A5031008609- Organometallic Complex Synthesis and Catalysis
- Asymmetric Hydrogenation and Catalysis
- Metal complexes synthesis and properties
- Chemical Synthesis and Analysis
- Nosocomial Infections in ICU
- Respiratory Support and Mechanisms
- Organometallic Compounds Synthesis and Characterization
- Pneumonia and Respiratory Infections
- Carbon dioxide utilization in catalysis
- Chemical Synthesis and Reactions
- Airway Management and Intubation Techniques
- Synthetic Organic Chemistry Methods
- Magnetism in coordination complexes
- Catalysis and Hydrodesulfurization Studies
- Catalytic C–H Functionalization Methods
- Sulfur-Based Synthesis Techniques
- Sepsis Diagnosis and Treatment
- Oxidative Organic Chemistry Reactions
- Surface Chemistry and Catalysis
- Synthesis and characterization of novel inorganic/organometallic compounds
- Venous Thromboembolism Diagnosis and Management
- Inorganic and Organometallic Chemistry
- Electrocatalysts for Energy Conversion
- Asymmetric Synthesis and Catalysis
- Nanomaterials for catalytic reactions
Consorci Institut D'Investigacions Biomediques August Pi I Sunyer
2023-2025
Fondazione IRCCS Ca' Granda Ospedale Maggiore Policlinico
2020-2024
Ospedale Maggiore
2023-2024
Azienda Socio Sanitaria Territoriale Santi Paolo e Carlo
2018-2022
University of Milan
2018-2021
Hospital Clínic de Barcelona
2018-2020
Ospedale San Paolo
2018-2019
University Hospital Bonn
2018
Ospedale San Paolo
2018
Institute for the Chemistry of OrganoMetallic Compounds
2003
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligandsClaudio Bianchini, Andrea Meli, Maurizio Peruzzini, Piero Frediani, Cristina Bohanna, Miguel A. Esteruelas, Luis OroCite this: Organometallics 1992, 11, 1, 138–145Publication Date (Print):January 1992Publication History Published online1 May 2002Published inissue 1...
Abstract A new family of C s ‐ and 1 ‐symmetric 2,6‐bis(imino)pyridyl ligands has been synthesised. These ligands, which differ from their known counterparts in the contemporaneous presence alkyl aryl substituent at ketimine nitrogen atoms, form stable, five‐coordinate complexes with FeCl 2 CoCl . All catalysts have fully characterised both solid state solution. single‐crystal X‐ray analysis [CoCl {2‐[CMe=N−(2,6‐dimethylphenyl)]‐6‐(CMe=N−C 6 H 11 )C 5 3 N}]·H O shows metal centre to adopt a...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3Claudio Bianchini, Andrea Meli, Maurizio Peruzzini, Francesco Vizza, Piero Frediani, Jose A. RamirezCite this: Organometallics 1990, 9, 1, 226–240Publication Date (Print):January 1990Publication History Published online1 May 2002Published inissue 1 January...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHDS Model Systems. Coordination, Opening, and Hydrogenation of Benzo[b]thiophene at IridiumClaudio Bianchini, Andrea Meli, Maurizio Peruzzini, Francesco Vizza, Simonetta Moneti, Veronica Herrera, Roberto A. Sanchez-DelgadoCite this: J. Am. Chem. Soc. 1994, 116, 10, 4370–4381Publication Date (Print):May 1, 1994Publication History Published online1 May 2002Published inissue 1...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOpening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phaseClaudio Bianchini, Andrea Meli, Maurizio Peruzzini, Francesco Vizza, Piero Frediani, Veronica Herrera, Roberto A. Sanchez-DelgadoCite this: J. Am. Chem. Soc. 1993, 115, 7, 2731–2742Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA homogeneous iron(II) system capable of selectivity catalyzing the reduction terminal alkynes to alkenes and buta-1,3-dienesClaudio Bianchini, Andrea Meli, Maurizio Peruzzini, Francesco Vizza, Fabrizio Zanobini, Piero FredianiCite this: Organometallics 1989, 8, 2080–2082Publication Date (Print):August 1, 1989Publication History Published online1 May 2002Published inissue 1 August...
Abstract Background Streptococcus pneumoniae , a primary cause of community-acquired pneumonia (CAP), is typically treated with β-lactams and macrolides or quinolones. Corticosteroids are now recommended as adjunctive therapy in severe CAP to improve outcomes. I n this prospective randomized animal study, we evaluated the bactericidal efficacy various antibiotic regimens combined corticosteroids using porcine pneumococcal model. Results In 30 White-Landrace female pigs, was induced by...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA deceptively simple case of selective hydrogenation phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complexClaudio Bianchini, Cristina Bohanna, Miguel A. Esteruelas, Piero Frediani, Andrea Meli, Luis Oro, and Maurizio PeruzziniCite this: Organometallics 1992, 11, 3837–3844Publication Date (Print):November 1, 1992Publication History Published online1 May 2002Published inissue 1 November...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn .eta.4-benzene species mediates acetylene cyclotrimerizationClaudio Bianchini, Kenneth G. Caulton, Catherine Chardon, Odile Eisenstein, Kirsten Folting, Todd J. Johnson, Andrea Meli, Maurizio Peruzzini, David Rauscher, and Cite this: Am. Chem. Soc. 1991, 113, 13, 5127–5129Publication Date (Print):June 1, 1991Publication History Published online1 May 2002Published inissue 1 June...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA stable .eta.2-dihydrogen complex of cobalt. Role the hydrogen-hydrogen interaction in hydrogen transfer from metal to alkeneClaudio. Bianchini, Carlo. Mealli, Andrea. Meli, Maurizio. Peruzzini, and Fabrizio. ZanobiniCite this: J. Am. Chem. Soc. 1988, 110, 26, 8725–8726Publication Date (Print):December 1, 1988Publication History Published online1 May 2002Published inissue 1 December...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReversible double addition of hydrogen on a bis(.mu.-sulfido) binuclear rhodium complexClaudio Bianchini, Carlo Mealli, Andrea Meli, and Michal SabatCite this: Inorg. Chem. 1986, 25, 26, 4617–4618Publication Date (Print):December 1, 1986Publication History Published online1 May 2002Published inissue 1 December 1986https://pubs.acs.org/doi/10.1021/ic00246a004https://doi.org/10.1021/ic00246a004research-articleACS PublicationsRequest reuse...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRhodium complexes with tripodal polyphosphines as excellent precursors to systems for the activation of H-H and C-H bondsClaudio. Bianchini, Dante. Masi, Andrea. Meli, Maurizio. Peruzzini, Fabrizio. ZanobiniCite this: J. Am. Chem. Soc. 1988, 110, 19, 6411–6423Publication Date (Print):September 1, 1988Publication History Published online1 May 2002Published inissue 1 September...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHomogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation the Hydrodesulfurization Mechanism and an Effective Method Synthesis Unusual Organosulfur CompoundsClaudio Bianchini, Piero Frediani, Veronica Herrera, M. Victoria Jimenez, Andrea Meli, Luis Rincon, Roberto Sanchez-Delgado, Francesco VizzaCite this: J. Am. Chem. Soc. 1995, 117, 15, 4333–4346Publication Date (Print):April 1, 1995Publication History...
The substitution of two hydrogen atoms by methyl groups in the 1,2 positions 1,2-bis(diphenylphosphino)ethane (dppe) gives meso- and rac-2,3-bis(diphenylphosphino)butane (meso-2,3-dppb rac-2,3-dppb). corresponding Pd(II) complexes Pd(OTs)2(meso-2,3-dppb) Pd(OTs)2(rac-2,3-dppb) are effective catalyst precursors for alternating copolymerization terpolymerization carbon monoxide with ethene ethene/propene MeOH productivities that higher than those unsubstituted dppe Pd(OTs)2(dppe) even a factor...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA novel oxygen-carrying and activating system of rhodium(III). Oxidation oxygenation reactions 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complexClaudio Bianchini, Piero Frediani, Franco Laschi, Andrea Meli, Francesco Vizza, ZanelloCite this: Inorg. Chem. 1990, 29, 18, 3402–3409Publication Date (Print):September 1, 1990Publication History Published online1 May...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, characterization, and electrochemical properties of a family dinuclear rhodium complexes containing two terminal hydride ligands (or chloride) bridges. Stoichiometric catalytic hydrogenation reactions alkynes alkenesClaudio Bianchini, Andrea Meli, Franco Laschi, Jose A. Ramirez, Piero Zanello, Alberto VaccaCite this: Inorg. Chem. 1988, 27, 24, 4429–4435Publication Date (Print):November 1, 1988Publication History Published online1 May...
Background: Little is known about risk and prognostic factors in very old patients developing sepsis secondary to community-acquired pneumonia (CAP). Methods: We conducted a retrospective observational study of data prospectively collected at the Hospital Clinic Barcelona over 13-year period. Consecutive hospitalized with CAP were included if they (≥80 years) divided into those without for comparison. Sepsis was diagnosed based on Sepsis-3 criteria. The main clinical outcome 30-day...
Pseudomonas aeruginosa pneumonia is commonly treated with systemic antibiotics to ensure adequate treatment of multidrug resistant (MDR) bacteria. However, intravenous (IV) often achieve suboptimal pulmonary concentrations. We therefore aimed evaluate the effect inhaled amikacin (AMK) plus IV meropenem (MEM) on bactericidal efficacy in a swine model monolateral MDR P. pneumonia.We ventilated 18 pigs for up 102 h. At 24 h after bacterial challenge, animals were randomized receive 72 either...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and CatalysisClaudio Bianchini, Kenneth G. Caulton, Catherine Chardon, Marie-Liesse Doublet, Odile Eisenstein, Sarah A. Jackson, Todd J. Johnson, Andrea Meli, Maurizio Peruzzini, Cite this: Organometallics 1994, 13, 5, 2010–2023Publication Date (Print):May 1, 1994Publication History Published online1 May 2002Published inissue 1...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemoselective oxidation of 3,5-di-tert-butylcatechol by molecular oxygen. Catalysis an iridium(III) catecholate through its dioxygen adductPierluigi Barbaro, Claudio Bianchini, Piero Frediani, Andrea Meli, and Francesco VizzaCite this: Inorg. Chem. 1992, 31, 8, 1523–1529Publication Date (Print):April 1, 1992Publication History Published online1 May 2002Published inissue 1 April...
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTActivation of 1-alkynes at tripodal (polyphosphine)rhodium systems. Regioselective synthesis enol esters from and carboxylic acids catalyzed by rhodium(I) monohydridesClaudio Bianchini, Andrea Meli, Maurizio Peruzzini, Fabrizio Zanobini, Christian Bruneau, Pierre H. DixneufCite this: Organometallics 1990, 9, 4, 1155–1160Publication Date (Print):April 1, 1990Publication History Published online1 May 2002Published inissue 1 April...
<h3>BACKGROUND:</h3> Mechanical insufflation-exsufflation (MI-E) has been proposed as a potential strategy to generate high expiratory flows and simulate cough in the critically ill. However, efficacy safety of MI-E during invasive mechanical ventilation are still be fully elucidated. This study intubated mechanically ventilated pigs aimed evaluate effects 8 combinations pressures on mucus displacement, respiratory flows, well mechanics hemodynamics. <h3>METHODS:</h3> Six healthy...