A5079747523- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Metalloenzymes and iron-sulfur proteins
- Crystallography and molecular interactions
- Electrocatalysts for Energy Conversion
- Molten salt chemistry and electrochemical processes
- Organometallic Complex Synthesis and Catalysis
- Advanced battery technologies research
- Metal-Catalyzed Oxygenation Mechanisms
- Asymmetric Hydrogenation and Catalysis
- Magnetism in coordination complexes
- Extraction and Separation Processes
- Carbon dioxide utilization in catalysis
- Ammonia Synthesis and Nitrogen Reduction
- Algal biology and biofuel production
- Nanomaterials for catalytic reactions
- Metal complexes synthesis and properties
- Nuclear materials and radiation effects
- Marine and coastal ecosystems
- Photosynthetic Processes and Mechanisms
- Metallurgical Processes and Thermodynamics
- Advancements in Battery Materials
- CO2 Reduction Techniques and Catalysts
- Metal-Organic Frameworks: Synthesis and Applications
- Thermodynamic and Structural Properties of Metals and Alloys
Dalian University
2016-2025
Dalian University of Technology
2016-2025
Chinese Academy of Sciences
2011-2024
Beijing National Laboratory for Molecular Sciences
2023-2024
Institute of High Energy Physics
2019-2023
Harbin Engineering University
2007-2021
Ningbo Institute of Industrial Technology
2020
North China University of Science and Technology
2019
Beihang University
2018
National Chung Hsing University
2018
Batch Normalization (BN) is capable of accelerating the training deep models by centering and scaling activations within mini-batches. In this work, we propose Decorrelated (DBN), which not just centers scales but whitens them. We explore multiple whitening techniques, find that PCA causes a problem call stochastic axis swapping, detrimental to learning. show ZCA does suffer from problem, permitting successful DBN retains desirable qualities BN further improves BN's optimization efficiency...
Interaction of a diiron thiolate-bridged complex, [Cp*Fe(μ-η2:η4-bdt)FeCp*] (1) (Cp* = η5-C5Me5; bdt benzene-1,2-dithiolate) with proton gives an FeIIIFeIII hydride bridged [Cp*Fe(μ-bdt)(μ-H)FeCp*][BF4] (3[BF4]). According to in situ variable temperature 1H NMR studies, the formation 3[BF4] was evidenced occur through stepwise pathway: protonation occurring at iron center produce terminal [Cp*Fe(μ-bdt)(t-H)FeCp*][BF4] (2) and subsequent intramolecular isomerization bridging 3[BF4]. A...
Batch Normalization (BN) is capable of accelerating the training deep models by centering and scaling activations within mini-batches. In this work, we propose Decorrelated (DBN), which not just centers scales but whitens them. We explore multiple whitening techniques, find that PCA causes a problem call stochastic axis swapping, detrimental to learning. show ZCA does suffer from problem, permitting successful DBN retains desirable qualities BN further improves BN's optimization efficiency...
Electrochemical behaviors of lanthanide (i.e. La, Ce, Pr and Nd) chlorides in LiCl-KCl melt were demonstrated via cyclic voltammetry (CV) open circuit potential (OCP) techniques at temperatures from 723 K to 873 K. An electrochemical galvanostatic intermittent titration technique (GITT) was performed obtain the thermodynamic data (Ln) on liquid bismuth electrode. The relationship between activity coefficient temperature determined. Galvanostatic pulse (GP) impedance spectroscopy (EIS) as...
Viscosity, at the subcellular level, plays a crucial role as physicochemical factor affecting microenvironment homeostasis. Abnormal changes in mitochondrial viscosity often lead to various diseases organism. Based on twisted intramolecular charge transfer mechanism, four hemicyanine dye fluorescent probes (HT-SA, HT-SA-S, HT-Bzh, and HT-NA) were designed synthesized for response. The single bond between nitrogen-containing heterocycle carbon–carbon double structure of probe served response...
Thiolate‐bridged diiron complexes have drawn extensive attention due to their wide applications in the biomimetic simulation for structure and function of various metalloenzymes related bioinspired catalysis. Through introduction functional subunit into bridging thiolate ligands, resulting thiolate‐bridged with different geometric electronic structures can exhibit distinct reactivity. Herein, we utilize a half‐sandwich type mononuclear iron complex as reaction precursor construct two novel...
A series of novel monothiolate-bridged dirhodium complexes, [Cp*Rh(μ-SR)(μ-Cl)2RhCp*][BF4] {Cp* = η5-C5Me5, R tertiary butyl (tBu), 1a; ferrocenyl (Fc), 1b; adamantyl (Ad), 1c} were designed and successfully synthesized, which can smoothly facilitate highly regioselective stereoselective hydrosilylation terminal alkynes to afford β(Z) vinylsilanes with good functional group compatibility. Furthermore, the hydride bridged complex [Cp*Rh(μ-StBu)(μ-Cl)(μ-H)RhCp*][BF4] (5) as a potential...
The novel thioether-dithiolate-bridged diiron complex [Cp*Fe(μ-1κ3SSS′:2κ2SS-tpdt)FeCp*] (1, Cp* = η5-C5Me5; tpdt S(CH2CH2S−)2) has been prepared by the reaction of [Cp*FeCl]2 with Li2(tpdt) in THF. Given thermodynamic instability 1, a one-electron oxidation was performed Fc·PF6 (Fc ferrocene) affording 1[PF6]. Treatment 1[PF6] CO or tBuNC CH2Cl2 gave complexes [Cp*Fe(μ-1κ3SSS′:2κ2SS-tpdt){Cp*Fe(η1-CO)}][PF6] (2[PF6]) and [Cp*Fe(μ-1κ3SSS′:2κ2SS-tpdt){Cp*Fe(η1-tBuNC)}][PF6] (3[PF6]). In...
A series of nitrile-coordinating complexes [Cp*Fe(μ-SEt)RCN]2[PF6]2 (1, R = alkyl, aryl, vinyl, amine) have been obtained by the reaction [Cp*Fe(μ-SEt)MeCN]2[PF6]2 (1a) with various nitriles in acetone. Complexes 1 can realize hydration a nitrile ligand under ambient conditions. [Cp*Fe(μ-SEt)2(μ-η1:η1-NH(O)CR)FeCp*][PF6] (2) were successfully isolated as intermediates during process, 2b and 2e (R CH2═CH Et2N) being characterized spectrometry X-ray crystallography. Treatment 2 HBF4·Et2O...
Abstract By using 3,7‐dithianonane‐1,9‐dithiol (S 4 ) and N , N′ ‐dimethyl‐ ‐bis(2‐mercaptoethyl)ethylenediamine (N 2 S as ligands, two CH 3 CN‐coordinated nickel‐iron heterodimetallic complexes, [NiS Fe(CH CN)Cp*][PF 6 ] ( 1a [NiN 1b (Cp* = η 5 ‐C Me ), were synthesized characterized spectroscopically crystallographically. Reactivities of towards CO, Cl HBF NOPF have also been investigated. A series complexes coordinated with small molecules Fe(L)Cp*][PF n [ 1, L 2a CO 3a ); 2, NO 4a )], [L...
Using an assembly method, dinuclear CoCo and CoFe complexes supported by a bdt ligand, [Cp*Co(μ–η<sup>2</sup>:η<sup>2</sup>-bdt)(μ-I)CoCp*][PF<sub>6</sub>] (<bold>1[PF6]</bold>, Cp* = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>, benzene-1,2-dithiolate), [Cp*Co(μ–η<sup>2</sup>:η<sup>4</sup>-bdt)FeCp′][PF<sub>6</sub>] (<bold>3[PF6]</bold>, Cp′ η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>H) were synthesized in high yields.