A5100329612- Metal-Organic Frameworks: Synthesis and Applications
- Radioactive element chemistry and processing
- Crystallography and molecular interactions
- Chemical Synthesis and Characterization
- Catalytic C–H Functionalization Methods
- Crystal structures of chemical compounds
- Covalent Organic Framework Applications
- Polyoxometalates: Synthesis and Applications
- Nanoplatforms for cancer theranostics
- Advanced Nanomaterials in Catalysis
- Geochemistry and Elemental Analysis
- Coconut Research and Applications
- Advanced Photocatalysis Techniques
- Synthesis and biological activity
- Supramolecular Chemistry and Complexes
- Zeolite Catalysis and Synthesis
- Lanthanide and Transition Metal Complexes
- Molecular Sensors and Ion Detection
- Magnetism in coordination complexes
- Metal complexes synthesis and properties
- Synthesis and Characterization of Heterocyclic Compounds
- Catalytic Alkyne Reactions
- Radical Photochemical Reactions
- Enzyme function and inhibition
- Quinazolinone synthesis and applications
Northeast Normal University
2011-2024
Southwest University
2024
Northeastern University
2024
Heilongjiang Center for Tuberculosis Control and Prevention
2024
Liaoning University of Technology
2024
Luoyang Normal University
2022-2023
Henan Agricultural University
2021-2023
China West Normal University
2023
Ministry of Education of the People's Republic of China
2023
Northwest University
2023
A variety of organometallic supramolecular architectures have been constructed over the past decades and their properties were also explored via different strategies. However, synthesis metalla-Russian doll is still a fascinating challenge. Herein, series new coordination complexes, including doll, metalla[2]catenanes, metallarectangles, synthesized by using meticulously selected Cp*Rh (Cp* = η5-C5Me5) building units (E1, E2, E3) three rigid anthracylpyridine ligands (L1, L2, L3)...
A photo-induced copper-catalyzed nitrogen extraction/SO 2 insertion of aryltriazenes for the controllable synthesis aryl sulfonamides and diaryl sulfones has been established. Under purple LED irradiation, using CuI as catalyst and...
A general and facile catalytic asymmetric protocol for the construction of enantioenriched spiro gem-diamines through [3+3] annulation α,β-unsaturated N-sulfonyl ketimines 3-aminobenzofurans has been accomplished under catalysis of...
The efficient and divergent construction of two types valuable N-heterocycle is achieved easily, with the first example generation α-oxo copper carbenes via copper-catalyzed oxidation non-polarized alkynes.
Abstract General access to highly valuable seven-membered rings via Büchner-type reaction remains a formidable challenge. Here we report Cu-catalyzed intermolecular oxidation of alkynes using N-oxides as oxidants, which enables expedient preparation benzo[6,7]azepino[2,3-b]quinolines and pyridine-based diones. Importantly, in contrast the well-established gold-catalyzed alkyne oxidation, dissociated pyridine or quinoline partner could be further utilized construct N-heterocycles this system...
Magnetite is often associated with U(VI) in uranium (U) contaminated soils. In -situ reduction of magnetite has been demonstrated as a cost-effective method to remedy U pollution the subsurface. While, results indicate that surface passivation may significantly affect removal efficiency U(VI). Hence, mixed culture metal-reducing bacteria, which consisted different species genera Bacillus, Clostridium XIV, Ochrobactrum, and XI enriched from rice soil, was employed remove passive film on...
Efficient charge transfer has always been a challenge in heterogeneous MOF-based photoredox catalysis due to the poor electrical conductivity of MOF photocatalyst, toilless electron–hole recombination, and uncontrollable host–guest interactions. Herein, propeller-like tris(3′-carboxybiphenyl)amine (H3TCBA) ligand was synthesized fabricate 3D Zn3O cluster-based Zn(II)-MOF Zn3(TCBA)2(μ3-H2O)H2O (Zn-TCBA), which applied efficient photoreductive H2 evolution photooxidative aerobic...
The controlled synthesis of organometallic supramolecular macrocycles cages remains interesting and challenging work in the field chemistry. Here, two tetranuclear rectangular an octuclear cage were designed synthesized utilizing a rigid functionalized pillar linker, 2,6-bis(pyridin-4-yl)-1,7-dihydrobenzo [1,2-d:4,5-d′]diimidazole (BBI4PY) based on three half-sandwich rhodium building blocks bearing different sizes. X-ray crystallography combination with 1H NMR spectroscopy elucidated that...
The synthesis of 3-methoxy-benzanthrones was achieved in two steps by Suzuki–Miyaura coupling and BBr 3 -promoted Friedel–Crafts acylation under mild conditions with an overall yield 17–74% tolerance toward various substrates using commercially available reagents.