that Th Y or Dy are encapsulated inside variably sized fullerene carbon cages. The ESR study...
Abstract Molecular doping plays an important role in controlling the carrier concentration of organic semiconductors. However, introduction dopant counterions often results increased energetic disorder and traps due to molecular packing disruption Coulomb potential wells. To date, no general strategy has been proposed reduce counterion-induced structural disorder. Here, we demonstrate critical non-covalent interactions (NCIs) between polymers. Employing a computer-aided approach, identified...
Keratinases are valuable enzymes for converting feather keratin waste into bioactive products but often suffer from poor substrate specificity and low catalytic efficiency. This study reported the creating of a novel keratinase with targeted adherence specific degradation on keratins by fusing prepeptidase C-Terminal (PPC) domain. A PPC domain metalloprotease E423 specifically adsorbed hydrogen bonds hydrophobic interactions in time- temperature-dependent manner. Stepwise N-/C-terminal...
Head and neck squamous cell carcinoma (HNSCC) is among the most aggressive malignancies, underscoring need for early diagnosis to improve patient outcomes. Tumor-derived exosomes, which can be non-invasively obtained reflect metabolic state of tumors in real-time, are under increasing investigation their diagnostic potential. Herein we analyzed metabolite differences serum, tissues from patients with HNSCC identify potential biomarkers clinical relevance. Non-targeted metabolomics based on...
Zn(II) complexes based on salicylaldehyde hydrazone ligands have emerged as a promising class of stimuli-responsive luminescent materials. Herein, three complexes, namely, [Zn2(HL1)2(py)2]·H2O (1a), Zn2(HL1)2(py)2 (1b), and Zn2(HL2)2(py)2 (2), were synthesized by self-assembly with under solvothermal conditions. Complexes 1a 2 exhibit reversible mechanochromic luminescence (MCL) during grinding fuming processes due to the transformation between crystalline phase amorphous phase. In addition,...
We studied the potential protective effects of 1,25-dihydroxyvitamin D3 (1,25 VD3) supplementation on liver damage induced by a choline-deficient (CD) diet in rats, where impaired function leads to decreased 25-hydroxyvitamin levels, precursor for active 1,25 VD3. The CD reduced serum 25 VD3 levels and increased enzymes, indicative damage. Conversely, alleviated damage, reducing enzymes improving histopathological features characteristic non-alcoholic steatohepatitis (NASH). Oxidative stress...
Charge transfer (CT) and electron (ET) underlie the various applications of viologen compounds. However, CT ET in solids are still insufficiently understood difficult to control, which is challenging but fundamental design multifunctional materials. Our strategy attempt a delicate control by subjecting model compounds pressure. In this work, series viologens same cation with different anions show anion-dependent color piezo-/photochromism due ground-state stimuli-induced ET; ease solid-state...
High spin magnetic molecules are promising candidates for quantum information processing because they intrinsically have multiple sublevels storage and computational operations. However, due to their susceptibility the environment limitation from selection rule, arbitrary control of state a multilevel system on molecular electron basis has not been realized. Here we exploit photoexcited triplet C70 as qutrit. After was initialized by photoexcitation, prepared it into representative...