A5102000400- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Metal complexes synthesis and properties
- Polyoxometalates: Synthesis and Applications
- Covalent Organic Framework Applications
- Electrochemical Analysis and Applications
- Optical measurement and interference techniques
- Nanoparticle-Based Drug Delivery
- Nanoplatforms for cancer theranostics
- Luminescence and Fluorescent Materials
- Crystallography and molecular interactions
- Advanced Battery Technologies Research
- Tryptophan and brain disorders
- Conducting polymers and applications
- Electrocatalysts for Energy Conversion
- Electric Vehicles and Infrastructure
- Electrochemical sensors and biosensors
- Autophagy in Disease and Therapy
- Ferrocene Chemistry and Applications
- Cancer therapeutics and mechanisms
- Image Processing Techniques and Applications
- Inflammasome and immune disorders
- Photoacoustic and Ultrasonic Imaging
Shandong University of Traditional Chinese Medicine
2025
Affiliated Hospital of North Sichuan Medical College
2025
North Sichuan Medical University
2025
Henan Provincial People's Hospital
2022-2024
Zhengzhou University
2011-2024
SAIC Motor (China)
2024
Taiyuan University of Technology
2024
Hefei University of Technology
2007-2022
Wenzhou Medical University
2021
Tianjin University
2021
To systematically explore the effect of polynuclear complexes on photocatalytic degradation organic dyes, a series coordination containing CdII clusters, formulated as {[Cd3L2(H2O)5]·H2O}n (1), {[Cd3L2(hbmb)(H2O)2]·2.5H2O}n (2), {[Cd3L2(btbb)(H2O)2]·2EtOH·1.5H2O}n (3), and {[Cd6L4(bipy)2(H2O)6]·3H2O}n (4) (H3L = 3,4-bi(4-carboxyphenyl)-benzoic acid, hbmb 1,1′-(1,6-hexane)bis(2-methylbenzimidazole), btbb 1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene, 4,4′-bipy 4,4′-bipyridine), have...
Six interesting architectures with different structural and topological motifs have been obtained. <bold>3</bold>, <bold>4</bold> <bold>6</bold> exhibit good photocatalytic activities for methylene blue degradation.
Six fascinating coordination polymers (CPs) showed good photocatalytic activities for the degradation of methylene blue (MB).
It remains an unresolved challenge to achieve spatial and temporal monitoring of drug release from nanomedicines (NMs) in vivo, which is crucial importance disease treatment. To tackle this issue, we constructed core-satellite ICG/DOX@Gel-CuS NMs, consist gelatin (Gel) nanoparticles (NPs) with payloads near-infrared fluorochrome indocyanine green (ICG) chemo-drug doxorubicin (DOX) surrounding CuS NPs. The fluorescence ICG was initially shielded by satellite NPs within the intact NMs...
To seek the effect that condition of complexes has on manufacture biaryl compounds, seven Ni(II) complexes, namely, {[Ni(L)0.5(bpa)(H2O)]·2H2O}n (1), {[Ni2(L)(dpp)2(H2O)]·4H2O}n (2), {[Ni(L)0.5(pbmb)(H2O)]·H2O}n (3), {[Ni2(L)(bmp)2(H2O)]·7H2O}n (4), {[Ni(L)0.5(pbib)1.5]·2H2O}n (5), {[Ni2(L)(pbib)1.5]·3H2O}n (6), and [Ni(L)0.5(beb)2(H2O)]n (7) (bpa = 1,2-bis(4-pyridyl)ethane, dpp 1,3-di(4-pyridyl)propane, pbmb 1,1′-(1,3-propane)bis(2-methylbenzimidazole), bmp 1,5-bis(2-methylbenzimidazol)...
Eight entangled coordination complexes, formulated as [M(hbmb)0.5(o-phda)]n [M = Zn (1), Cd (2)], {[M(hbmb)(p-phda)]·H2O}n (3), (4)], [M(hbmb)0.5(oba)]n (5), (6)], {[M(hbmb)(sdba)]m}n Zn, m 2 (7); 1, (8)] (H2phda phenylenediacetic acid, H2oba 4,4′-oxybis(benzoic acid), H2sdba 4,4′-sulfonyldibenzoic have been prepared by hydrothermal reactions of the flexible ligand 1,1′-(1,6-hexane)bis-(2-methylbenzimidazole)) (hbmb) with metal ions in presence various dicarboxylate coligands. Isostructural...
By the solvothermal reactions of a [1,1′:3′,1″-terphenyl]-3,3″,5,5″-tetracarboxylic acid (H4tpta) with transition metal ions, three novel polymeric complexes, namely {[Ni2(tpta)(H2O)3]·H2O}n (1), {[Co4(tpta)2(4,4′-bpy)(H2O)3]·3H2O}n (2), and {[Mn2(tpta)(H2O)2]·2H2O}n (3), have been isolated. The heterometallic clusters these complexes are dimeric tetrameric, respectively. 1 is composed paddle wheel Ni(II) units to generate 2D structure. In 2 3, ions form tetrameric that extend via all...
To explore new 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY)-derived metal-organic frameworks (MOFs), we employed 2,6-dicarboxyl-1,3,5,7-tetramethyl-8-phenyl-4,4-difluoroboradiazaindacene (H2L) as a ligand to successfully synthesize five coordination polymers, namely, {[Zn2(L)2(bpp)]·2H2O·2EtOH}n (1), {[Cd2(L)2(bpp)]·2H2O·EtOH}n (2), {[Cd2(L)(bpe)3(NO3)2]·2H2O·DMF·EtOH}n (3), {[Cd(L)(bpe)0.5(DMF)(H2O)]}n (4), and {[Cd(L)(bpe)0.5]·1.5H2O·DMF}n (5) (bpp = 1,3-bi(4-pyridyl)propane, bpe...
By tuning the synthesis conditions, based on a conformation-sensitive ligand, 1,4-bis(1,2,4-triazole-1-methylene)-2,3,5,6-tetramethyl benzene (btmx) and Cu(NO3)2·3H2O/CuCl2·2H2O, we have obtained three Cu(ii) coordination polymers with diverse structures, namely, {[Cu(btmx)2(H2O)]·2NO3}n (), {[Cu(btmx)2(Cl)2]·5H2O}n () [Cu(btmx)(Cl)2]n (). Complex exhibits novel 2D → 3D interpenetrating structure point symbol of 6(3). features an irregular grid (4(4)·6(2)) topology. The complex is 1D double...
Acupuncture (Acu) has been clinically validated as an effective treatment for depression. However, the underlying mechanism of Acu treatment's antidepressant effect remains unclear. Methods: We investigate effects at LR3 point in mice subjected to chronic social defeat stress (CSDS). GCaMP6m-based fiber-optic photometry was employed ventral CA1 (vCA1) regions first time monitor Ca2+ transients vivo during behavioral testing. Electrophysiological recordings were used detect activity and...
Major depressive disorder (MDD) is a multifactorial involving genetic and environmental factors, with unclear pathogenesis. This study aims to explore the pathogenic pathway of MDD its relationship immune responses discover potential targets by bioinformatics methods. We first applied gene set variation analysis (GSVA) seven different infiltration algorithms GSE98793 dataset determine differences in signaling pathways, metabolic cell between patients healthy controls. Differentially...
Abstract In our continuing quest to develop a metal–organic framework (MOF)‐catalyzed tandem pyrrole acylation–Nazarov cyclization reaction with α,β‐unsaturated carboxylic acids for the synthesis of cyclopentenone[ b ]pyrroles, which are key intermediates in natural product (±)‐roseophilin, series template‐induced Zn‐based ( 1–3 ) metal‐organic frameworks (MOFs) have been solvothermally synthesized and characterized. Structural conversions from non‐porous MOF 1 porous 2 , back 3 arising...
Five coordination polymers containing transition metals (Mn, Co, Ni) and the organic ligand [1,1′:3′,1′′-terphenyl]-3,3′′,5,5′′-tetracarboxylic acid (H<sub>4</sub>TPTA) were synthesized characterized. Moreover, magnetism of complexes <bold>3–5</bold> is also discussed.
To systematically explore the impact of coordination complexes on synthesis 2-imidazoline and 1,4,5,6-tetrahydropyrimidine derivatives, five Co(II)/Mn(II)/Cu(II) architectures, formulated as {[Co(L)0.5(H2O)2]·CH3OH·H2O}n (1), {[Co(L)0.5(pbib)]·4H2O}n (2), [Mn(L)0.5(Hatz)0.5(H2O)]n (3), {[Cu(L)0.5(phen)2][Cu(L)0.5(phen)2]·0.5L·5H2O}n (4), {[Cu(L)0.5(2,2′-bpy)(H2O)]·H2O}n (5) (H4L = 5,5′-(hexane-1,6-diyl)-bis(oxy)diisophthalic acid, pbib 1,4-bis(imidazol-1-ylmethyl)benzene, Hatz...
Pigeons have a natural affinity for travel by flight. Researchers recently achieved modulation of pigeon locomotor behaviour intracortical microstimulation. However, there is lack research focused on the analysis microstimulations parameters in control Here, chronic microelectrode implantation technology employed to establish model evaluation effects flight modulation. Furthermore, three stimulation are compared (amplitude, frequency, and duty ratio) analyzed as how they their interactions...
Abstract Crystal violet lactone (CVL) is a classic halochromic dye which has been widely used as chromogenic reagent in thermochromic and piezochromic systems. In this work, very first example of CVL-based reversible photochromic compound was developed, showed distinct color change upon UV-visible light irradiation both solution solid matrix. Moreover, metal complex CVL salicylaldehyde hydrozone facilely synthesized, exhibiting properties with good fatigue resistance. It served promising...
Introducing organic molecules as coligands, several coordination polymers with new topologies and remarkable solvent resistance properties have been obtained.