A5102004047- Advanced Memory and Neural Computing
- Cell Image Analysis Techniques
- Catalytic C–H Functionalization Methods
- Plant biochemistry and biosynthesis
- Photosynthetic Processes and Mechanisms
- Plant Stress Responses and Tolerance
- Pharmaceutical and Antibiotic Environmental Impacts
- EEG and Brain-Computer Interfaces
- Chemical Synthesis and Analysis
- CCD and CMOS Imaging Sensors
- interferon and immune responses
- Insect and Pesticide Research
- CRISPR and Genetic Engineering
- Pesticide and Herbicide Environmental Studies
- BIM and Construction Integration
- Neural dynamics and brain function
- Radical Photochemical Reactions
- Synthetic Organic Chemistry Methods
- Nanoplatforms for cancer theranostics
- ECG Monitoring and Analysis
- Photonic and Optical Devices
- Pluripotent Stem Cells Research
- Sulfur-Based Synthesis Techniques
- MicroRNA in disease regulation
- Microplastics and Plastic Pollution
Zhejiang University of Technology
2023-2025
Peking University
2019-2025
Zhongyuan University of Technology
2024-2025
Smart Material (Germany)
2025
Emory University
2024
Beijing University of Chemical Technology
2024
The University of Sydney
2022-2024
University of Cambridge
2024
Soochow University
2024
China Pharmaceutical University
2022
The Schmidt reaction has been an efficient and widely used synthetic approach to amides nitriles since its discovery in 1923. However, application often entails the use of volatile, potentially explosive, highly toxic azide reagents. Here, we report a sequence whereby triflic anhydride formic acetic acids activate bulk chemical nitromethane serve as nitrogen donor place azides Schmidt-like reactions. This protocol further expands substrate scope alkynes simple alkyl benzenes for preparation nitriles.
Pesticides promote the stable development of intensive global agriculture. Nevertheless, their residues in soil can cause ecological and human health risks. Glyphosate is a popular herbicide generally thought to be ecologically safe nontoxic, but this conclusion has been questioned. Herein, we investigated interaction among fauna (Enchytraeus crypticus) exposed glyphosate found that induced oxidative stress detoxification responses E. crypticus disturbed lipid metabolism digestive systems....
Control of selectivity is one the central topics in organic chemistry. Although unprecedented alkoxyl-radical-induced transformations have drawn a lot attention, compared to selective C-H activation, radical O-H activation remains less explored. Herein, we report novel strategy diols by combining spatial effects with proton-coupled electron transfer (PCET). It was found that DMSO an essential reagent enables regioselective transformation diols. Mechanistic studies indicated existence alkoxyl...
Cell necroptosis has presented great potential, acting as an effective approach against tumor apoptotic resistance, and it could be further enhanced via accompanying reactive oxygen species (ROS) overexpression. However, whether overproduced ROS assists the necroptotic pathway remains unclear. Thus, iron-palladium nanozyme (FePd NZ)- shikonin (SKN)-encapsulated functional lipid nanoparticles (FPS-LNPs) were designed to investigate overexpression-enhanced SKN-induced necroptosis. In this...
Deconstructive transformation of carbon-carbon double bonds (C=C) is a pivotal strategy in synthetic chemistry and drug discovery. Despite the substantial advances olefin metathesis ozonolysis for natural product synthesis through C=C double-bond cleavage, catalytic remodeling complex molecules deconstruction has been underdeveloped. We report heterogeneous copper-catalyzed which enables by converting carbons on either side bond to carbonyl cyano groups, respectively. In particular, this...
Abstract Epilepsy poses a significant global health challenge, driving the need for reliable diagnostic tools like scalp electroencephalogram (EEG), subscalp EEG, and intracranial EEG (iEEG) accurate seizure detection, localization, modulation treating seizures. However, these techniques often rely on feature extraction such as Short Time Fourier Transform (STFT) efficiency in detection. Drawing inspiration from brain architecture, we investigate biologically plausible algorithms,...
High-entropy alloy (HEA) electrocatalysts have attracted increasing attention for improving sulfur reaction kinetics and anchoring lithium polysulfides (LiPSs) in lithium-sulfur batteries (LSBs). However, fundamentally understanding the relationship between components of HEAs adsorption catalysis LiPSs remains a challenge. Here, FeCoNiMnRu are employed as model to first disclose selective adsorption-catalysis effect LiPSs, induced by competition spin polarization electronegativity Ni−Co−Ru...
Rationally designing and constructing ionic/electronic coconductor electrocatalysts with adjustable active sites to enhance the redox kinetics of lithium–sulfur batteries (LSBs) in lean electrolyte conditions is a challenge. Herein, this study presents promotion for lithium polysulfides (LiPSs) through construction ion/electron coconductive catalytic triple-phase interface using lanthanum titanate/carbon (LLTO/C) nanofibers, which due manipulating geometric torsion BO6 octahedron LLTO....
Abstract Imaging flow cytometry (IFC) is a powerful cell analytic tool that exploits multi-parameters in single-cell images to characterise phenotypes and fluorescence information. It enables in-depth analysis of signalling, DNA repair marker localisation. However, conventional frame-based acquisition bound the triangle imaging constraints – speed, resolution sensitivity, which has become an everlasting challenge overcome during development. Neuromorphic photosensors detect contrast changes...
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As prefabricated buildings play a significant role in the global fight against new coronavirus “COVID‐19,” they attract more attention than other types of buildings. Lean construction helps to improve benefits enterprises and working environment workers. However, are encountering various challenges implementing on‐site lean construction. According cause‐and‐effect relationship, it will be meaningful explore critical causes hindering construction, namely, barriers. Hence, this paper...
Lithium–sulfur batteries (LSBs) are promising next-generation energy storage systems because of their high densities and theoretical specific capacities. However, most catalysts in the LSBs based on carbon materials, which can only improve conductivity unable to accelerate lithium-ion transport. Therefore, it would be worthwhile develop a catalytic electrode exhibiting both ion electron conductivity. Herein, triple-phase interface using lithium lanthanum titanate/carbon (LLTO/C) nanofibers...
This work introduces on-device edge learning for cardiac abnormality detection by merging spiking 2D Convolutional Long-Short-Term Memory (ConvLSTM2D) with a bio-inspired shallow neural network, referred to as Closed-form Continuous-time (CfC), form the sCCfC model. The model achieves an F1 score and AUROC of 0.82 0.91 in abnormalities detection. These results are comparable non-spiking ConvLSTM2D–CfC (ConvCfC) [Huang et al., J. Cardiovasc. Transl. Res. (published online, 2024)]. Notably,...
Herein, we report concise total syntheses of diterpene natural products (−)-crinipellins A and B with a tetraquinane skeleton, three adjacent all-carbon quaternary centers, multiple oxygenated labile functional groups. Our synthesis features convergent Kozikowski β-alkylation to unite two readily available building blocks all the required carbon atoms, an intramolecular photochemical [2 + 2] cycloaddition install challenging centers 5–6–4–5 tetracyclic controlled Cargill rearrangement...
Abstract Control of selectivity is one the central topics in organic chemistry. Although unprecedented alkoxyl‐radical‐induced transformations have drawn a lot attention, compared to selective C−H activation, radical O−H activation remains less explored. Herein, we report novel strategy diols by combining spatial effects with proton‐coupled electron transfer (PCET). It was found that DMSO an essential reagent enables regioselective transformation diols. Mechanistic studies indicated...
The capabilities (e.g., basic capabilities, professional and lean consciousness of workers) benefits time, economy, quality benefits) construction in some precast building projects are insufficiently coordinated due to the moderating effects multiple variables. Revealing relationship among these variables, is necessary solve this problem. Hence, study identified three variables complexity, management, policies from existing literature proposed seven hypotheses regarding relationships them,...
Comprehensive Summary A rhodium‐catalyzed denitrogenative carbonylation of 1,2,3‐thiadiazole with alkynes to construct (benzo)thiochromenones is developed. Both terminal and internal were compatible in this [3+2+1] cycloaddition, affording a broad range poly‐substituted thiochromenones. Unsymmetrical alkyne substrates exhibited good regioselectivity. It noteworthy that the present strategy could be used both monocyclic benzo‐thiochromenones, it novel example transannulation CO insertion.