A5008301880- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Luminescence and Fluorescent Materials
- Advanced Chemical Physics Studies
- Perovskite Materials and Applications
- Conducting polymers and applications
- Molecular Sensors and Ion Detection
- Synthesis and Properties of Aromatic Compounds
- Advanced Photocatalysis Techniques
- Organic Electronics and Photovoltaics
- Nanoplatforms for cancer theranostics
- Molecular Junctions and Nanostructures
- Metal-Organic Frameworks: Synthesis and Applications
- Quantum Dots Synthesis And Properties
- Catalytic C–H Functionalization Methods
- Ammonia Synthesis and Nitrogen Reduction
- Supramolecular Chemistry and Complexes
- Advanced battery technologies research
- Electrochemical Analysis and Applications
- Spectroscopy and Quantum Chemical Studies
- Analytical Chemistry and Sensors
- Radical Photochemical Reactions
- Oxidative Organic Chemistry Reactions
- Iron oxide chemistry and applications
- Pesticide and Herbicide Environmental Studies
Hangzhou Normal University
2020-2025
Dalian Medical University
2022
Second Affiliated Hospital of Dalian Medical University
2022
Nanjing University
2012-2021
Affiliated Hospital of Hangzhou Normal University
2021
University of Arkansas at Fayetteville
2016-2019
KU Leuven
1994-1996
Rega Institute for Medical Research
1994
Abstract The newly emerged aqueous Zn–organic batteries are attracting extensive attention as a promising candidate for energy storage. However, most of them suffer from the unstable and/or soluble nature organic molecules, showing limited cycle life (≤3000 cycles) that is far away requirement (10 000 grid‐scale Here, new zinc battery proposed by using sulfur heterocyclic quinone dibenzo[b,i]thianthrene‐5,7,12,14‐tetraone (DTT) cathode. cell shows high reversible capacity 210.9 mAh g DTT −1...
Zn–organic batteries are attracting extensive attention, but their energy density is limited by the low capacity (<400 mAh g–1) and potential (<1 V vs Zn/Zn2+) of organic cathodes. Herein, we propose a long-life high-rate battery that includes poly(1,5-naphthalenediamine) cathode Zn anode in an alkaline electrolyte, where reaction based on coordination between K+ C═N group (i.e., C═N/C–N–K conversion). Interestingly, find discharged can recover to its initial state quickly with presence O2,...
Abstract The p‐type or n‐type redox reactions of organics are being used as the reversible electrodes to build next‐generation rechargeable batteries with sustainable and tunable characteristics. However, that store cations generally exhibit low potential (<0.8 V vs. Zn/Zn 2+ ), while anions suffer from limited capacity (<100 mAh g −1 ). Herein, we demonstrate bis(phenylamino)phenothiazin‐5‐ium iodide (PTD‐1) containing both moieties exhibits a hybrid charge storage mechanism (n/p‐type...
Aryl-substituted bicyclo[1.1.1]pentane (BCP-aryl) derivatives represent the most important bioisosteres of biaryl scaffolds and widely exist in numerous complex pharmaceutical molecules. The current synthetic method limitations using only tertiary radical precursors, prefunctionalized heteroarenes, toxic transition metals, expensive photocatalysts make it urgent to develop a more simple practical protocol. To confront enrich Minisci-type chemistry, herein, we disclose photocatalytic...
We present the first D–A–D aza-BODIPY scaffold to construct CT-coupled J-aggregates, which show promising results for highly efficient phototherapy.
A visible light-mediated direct C–H arylation of quinoxalin-2(1<italic>H</italic>)-ones with aryl acyl peroxides has been developed.
This study describes a novel aqueous reaction for the synthesis of (<italic>Z</italic>)-enaminones through combination heterogeneous catalysis and photocatalysis.
Proteolysis Targeting Chimeras (PROTACs) represent a promising therapeutic modality to address undruggable and resistant issues in drug discovery. However, potential on-target toxicity remains clinically challenging. We developed generalized caging strategy synthesize series of stimuli-responsive PROTACs (sr-PROTACs) with diverse molecular blocks bearing robust cleavable linkers, presenting "turn on" features manipulating protein degradation. By leveraging pathological cues, such as elevated...
Our recent developments on cluster-in-molecule (CIM) local correlation method are reviewed in this paper. In the CIM method, energy of a large system can be approximately obtained from electron calculations series clusters, each which contains subset occupied and virtual localised molecular orbitals certain region. The is linear scaling its inherent parallelisation allows very systems to feasible at ordinary workstations. illustrative applications, approach applied investigate conformational...
The cluster-in-molecule (CIM) local correlation approach with an accurate distant pair energy correction is presented. For large systems, the inclusion of energies essential for prediction absolute and relative energies. Here, we propose a simple efficient scheme evaluating CIM approaches. corrections can be readily extracted from electron calculations clusters almost no additional effort. Benchmark show that improved recover more than 99.94% calculated by parent method. By combining...
Abstract Donor−acceptor molecules with hybridized local and charge transfer (HLCT) excited state have been demonstrated to be an efficient strategy for achieving high performance electroluminescence by harvesting both singlet triplet excitons. In this study, a series of bipolar D−A twisted bridge are synthesized these chromophores exhibit good thermal, morphological photophysical properties, electrochemical stabilities as well HLCT features. Excellent deep‐blue (EL) performances achieved...
Abstract Near‐infrared (NIR) chiroptical response has been less explored because it is challenging to achieve both chirality and NIR absorption/emission. Herein, we describe the design of heterohelicene‐type β‐isoindigo‐based boron‐dipyrromethene (BODIPY) analogs (β‐IBs), which shift absorption peak 800 nm produce significant Cotton effects (127.8 M −1 cm ) absorbance dissymmetry factors (| g abs | = 3.5 × 10 −3 ). The luminescence factor ( lum circularly polarized (CPL) brightness B CPL up...
Abstract Although natural dual‐ion exchangers are indispensable for bio‐organic functions, developing their artificial counterparts remains nearly unexplored. Herein, this work proposes a novel light‐controlled K + /Na ‐transport‐exchanger TE12 , realizing an unprecedented reversible switch between ‐ and Na ‐transmembrane transport by changing its mechanism (channel carrier). The conformational transformation of the azobenzene moiety in essentially induces this. selectivity ‐channel...
The aging of precursor solutions is the major stumbling block for commercialization perovskite solar cells (PSCs). Herein, first time we used state-of-the-art in situ liquid time-of-flight secondary ion mass spectrometry to molecularly explore solution chemistry. We identified that methylammonium and formamidinium cations I- anion are motivators Further, introduced two kinds Lewis bases, triethyl phosphate (TP) ethyl ethanesulfonate (EE), as new additives unraveled both them can protect...
It is essential to create organic compounds that exhibit circularly polarized luminescence (CPL) in the near-infrared (NIR) range. Helicene-type emitters possess appealing chiroptical features, however, such NIR molecules are scarce due a paucity of synthetic strategies. Herein, we developed series helical β-isoindigo-based B-O-B bridged aza-BODIPY analogs were synthesized conveniently. The reaction diimino-β-isoindigo with heteroaromatic amine produced restricted ligand cavity, which...
The first photothermal molecular platform, boron isoindoline-1-one-pyridyl dyes, viz . BOINPY, was rationally designed in high yields by a one-step continuous process.
The generalized energy-based fragmentation (GEBF) method has been applied to investigate relative energies of large water clusters (H2O)n (n = 32, 64) with the coupled-cluster singles and doubles noniterative triple excitations (CCSD(T)) second-order Møller-Plesset perturbation theory (MP2) at complete basis set (CBS) limit. Here are chosen be representative structures sampled from molecular dynamics (MD) simulations liquid water. Our calculations show that GEBF is capable providing highly...
Abstract Chiral α‐amino acids play critical roles in the metabolic process nearly all life forms. So far, chiral recognition of has mainly focused on determination l / d enantiomers. Herein, selection planar conformations between water‐soluble pillar[5]arene WP5 and pillar[6]arene WP6 was observed due to α‐side chain or ethyl ester moieties ‐α‐amino acid hydrochlorides binding with , respectively. Therefore, were recognized by observing induced CD signal its inversion. This is a rare example...
An environmentally friendly and practical protocol for the visible-light-triggered regioselective radical cascade sulfonylation/cyclization of unactivated alkenes towards synthesis polycyclic benzimidazoles containing sulfone group has been developed.
The salt metathesis reaction involving a diamine-based antimony chloride precursor with sodium arsaethynolate in the presence of PMe3 leads to formation stibanyl-functionalized PMe3-arsinidene (2). Detailed analyses through single-crystal X-ray diffraction and density functional theory 2 confirm covalent Sb-As bonds reveal its polarized nature multiple-bond character. In contrast complex 2, substituting xylyl isocyanide or 1,3-diisopropyl-4,5-dimethyl-imidazolin-2-ylidene (IiPr) produces an...
Chiral binaphthols (BINOL)-metal combinations serve as powerful catalysts in asymmetric synthesis. Their chiral induction mode, however, typically relies on multifarious non-covalent interactions between the substrate and BINOL ligand. In this work, we demonstrate that chiral-at-metal stereoinduction mode could an alternative mechanism for BINOL-metal catalysis, based mechanistic studies of BINOL-aluminum-catalyzed hydroboration heteroaryl ketones. Theoretical calculations reveal octahedral...
The fractal theory is introduced to explore the stable characteristics of correlation between industrial water use efficiency (IWUE) and economic development level (EDL) at different spatial temporal scales. research was carried out based on statistical data including consumption per 104 yuan added value (as IWUE) capita GDP EDL) 336 cities in China from 1998 2017 142 countries across world 2017. results show that during 1998-2017, IWUE EDL Chinese have improved gradually. Although...