A5045995865- Catalytic C–H Functionalization Methods
- Radical Photochemical Reactions
- Chemical Synthesis and Reactions
- Sulfur-Based Synthesis Techniques
- Catalytic Cross-Coupling Reactions
- Advanced Photocatalysis Techniques
- Safety Systems Engineering in Autonomy
- Real-Time Systems Scheduling
- Radiation Effects in Electronics
- Synthesis and Catalytic Reactions
- Ammonia Synthesis and Nitrogen Reduction
- Catalytic Alkyne Reactions
- Energy Harvesting in Wireless Networks
- Mobile Ad Hoc Networks
- Parallel Computing and Optimization Techniques
- Synthetic Organic Chemistry Methods
- Software Reliability and Analysis Research
- Energy Efficient Wireless Sensor Networks
- Flexible and Reconfigurable Manufacturing Systems
University of Amsterdam
2022-2024
TU Wien
2023
Friedrich-Alexander-Universität Erlangen-Nürnberg
2014-2015
The ability to construct C(sp3 )-C(sp3 ) bonds from easily accessible reagents is a crucial, yet challenging endeavor for synthetic organic chemists. Herein, we report the realization of such cross-coupling reaction, which combines N-sulfonyl hydrazones and )-H donors through diarylketone-enabled photocatalytic hydrogen atom transfer subsequent fragmentation obtained alkylated hydrazide. This mild metal-free protocol was employed prepare wide array alkyl-alkyl cross-coupled products tolerant...
The development of robust and reliable methods for the construction C(sp
Because of shrinking structure sizes and operating voltages, computing hardware exhibits an increasing susceptibility against transient faults: Issues previously only known from avionics systems, such as bit flips caused by cosmic radiation, nowadays also affect automotive other cost-sensitive "ground-level" control systems. For many software-based measures have been suggested to harden applications effects. However, all these assume that the underlying system works reliably in cases. We...
The development of robust and reliable methods for the construction C(sp2)–C(sp3) bonds is vital accessing an increased array structurally diverse scaffolds in drug discovery campaigns. While significant advances towards this goal have been achieved using metallaphotoredox chemistry, many these utilise photocatalysts based on precious-metals due to their efficient redox processes tuneable properties. However, cost, scarcity, toxicity metals, search suitable replacements should be a priority....
Despite intensive research in the field of mote-class Wireless Sensor Networks recent years, real-life deployments are still challenging and systems prone to failures. This can typically be attributed fragile hardware or misbehaving software. Issues caused by software, often induced inherent constraints resources, countered using simulations. However simulation results do not reflect those specific deployment. We suggest analyzing actual environment conditions a deployed network map them...
Abstract The development of robust and reliable methods for the construction C(sp 2 )−C(sp 3 ) bonds is vital accessing an increased array structurally diverse scaffolds in drug discovery campaigns. While significant advances towards this goal have been achieved using metallaphotoredox chemistry, many these utilise photocatalysts based on precious‐metals due to their efficient redox processes tuneable properties. However, cost, scarcity, toxicity metals, search suitable replacements should...
Toluene as a replacement for common N-benzylating agents, such benzyl bromide, can be an atom-efficient alternative reagent. Under nickel catalysis and mildly oxidative conditions, it is possible to activate toluene efficiently use directly the benzylation of different 2-aminopyridines. The transformation not restricted simple toluene, but also substituted derivatives give desired product in good yields. Effective cleavage pyridine moiety presented.
Abstract The ability to construct C(sp 3 )−C(sp ) bonds from easily accessible reagents is a crucial, yet challenging endeavor for synthetic organic chemists. Herein, we report the realization of such cross‐coupling reaction, which combines N‐ sulfonyl hydrazones and )−H donors through diarylketone‐enabled photocatalytic hydrogen atom transfer subsequent fragmentation obtained alkylated hydrazide. This mild metal‐free protocol was employed prepare wide array alkyl‐alkyl cross‐coupled...
A catalytic and highly regioselective method for the rearrangement of aryl-pentadienyl ethers into corresponding ortho - or para -alkylated products.
The ability to construct C(sp3)–C(sp3) bonds from easily accessible reagents is a crucial, yet challenging endeavor for synthetic organic chemists. Herein, we report the realization of such cross-coupling reaction, which combines N-sulfonyl hydrazones and C(sp3)–H donors through diarylketone-enabled photocatalytic Hydrogen Atom Transfer subsequent fragmentation obtained alkylated hydrazide. This mild metal-free protocol was employed prepare wide array alkyl-alkyl cross-coupled products...