A5074671094- Fluorine in Organic Chemistry
- Synthesis and Reactions of Organic Compounds
- Inorganic Fluorides and Related Compounds
- High-pressure geophysics and materials
- Geological and Geochemical Analysis
- Organic Chemistry Cycloaddition Reactions
- Advanced Chemical Physics Studies
- Synthesis and Biological Evaluation
- Asymmetric Synthesis and Catalysis
- Crystallization and Solubility Studies
- Analytical Chemistry and Chromatography
- earthquake and tectonic studies
- X-ray Diffraction in Crystallography
- Ionic liquids properties and applications
- Cyclization and Aryne Chemistry
- Catalysis and Oxidation Reactions
- Chemistry and Chemical Engineering
- Catalytic Processes in Materials Science
- Catalysts for Methane Reforming
- Synthetic Organic Chemistry Methods
- Radioactive element chemistry and processing
- Molecular Spectroscopy and Structure
- Catalysis for Biomass Conversion
- Geochemistry and Elemental Analysis
- Geomagnetism and Paleomagnetism Studies
Novosibirsk Institute of Organic Chemistry
2007-2024
Siberian Branch of the Russian Academy of Sciences
2020
Russian Academy of Sciences
2014
Novosibirsk State University
2006-2014
Polycyclic aromatic compounds (PACs) represent a class of molecules consisting two or more condensed rings. They are currently great interest as potential semiconducting materials for organic field‐effect transistors, light‐emitting diodes, and solar panels. Substituted PACs not always readily available may require complicated multi‐step synthetic procedures to be obtained. One the promising methods synthesis functionalized is assembly polycyclic backbones from substituted building blocks...
We demonstrated the influence of liquid additives on rate and selectivity mechanochemical fluorination aromatic 1,3-dicarbonyl compounds with F-TEDA-BF
An effective protocol for the solvent‐free fluorination of electron‐rich aromatic compounds with 1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F‐TEDA‐BF 4 ) is described. The allows easy and efficient isolation fluorinated products in high yields purities low E factors (kg waste kg product –1 by vacuum‐sublimation without use any solvent. solid‐state naphthalen‐2‐ol was studied differential thermal analysis, scanning electron microscopy used to obtain...
A wide range of organic molecules can participate in hydrogen atom transfer (HAT) processes as both HAT-donors and photo-HAT-acceptors simultaneously. Therefore, it opens the possibilities to exclude catalysts for C-H functionalization such cases. This is underlying idea presented catalyst-free bond fluorination approach. We demonstrated that broad aryl alkyl ketones be efficiently fluorinated with Selectfluor-based reagents at benzylic position under UV-A irradiation without any added...
A wide range of organic molecules can participate in hydrogen atom transfer (HAT) processes as both HAT-donors and photo-HAT-acceptors simultaneously. Therefore, it opens the possibilities to exclude catalysts for C-H functionalization such cases. This is underlying idea presented catalyst-free bond fluorination approach. We demonstrated that broad aryl alkyl ketones be efficiently fluorinated with Selectfluor-based reagents at benzylic position under UV-A irradiation without any added...
The formation of hydrocarbons (HCs) upon interaction metal and metal–carbon phases (solid Fe, Fe3C, Fe7C3, Ni, liquid Fe–Ni alloys) with or without additional sources carbon (graphite, diamond, carbonate, H2O–CO2 fluids) was investigated in quenching experiments at 6.3 GPa 1000–1400 °C, wherein hydrogen fugacity (fH2) controlled by the Fe–FeO + H2O Mo–MoO2 equilibria. aim study to investigate abiotic generation characterize diversity HC species that form presence Fe/Ni P–T–fH2 conditions...
C- and N-bearing species in reduced fluids weree studied experimentally C–O–H–N muscovite–C–O–H–N systems natural carbonate-bearing samples at mantle P–T parameters. The experiments reproduced three types of reactions leading to formation hydrocarbons (HCs) 3.8–7.8 GPa 800–1400 °C hydrogen fugacity (fH2) buffered by the Fe–FeO (IW) + H2O or Mo–MoO2 (MMO) equilibria: (i) Thermal destruction organic matter during its subduction into (with an example docosane), (ii) hydrogenation graphite upon...