- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metal-Organic Frameworks: Synthesis and Applications
- Magnetism in coordination complexes
- Crystallography and molecular interactions
- Metal complexes synthesis and properties
- Advanced Chemical Physics Studies
- Crystal structures of chemical compounds
- Mass Spectrometry Techniques and Applications
- Fullerene Chemistry and Applications
- Electrochemical Analysis and Applications
- Analytical chemistry methods development
- Supramolecular Chemistry and Complexes
- Chemical Reactions and Mechanisms
- Supercapacitor Materials and Fabrication
- Adsorption and biosorption for pollutant removal
- Lanthanide and Transition Metal Complexes
- Covalent Organic Framework Applications
- Advanced battery technologies research
- Synthesis and Properties of Aromatic Compounds
- Molecular Junctions and Nanostructures
- Chemical Synthesis and Characterization
- History and advancements in chemistry
- Polyoxometalates: Synthesis and Applications
- Cyclization and Aryne Chemistry
Beijing University of Posts and Telecommunications
2025
Shandong University of Science and Technology
2012-2023
Industrial Technology Research Institute
2022
Qingdao Center of Resource Chemistry and New Materials
2015-2018
Guangdong Medical College
2018
Nanjing University
2006-2017
Collaborative Innovation Center of Advanced Microstructures
2017
Xiamen University
2004-2012
ITRI International
2011
Guangxi Normal University
2008
Utilizing battery storage systems (BSSs) can reduce the intermittent output of PV generation (PVGSs) and make them dispatchable. The aim this paper is to design an optimal charging/discharging scheduling for BSSs such that line loss distribution interconnected with sizeable PVGSs be minimized. A mathematical model which used simulate charging procedures as commonly-used constant current voltage (CC-CV) method, discharging state charge (SOC) proposed first. minimum problem considering then...
Five novel coordination polymers [Zn(2)(OA)(4,4'-bipy)(H(2)O)].0.5(4,4'-bipy), [Zn(2)(OA)(dib)(H(2)O)].H(2)O, [Zn(2)(OA)(bbi)(2)].3H(2)O, [Zn(2)(OA)(phen)(2)(H(2)O)] and [Zn(4)(OA)(2)(2,2'-bipy)(2)(H(2)O)].2H(2)O were obtained by hydrothermal reactions of Zn(NO(3))(2).6H(2)O with a V-shaped multicarboxylate ligand 3,3',4,4'-oxydiphthalic acid (H(4)OA) series N-donor ligands, namely 4,4'-bipyridine (4,4'-bipy), 1,4-di(1-imidazolyl)benzene (dib), 1,1'-(1,4-butanediyl)bis(imidazole) (bbi),...
A novel coordination polymer Zn(DMA)(TBA) (<bold>1</bold>) (H<sub>2</sub>TBA = 4-(1<italic>H</italic>-tetrazol-5-yl)-benzoic acid) features a unique two-dimensional (2D) network structure, exhibiting excellent luminescence and good stability in both water other organic solvents.
This work presents a systematic investigation on reactions of flexible tricarboxylic acid with Zn(II), Cd(II) in the presence varied N-donor ancillary ligands. Seven new metal−organic frameworks [Zn3(bta)2(bpy)2] (1), [Zn3(bta)2(dpe)2]·2H2O (2), [Zn2(OH)(bta)(bpe)]·2H2O (3), [Zn2(OH)(bta)(bpp)] (4), [Cd2(bta)(bpy)2(H2O)]ClO4·H2O (5), [Cd3(bta)2(bpy)2]·2H2O (6), and [Cd3(bta)2(H2O)2] (7) [bta3− = benzene-1,3,5-triacetate, bpy 4,4′-bipyridine, dpe 1,2-di(4-pyridyl)ethylene, bpe...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEvidence for an externally bound iron+-buckminsterfullerene complex, FeC60+, in the gas phaseL. M. Roth, Y. Huang, J. T. Schwedler, C. Cassady, D. Ben-Amotz, B. Kahr, and S. FreiserCite this: Am. Chem. Soc. 1991, 113, 16, 6298–6299Publication Date (Print):July 1, 1991Publication History Published online1 May 2002Published inissue 1 July 1991https://pubs.acs.org/doi/10.1021/ja00016a071https://doi.org/10.1021/ja00016a071research-articleACS...
Herein, we report that the surface charge status and size of metal–organic framework (MOF) MIL-101(Cr) can be tailored by varying concentration tetramethylammonium hydroxide. The adsorption capacity MIL-101(Cr)-2 toward anionic dye Congo red (CR) was found to significantly higher than other adsorbents, although MIL-101(Cr)-3 microcrystals exhibited highest methyl orange (MO) due different mechanisms involved. This is first demonstration synergetic interplay between electrostatic π–π...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExternally bound metal ion complexes of buckminsterfullerene, MC60+, in the gas phaseYongqing Huang and Ben S. FreiserCite this: J. Am. Chem. Soc. 1991, 113, 24, 9418–9419Publication Date (Print):November 1, 1991Publication History Published online1 May 2002Published inissue 1 November 1991https://pubs.acs.org/doi/10.1021/ja00024a086https://doi.org/10.1021/ja00024a086research-articleACS PublicationsRequest reuse permissionsArticle...
Solvent-induced trinuclear NiII complexes, [{Ni(L)(MeOH)}2(OAc)2Ni]·2MeOH (1), [{Ni(L)(EtOH)}2(OAc)2Ni]·2H2O (2), [{Ni(L)(n-PrOH)}2(OAc)2Ni]·2H2O (3) and [{Ni(L)(i-PrOH)}2(OAc)2Ni] (4), have been prepared with an unsymmetric Salamo-like ligand H2L, characterized via X-ray crystallography, FT-IR, UV-Vis fluorescence spectra. In complexes 1, 2, 3 4, there are two (L)2− moieties, acetato ligands, coordinated methanol, ethanol, n-propanol or i-propanol molecules, respectively, as well other...
Abstract 3D photodetectors (3dPDs) fabricated by mechanically‐guided assembly have garnered significant attention for their unique structures and photodetection capabilities. However, 3dPDs constructed with heterostructures still face major challenges yet to demonstrate self‐powered polarization‐sensitive photodetection, owing the extreme difficulties in of fabrication perfectly‐matched electrodes. In this study, based on been demonstrated first time through controllable rolling crafted...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of bis(buckminsterfullerene)nickel cation, Ni(C60)2+, in the gas phaseYongqing Huang and Ben S. FreiserCite this: J. Am. Chem. Soc. 1991, 113, 21, 8186–8187Publication Date (Print):October 1, 1991Publication History Published online1 May 2002Published inissue 1 October 1991https://pubs.acs.org/doi/10.1021/ja00021a065https://doi.org/10.1021/ja00021a065research-articleACS PublicationsRequest reuse permissionsArticle...
Seven new coordination polymers {[Cu3(tib)4](NO3)6·4.94H2O}n (1), {[Cu2(tib)2(SO4)2]·2EtOH·2H2O}n (2), [Cu(tib)Cl2]n (3), {[Cd(tib)2](NO3)2·4H2O}n (4), {[Cd(tib)(H2O)2(SO4)]·EtOH·H2O}n (5) {[Co(tib)(H2O)2(SO4)]·EtOH·H2O}n (6), and {[Ni(tib)(H2O)2(SO4)]·EtOH·H2O}n (7) (EtOH = ethanol) were prepared by reactions of flexible tripodal ligand 1,3,5-tris(imidazol-1-ylmethyl)benzene (tib) with the corresponding metal salts. Their structures determined X-ray crystallography. The different 1−3 as...
Six new three-dimensional (3D) Cd(II) coordination polymers, {[Cd2(L)3](NO3)4·6H2O}n (1), {[Cd2(L)3](ClO4)4·2H2O}n (2), {[Cd2(L)3](BF4)4·2H2O}n (3), {[Cd(L)Cl2]·2H2O}n (4), {[Cd2(L)2(SO4)2(H2O)]·2H2O}n (5) and {[Cd2(L)(SO4)2(H2O)3]·4H2O}n (6), have been solvothermally synthesized by reactions of the corresponding salts with flexible tetradentate ligand 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene (L), respectively. The X-ray diffraction analysis revealed that isostructural 1, 2 3 3D...
Seven new silver(I) complexes of the formula [Ag2(L)2(CF3SO3)2] (1), [Ag2(L)2(CH3SO3)2] (2) [Ag2(L)2](BF4)2 (3), [Ag3(L)2(NO3)2]NO3.5H2O (4), [Ag2(L)(NO3)2].CH3OH (5), [Ag2(L)2](ClO4)2 (6) and [Ag3(L)2(CH3CN)3](ClO4)3 (7) have been synthesized by reactions 1,3,5-tris(2-oxazolinyl)benzene (L) with varied salts under different conditions. The influences counter anions reaction conditions on structure are discussed. Three , 1, 2 3 two kinds 1D chain structures were obtained same synthetic using...
Five novel transition metal complexes [Cd(II) (3)(tpba-2)(2)(SCN)(6)].6 THF.3 H(2)O (1), [Cu(II) (2), [Ni(II) (3), (2)(tpba-2)(SCN)(3)]ClO(4) (4), [Cu(I) (3)(SCN)(6)(H(3)tpba-2)] (5) [TPBA-2 = N',N'',N'''-tris(pyrid-2-ylmethyl)-1,3,5-benzenetricarboxamide, THF=tetrahydrofuran] were obtained by reactions of the corresponding salts with TPBA-2 ligand in presence NH(4)SCN using layering or solvothermal method, respectively. The results X-ray crystallographic analysis showed that 1, 2 and 3 are...
Six cadmium(II) coordination polymers, {[Cd(tib)2](BF4)2}n (1), {[Cd(tib)2](NO3)2·2EtOH}n (2) (EtOH = ethanol), {[Cd(tib)(OAc)2]·4.5 H2O}n (3) (OAc acetate anion), {[Cd(tib)(μ2-Cl)Cl]·MeOH}n (4) (MeOH methanol), {[Cd(tib)2(H2O)2]Cl2·4 (5) and {[Cd(tib)2][Cd2I6]}n (6), were obtained by reactions of flexible tripodal ligand 1,3,5-tris(imidazol-1-ylmethyl)benzene (tib) with the corresponding metal salts, respectively. Their structures determined X-ray crystallography. Complexes 1 6 have...
Polymer blends incorporating poly (ethylene terephthalate) (PET), polyamide-6 (PA-6), and a reactive compatibilizer (low molecular weight bisphenol-A epoxy resin—E-44) were prepared with the following E-44 percent concentrations: 0, 0.3, 0.6, 1, 3, 5, 10. The samples was studied by scanning electron microscope (SEM), polarizing (PLM), dynamic mechanical thermal analysis (DMTA), wide-angle X-ray diffraction (WAXD), differential calorimeter (DSC), infrared spectroscopy (IR), testing. SEM PLM...
A new Cd(II) complex [Cd3(L)3(mu3-CO3)](ClO4)4.2CH3CN (1) with two-dimensional (2D) network structure was obtained by reaction of an imidazole-containing tripodal polyamine ligand N1-(2-aminoethyl)-N1-(2-imidazolethyl)-ethane-1,2-diamine (L) Cd(ClO4)2.6H2O at pH 9.0 in air. The carbonate anions (CO3(2-)) are from the hydration atmospheric carbon dioxide, which is same as previously reported Cu(II) [Cu3(L)3(mu3-CO3)](ClO4)4.3CH3CN (2). However, coordination mode CO3(2-) 1 mu3-eta2:eta2:eta2...
Three new metal–organic coordination networks with various metal-linker secondary building units are synthesized, which have luminescence and iodine adsorption properties.