A5022646366- Metal-Organic Frameworks: Synthesis and Applications
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Covalent Organic Framework Applications
- Rabies epidemiology and control
- Nanoplatforms for cancer theranostics
- Magnetism in coordination complexes
- Metal complexes synthesis and properties
- Advanced Photocatalysis Techniques
- Virus-based gene therapy research
- Viral Infections and Outbreaks Research
- Synthesis and biological activity
- Membrane Separation and Gas Transport
- Luminescence and Fluorescent Materials
- RNA Interference and Gene Delivery
- Molecular Sensors and Ion Detection
- Supramolecular Self-Assembly in Materials
- Synthesis and Characterization of Heterocyclic Compounds
- Thermochemical Biomass Conversion Processes
- Atmospheric chemistry and aerosols
- Advanced biosensing and bioanalysis techniques
- Nanoparticle-Based Drug Delivery
- Supramolecular Chemistry and Complexes
- Catalytic Cross-Coupling Reactions
- Crystallography and molecular interactions
South China Normal University
2023-2025
Shaanxi University of Technology
2020-2024
Jilin University
2022-2024
National University of Singapore
2022-2024
East China University of Technology
2017-2024
Shanxi University
2022-2024
Nanchang University
2021-2023
Shanghai Jiao Tong University
1999-2023
Xidian University
2023
Northwest A&F University
2019-2023
In this work, we innovatively assembled two types of traditional photosensitizers, that is pyridine ruthenium/ferrum (Ru(bpy)32+ /Fe(bpy)32+ ) and porphyrin/metalloporphyrin complex (2HPor/ZnPor) by covalent linkage to get a series dual photosensitizer-based three-dimensional metal-covalent organic frameworks (3D MCOFs), which behaved strong visible light-absorbing ability, efficient electron transfer suitable band gap for highly photocatalytic hydrogen (H2 evolution. Rubpy-ZnPor COF...
The high local electron density and efficient charge carrier separation are two important factors to affect photocatalytic activity, especially for the CO2 photoreduction reaction. However, systematic studies on structure-functional relationship regarding above based precisely structure model rarely reported. Herein, as a proof-of-concept, we developed new strategy evaluation of by controlling relative electron-deficient (ED) electron-rich (ER) intensity monomer at molecular level three...
In recent years, significant progress has been achieved in the field of three-dimensional covalent organic frameworks (3D COFs). However, there is still a great challenge to use flexible building units synthesize high-connectivity 3D COFs. this work, we showed that [6 + 3] COFs could be constructed by inducing highly planar blocks from C3 antitriangular prismed blocks. Herein, two with spn topology based on cyclotriphosphazene were and denoted as TAA/TAB-CTP-COF, their redox ability...
Among the few available mRNA delivery vehicles, lipid nanoparticles (LNPs) are most clinically advanced but they require cumbersome four components and suffer from inflammation-related side effects that should be minimized for safety. Yet, a certain level of proinflammatory responses innate immune activation required to evoke T-cell immunity cancer vaccination. To address these issues develop potent yet low-inflammatory vaccine vectors, series alternating copolymers "PHTA" featured with...
Electrocatalytic CO2 reduction (ECR) coupled with organic oxidation is a promising strategy to produce high value-added chemicals and improve energy efficiency. However, achieving the efficient redox coupling reaction still challenging due lack of suitable electrocatalysts. Herein, we designed two bifunctional polyimides-linked covalent frameworks (PI-COFs) through assembling phthalocyanine (Pc) porphyrin (Por) by non-toxic hydrothermal methods in pure water realize above catalytic...
The connectivity (valency) of building blocks for constructing 3D covalent organic frameworks (COFs) has long been limited to 4, 6, 8, and 12. Developing a higher remains great challenge in the field COF structural design. Herein, this work reports hierarchical expansion strategy making 16-connected construct COFs with sqc topology. [16 + 2] construction achieved by condensation between carbazolyl dicyanobenzene-based block (CzTPN) linear diamino linkers (BD or Bpy) affords two (named CzBD...
mRNA therapeutics hold great promise for disease treatment, yet a key challenge lies in achieving site-specific delivery to maximize therapeutic efficacy while minimizing off-target side effects. This viewpoint delves into multiple complementary targeting strategies achieve precise delivery, covering topics of administration routes, passive targeting, and active targeting. It highlights the critical importance rationally designed nanocarriers obtaining desired effects accelerating clinical...
Polymer-inorganic hybrid Janus nanoparticles (PI-JNPs) have attracted extensive attention due to their special structures and functions. However, achieving the synergistic enhancement of photochemical activity between polymer inorganic moieties in PI-JNPs remains challenging. Herein, construction a novel Au-porphyrin polymersome (J-AuPPS) heterostructure by facile one-step photocatalytic synthesis is reported. The near-field (NFE) effect porphyrin (PPS) Au J-AuPPS achieved enhance its...
ConspectusDevelopment of multifunctional nanoparticles (NPs) with desired properties is a significant topic in the field nanotechnology and has been anticipated to revolutionize cancer diagnosis treatment modalities. The surface character one most important parameters NPs that can directly affect their vivo fate, bioavailability, final theranostic outcomes thus should be carefully tuned maximize effects while minimizing unwanted side effects. Surface engineered have utilized various...
A series of novel N-heterocyclic carbene–palladium(II)–4,5-dihydrooxazole (NHC-PdII-Ox) complexes 3 were successfully synthesized from commercially available imidazolium salts 1, PdCl2, and 4,5-dihydrooxazoles 2 in a one-step process, these showed efficient catalytic activity toward the amination aryl chlorides. Both secondary primary amines tolerated under same reaction conditions. Under optimal conditions, expected coupling products obtained moderate to high yields.
Research on metal-free catalytic synthesis of polycaprolactone (PCL) is fueled by the many practical needs for biodegradable and biocompatible materials. In this regard, pursuit effective economical catalysts as well precise control over polymerization has become main challenge. Herein, we report a living cationic ring-opening ε-caprolactone catalyzed safe, inexpensive, Lewis acid trityl tetrafluoroborate. The initiated alcohol or water, which corroborated presence initiator segments at...
In this work, a series of new crystalline three‐dimensional covalent organic frameworks (3D COFs) based on [8+4] construction was designed and successfully realized efficient photocatalytic acetylene (C2H2) hydrogenation to ethylene (C2H4). By regulating the hydrogen‐localization transfer effect in these 3D COFs，the Cz‐Co‐COF‐H containing cobalt glyoximate active centers exhibited excellent C2H2‐to‐C2H4 performance, with an average C2H4 yield 1755.33 μmol g‐1 h‐1 pure C2H2, also showed near...
In this work, a series of new crystalline three‐dimensional covalent organic frameworks (3D COFs) based on [8+4] construction was designed and successfully realized efficient photocatalytic acetylene (C2H2) hydrogenation to ethylene (C2H4). By regulating the hydrogen‐localization transfer effect in these 3D COFs，the Cz‐Co‐COF‐H containing cobalt glyoximate active centers exhibited excellent C2H2‐to‐C2H4 performance, with an average C2H4 yield 1755.33 μmol g‐1 h‐1 pure C2H2, also showed near...