A5065415013- Electrocatalysts for Energy Conversion
- 2D Materials and Applications
- Advanced Chemical Physics Studies
- Supercapacitor Materials and Fabrication
- Advancements in Battery Materials
- Advanced battery technologies research
- Atmospheric chemistry and aerosols
- Graphene research and applications
- Atmospheric Ozone and Climate
- Chemical Reactions and Mechanisms
- Perovskite Materials and Applications
- Advanced Photocatalysis Techniques
- Synthesis and characterization of novel inorganic/organometallic compounds
- CO2 Reduction Techniques and Catalysts
- Advanced Thermoelectric Materials and Devices
- Transition Metal Oxide Nanomaterials
- Copper-based nanomaterials and applications
- Fuel Cells and Related Materials
- Crystallization and Solubility Studies
- RNA modifications and cancer
- ZnO doping and properties
- X-ray Diffraction in Crystallography
- Photochemistry and Electron Transfer Studies
- Molecular Spectroscopy and Structure
- Spectroscopy and Quantum Chemical Studies
Central South University
2021-2025
UNSW Sydney
2021-2025
Hunan Xiangdian Test Research Institute (China)
2025
Xiangya Hospital Central South University
2025
China University of Petroleum, East China
2025
Fudan University
2022-2024
Jiangsu University
2023-2024
Shanghai Guanghua Hospital of Integrated Traditional Chinese and Western Medicine
2024
Wuhan University of Technology
2024
National University of Defense Technology
2023-2024
Abstract Platinum is the most efficient catalyst for hydrogen evolution reaction in acidic conditions, but its widespread use has been impeded by scarcity and high cost. Herein, Pt atomic clusters (Pt ACs) containing Pt-O-Pt units were prepared using Co/N co-doped carbon (CoNC) as support. ACs are anchored to single Co atoms on CoNC forming strong interactions. Pt-ACs/CoNC exhibits only 24 mV overpotential at 10 mA cm −2 a mass activity of 28.6 A mg −1 50 mV, which more than 6 times higher...
Abstract A considerable amount of platinum (Pt) is required to ensure an adequate rate for the oxygen reduction reaction (ORR) in fuel cells and metal‐air batteries. Thus, implementation atomic Pt catalysts holds promise minimizing content. In this contribution, sites with nitrogen (N) phosphorus (P) co‐coordination on a carbon matrix (PtNPC) are conceptually predicted experimentally developed alter d‐band center Pt, thereby promoting intrinsic ORR activity. PtNPC record‐low content (≈0.026...
Single-atom catalysts (SACs) have shown potential for achieving an efficient electrochemical CO2 reduction reaction (CO2RR) despite challenges in their synthesis. Here, Ag2S/Ag nanowires provide initial anchoring sites Cu SACs (Cu/Ag2S/Ag), then Cu/Ag(S) was synthesized by treatment resulting complete sulfur removal, i.e., on a defective Ag surface. The CO2RR Faradaic efficiency (FECO2RR) of reaches 93.0% at partial current density (jCO2RR) 2.9 mA/cm2 under -1.0 V vs RHE, which outperforms...
Abstract Relieving inflammation via scavenging toxic reactive oxygen species (ROS) during the acute phase of spinal cord injury (SCI) proves to be an effective strategy mitigate secondary and improve recovery motor function. However, commonly used corticosteroid anti‐inflammatory drugs show adverse side effects which may induce increased risk wound infection. Fortunately, hydrogen (H 2 ), featuring selective antioxidant performance, easy penetrability, excellent biosafety, is being...
The photovoltaic-alkaline water (PV-AW) electrolysis system offers an appealing approach for large-scale green hydrogen generation. However, current PV-AW systems suffer from low solar-to-hydrogen (STH) conversion efficiencies (e.g., <20%) at practical densities >100 mA cm −2 ), rendering the produced H 2 not economical. Here, we designed and developed a highly efficient that mainly consists of customized, state-of-the-art AW electrolyzer concentrator photovoltaic (CPV) receiver....
Abstract Morphology significantly affects material's electronic, catalytic, and magnetic properties, especially for 2D crystals. Abundant achievements have been made in the morphology engineering of high‐symmetry materials, but emerging low‐symmetry ones, such as ReS 2 , both control technique comprehension are lacking. Here, lateral shape vertical thickness by tailoring growth temperature substrate symmetry using chemical vapor deposition, is reported. The increase induces an...
At present, the evaluation perspective of gel plugging agent assessment method is incomprehensive, due to which experimental results deviate from field data. By analyzing current indoor methods and factors controlling sealing capability agents, an device for evaluating blocking effect oilfield agents has been designed. In contrast traditional methods, proposed approach offers advantages such as simple operation, rapid experimentation, accurate results. The show that gels selected using...
Background Cancer, influenced by genetics and the environment, involves anoikis, a cell death mechanism upon extracellular matrix detachment crucial for metastasis. Understanding this relationship is key therapy. We analyze cancer anoikis trends using bibliometrics.
Transition metal dichalcogenide based 2D/2D or 2D/3D van der Waals heterostructures exhibit superior properties for high-performance electronics, tunneling transistors, and catalysts. Here, we report on the fabrication of high quality MoS2/MoO2 with an atomic clean interface by one-step chemical vapor deposition. Optical microscopy, force Raman spectroscopy, scanning electron energy dispersive spectroscopy measurements reveal high-quality as-grown samples specific epitaxial relationship...
Abstract The van der Waals (vdW) interface provides two important degrees of freedom—twist and slip—to tune interlayer structures inspire unique physics. However, constructing diversified high‐quality slip stackings (i.e., lattice orientations between layers are parallel with only sliding) is more challenging than twisted due to angstrom‐scale structural discrepancies different stackings, sparsity thermodynamically stable candidates insufficient mechanism understanding. Here, using...
Group-VA two-dimensional layered materials in a puckered honeycomb structure exhibit strong in-plane anisotropy and have emerged as new platforms for novel devices. Here, we report on systematic Raman investigations exfoliated b-As flakes the Ag1 Ag2 polarization dependence their symmetry, excitation wavelength, flake thickness. The intensity maximums of both phonons are corrected armchair direction under 633 nm regardless thickness upon considering optical birefringence effects interference...
Cobalt-based sulfides with variable valence states and unique physical chemical properties have shown great potential as oxygen evolution reaction (OER) catalysts for electrochemical water-splitting reactions. However, poor morphological characteristics a small specific surface area limit its further application. Here, hexagonal single-crystal two-dimensional (2D) CoS nanosheets different thicknesses are successfully prepared by an atmospheric-pressure vapor deposition method. Because of the...
Imidogen (NH) is the simplest nitrogen hydride that plays an important role in combustion and interstellar chemistry, its combination with H2O prototypical amidation reaction of O-H bonds involving a nitrene intermediate. Herein, we report observation elusive water complex NH, prereaction associated solid N2 matrix at 10 K. The hydrogen-bonded structure NH···OH2 (versus HN···HOH) confirmed via IR spectroscopy comprehensive isotope labeling (D, 18O, 15N) quantum chemical calculations...
Layered Palladium ditelluride (PdTe 2 ) is an interesting noble‐transition‐metal dichalcogenide with high electrical and thermal conductivity, exhibiting superconductivity a type‐II Dirac semimetallic phase due to the increased electron–phonon (e–ph) coupling. Herein, e–ph coupling constant λ of E g (in‐plane) A 1g (out‐of‐plane) modes in exfoliated PdTe nanoflakes via temperature‐dependent Raman spectroscopy within temperature range from 80 580 K determined. Both mode Gaussian line shape...
Interfacial interactions, including interfacial charge transfer and strain, play important roles in the applications of 2D layered materials. Recently, MoO 2 have been widely used as precursors or substrates for growth high‐quality MoS . Herein, photoluminescence (PL) Raman spectroscopy are to investigate dependence epitaxial monolayer PL properties on nanoflakes different thicknesses c‐sapphire. On all nanoflakes, trion exciton disappears due from The neutral exhibits a ≈60 meV redshift...
Massive spent lithium-ion batteries will peak soon, creating energy, environment, economy, and technology challenges key metal supply burdens in all resource-relevant industries. Here, we develop a universal energy-effective, sustainable, easily modularized recycling strategy to retrieve transition metals lithium from cathodes (LiCoO2 LiNi0.8Co0.1Mn0.1O2) via high-capacity cooperative leaching process. The with acid-free sustainable agents is enabled by strong coordination using green deep...
Abstract Diatomic molecules phosphorus monoxide (PO) and mononitride (PN) are the main reservoirs of gas-phase in interstellar circumstellar environments, indicating possibility forming new phosphorus-bearing through reactions with other species. To explore astrochemistry PO PN, simple [O, C, N, P] [2O, were generated gas phase isolated cryogenic matrices for characterization matrix-isolation IR UV/vis spectroscopy combination calculations at CCSD(T)-F12a/VTZ-F12 level theory. In an inert...