A5052495835- Metal-Organic Frameworks: Synthesis and Applications
- Solar-Powered Water Purification Methods
- Covalent Organic Framework Applications
- Solar Thermal and Photovoltaic Systems
- Supramolecular Chemistry and Complexes
- Molecular Sensors and Ion Detection
- Conducting polymers and applications
- Luminescence and Fluorescent Materials
- Magnetism in coordination complexes
- Membrane Separation Technologies
- X-ray Diffraction in Crystallography
- Advanced Nanomaterials in Catalysis
- Supramolecular Self-Assembly in Materials
- Nanocluster Synthesis and Applications
- Crystallization and Solubility Studies
- Nanoplatforms for cancer theranostics
- Lanthanide and Transition Metal Complexes
- Advanced battery technologies research
- Supercapacitor Materials and Fabrication
- Advanced biosensing and bioanalysis techniques
- Analytical Chemistry and Sensors
- Cell Adhesion Molecules Research
- Advanced Photocatalysis Techniques
- Corrosion Behavior and Inhibition
- Phase Change Materials Research
Hunan University
2010-2025
Fujian Academy of Agricultural Sciences
2019-2025
Chengdu University of Traditional Chinese Medicine
2019-2025
Zhongkai University of Agriculture and Engineering
2025
Peking University
2021-2025
Peking University Cancer Hospital
2021-2025
Hunan University of Science and Technology
2025
Yancheng Institute of Technology
2022-2024
Hubei University
2019-2024
Wuhan University of Technology
2012-2024
Prodrug activation, by exogenously administered enzymes, for cancer therapy is an approach to achieve better selectivity and less systemic toxicity than conventional chemotherapy. However, the short half-lives of activating enzymes in bloodstream has limited its success. Demonstrated here that a tyrosinase-MOF nanoreactor activates prodrug paracetamol cells long-lasting manner. By generating reactive oxygen species (ROS) depleting glutathione (GSH), product enzymatic conversion toxic...
Abstract While microbial‐based therapy has been considered as an effective strategy for treating diseases such colon cancer, its safety remains the biggest challenge. Here, probiotics and prebiotics, which possess ideal biocompatibility are extensively used additives in food pharmaceutical products, combined to construct a safe microbiota‐modulating material. Through host–guest chemistry between commercial Clostridium butyricum chemically modified prebiotic dextran, prebiotics‐encapsulated...
Crystal engineering of metal-organic frameworks (MOFs) has allowed the construction complex structures at atomic precision, but yet to reach same level sophistication as organic synthesis. The synthesis MOFs with multiple and/or inorganic components is ultimately limited by lack control over framework assembly in one-pot reactions. Herein, we demonstrate that multi-component unprecedented complexity can be constructed a predictable and stepwise manner under simple kinetic guidance, which...
Delivering sufficient water to the evaporation surface/interface is one of most widely adopted strategies overcome salt accumulation in solar-driven interfacial desalination. However, transport and heat conduction loss are positively correlated, resulting trade-off between thermal localization resistance. Herein, a 3D hydrogel evaporator with vertical radiant vessels prepared surmount long-standing trade-off, thereby achieving high-rate stable solar desalination high-salinity. Experiments...
Functionalizing porous materials with capping agents generates hybrid enhanced properties, while the challenge is how to improve selectivity and maintain porosity of parent framework. Herein, we developed a "Cage-on-MOF" strategy tune recognition catalytic properties MOFs without impairing their porosity. Two types coordination cages (PCCs) opposite charges containing secondary binding groups were coordinatively functionalize two distinct MOFs, namely MOF@PCC nanocomposites. We demonstrated...
Two-dimensional conductive metal–organic frameworks (2D-cMOFs) are a class of 2D layered MOFs with excellent electrical conductivity and other electronic properties. In recent years, their porous structure dense active sites have been widely used in electrocatalysis electrochemical sensing. The large electron delocalization domains generated by an extended π-conjugated framework through the covalent bonding between metal organic ligand endow them unique high conductivity. Yet despite few...
In this paper, we report a quick approach to self-assemble three-dimensional (3D) spongiform nanofiber stacks via electrospinning, which usually fabricates 2D non-woven fiber mats. Through controlling experimental conditions, cone-like polystyrene can be self-assembled on aluminum foil within 30 min. The are able reach height of more than 10 cm. Moreover, conversion between the 3D stack and thin film controlled. formation mechanism influence conditions have also been explored. may promising...
Electrochemical energy storage and conversion ( EESC ) technology is key to the sustainable development of human society. As an abundant renewable source, biomass has recently shown widespread applications in , achieving both low environmental impact high performances. This article provides overview perspectives on various types biomass‐derived materials, their preparation, role desired features, performances limitations, future research efforts.
Solar-driven water evaporation is deemed to be a green and sustainable strategy cope with the global freshwater crisis. However, effective achieve high yield in practical application significant but usually neglected. Here, molybdenum carbide/carbon-based chitosan hydrogel (MoCC-CH) designed not only as solar absorber also accelerator. The proportion of matrix tunable acquire low-tortuosity channels for facilitating solar-driven evaporation. Thus, rate MoCC-CH up ∼2.19 kg m–2 h–1,...
Effective interventions to improve prognosis in metastatic esophagogastric cancer (EGC) are urgently needed. We assessed the effect of early integration interdisciplinary supportive care for patients with EGC on overall survival (OS).
Solar evaporation has emerged as a facile and attractive technology for clean water production, desalination, organic solvent purification by virtue of abundant solar energy. However, developing high-performance, environment friendly, scalable evaporator remains significant challenge. Herein, one-step, low-cost, easy-to-manufacture synthesis three-dimensional macroporous steam generator is reported based on polypyrrole coated natural latex (PPy-NL) foam, offering sustainable solution to the...
It is extremely difficult to anticipate the structure and stereochemistry of a complex, particularly when ligand flexible metal node adopts diverse coordination numbers. When trivalent lanthanides (LnIII) enantiopure amino acid ligands are utilized as building blocks, self-assembly sometimes yields rare chiral polynuclear structures. In this study, an carboxyl-functionalized acid-based with C3 symmetry reacts lanthanum cations give homochiral porous cage, (Δ/Λ)12-PCC-57. The dodecanuclear...
Abstract Mimicking the active site and substrate binding cavity of enzyme to achieve specificity in catalytic reactions is an essential challenge. Herein, porous coordination cages (PCCs) with intrinsic cavities tunable metal centers have proved regulation reactive oxygen species (ROS) generating pathways as evidenced by multiple photo‐induced oxidations. Remarkably, presence Zn 4 ‐μ ‐O center, PCC converted dioxygen molecules from triplet singlet excitons, whereas Ni center promoted...
One of the hallmarks multicomponent metal-organic frameworks (MOFs) is to finely tune their active centers achieve product selectivity. In particular, obtaining bimetallic MOF hollow structures with precisely tailored redox under same topology still challenging despite a recent surge such efforts. Herein, we present an engineering strategy named "cluster labilization" generate hierarchically porous composites and tunable centers. By partially replacing zirconium cerium in hexanuclear...