- X-ray Diffraction in Crystallography
- Nanoplatforms for cancer theranostics
- Crystallization and Solubility Studies
- Metal-Organic Frameworks: Synthesis and Applications
- Mesoporous Materials and Catalysis
- Photodynamic Therapy Research Studies
- Advanced Nanomaterials in Catalysis
- Analytical Chemistry and Chromatography
- Porphyrin and Phthalocyanine Chemistry
- Adsorption and biosorption for pollutant removal
- Carbon Dioxide Capture Technologies
- Advanced Photocatalysis Techniques
- Supramolecular Self-Assembly in Materials
- Lanthanide and Transition Metal Complexes
- Advanced Drug Delivery Systems
- Magnetism in coordination complexes
- Dye analysis and toxicity
- TiO2 Photocatalysis and Solar Cells
- Click Chemistry and Applications
- Chemical Synthesis and Characterization
- Catalytic Processes in Materials Science
- Nanomaterials for catalytic reactions
University of Pavol Jozef Šafárik
2020-2025
Technical University of Košice
2020
Abstract In this study, we explore the mechanical treatment of two metal–organic frameworks (MOFs), HKUST-1 and MOF-76, applying various milling methods to assess their impact on stability, porosity, CO 2 adsorption capacity. The effects different grinding techniques, such as high-energy ball hand grinding, these MOFs were compared. time, speed size during was assessed via Design Experiments methodology, namely using a 3 Taguchi orthogonal array. results highlight marked improvement in...
Mesoporous SBA-15 silica material was prepared by the sol–gel method and functionalized with thermosensitive polyethylenimine polymers different molecular weight (g·mol−1): 800 (SBA-15(C)-800), 1300 (SBA-15(C)-1300) 2000 (SBA-15(C)-2000). The nonsteroidal anti-inflammatory drug (NSAID) diclofenac sodium selected as a model encapsulated into pores of supports. Materials were characterized combination infrared spectroscopy (IR), atomic force microscopy (AFM), transmission electron (TEM),...
Mesoporous silica SBA-15 was prepared via sol-gel synthesis and functionalized with different types of organosilanes containing various organic functional groups: (3-aminopropyl)triethoxysilane (SBA-15-NH2), (3-mercaptopropyl)triethoxysilane (SBA-15-SH), triethoxymethylsilane (SBA-15-CH3), triethoxyphenylsilane (SBA-15-Ph), (3-isocynatopropyl)triethoxysilane (SBA-15-NCO). The materials were investigated as drug delivery systems for naproxen. As model drugs, naproxen acid (HNAP) its sodium...
A series of four novel microporous alkaline earth metal-organic frameworks (AE-MOFs) containing methanetetrabenzoate linker (MTB) with composition {[Ca4(μ8-MTB)2]·2DMF·4H2O} n (UPJS-6), {[Ca4(μ4-O)(μ8-MTB)3/2(H2O)4]·4DMF·4H2O} (UPJS-7), {[Sr3(μ7-MTB)3/2]·4DMF·7H2O} (UPJS-8) and {[Ba3(μ7-MTB)3/2(H2O)6]·2DMF·4H2O} (UPJS-9) (UPJS = University Pavol Jozef Safarik) have been successfully prepared characterized. The framework stability thermal robustness materials were investigated using...