A5014776886- Metal-Organic Frameworks: Synthesis and Applications
- Covalent Organic Framework Applications
- Gas Sensing Nanomaterials and Sensors
- Electrocatalysts for Energy Conversion
- Catalytic Processes in Materials Science
- Advanced Photocatalysis Techniques
- Dendrimers and Hyperbranched Polymers
- Polymer Surface Interaction Studies
- Advanced Nanomaterials in Catalysis
- Electrochemical Analysis and Applications
- Luminescence and Fluorescent Materials
- Membrane Separation and Gas Transport
- Advanced battery technologies research
- Advanced Sensor and Energy Harvesting Materials
- Advanced oxidation water treatment
- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Nanomaterials for catalytic reactions
- Advanced Materials and Mechanics
- Gold and Silver Nanoparticles Synthesis and Applications
- Carbon dioxide utilization in catalysis
- Analytical Chemistry and Sensors
- Conducting polymers and applications
- Advanced Chemical Sensor Technologies
- MXene and MAX Phase Materials
Jilin University
1999-2025
Northeastern University
2016-2025
Sichuan University of Science and Engineering
2025
Hainan University
2025
Jilin Medical University
2025
Beijing University of Chemical Technology
2002-2025
Universidad del Noreste
2018-2025
College of Medical Sciences
2019-2025
East China Normal University
2020-2025
Southwest University
2023-2025
This communication describes the use of polyelectrolyte multilayer as a preformed matrix in electrochemical deposition to adjust morphology gold clusters, and only surface covered with dendritic clusters shows super-hydrophobic property, contact angle above 150° tilt less than 1.5°, after further chemisorbed self-assembled monolayer n-dodecanethiol.
An advanced supercapacitor material based on nitrogen-doped porous graphitic carbon (NPGC) with high a surface area was synthesized by means of simple coordination-pyrolysis combination process, in which tetraethyl orthosilicate (TEOS), nickel nitrate, and glucose were adopted as porogent, catalyst precursor, source, respectively. In addition, melamine selected nitrogen source owing to its nitrogen-enriched structure the strong interaction between amine groups unit. A low-temperature...
Abstract Substrate‐supported metal–organic frameworks (MOFs) films are desired to realize their potential in practical applications. Herein, a novel substrate‐seeding secondary‐growth strategy is developed prepare composites of uniform MOFs on aerogel walls. Briefly, the organic ligand “pre‐seeded” onto walls, and then small amount metal‐ion solution sprayed prepared aerogel. The diffuses along walls form continuous thin layer, which confines nucleation reaction, promoting formation whole...
Electron paramagnetic resonance (EPR) has been extensively used for the identification of free radicals that are generated from advanced oxidation processes (AOPs) so as to establish reaction mechanism. However, some misinterpretations or controversies on identity detected EPR signals remain in literature. This study, with Cu(II)-based AOPs examples, comprehensively investigated origin 5,5-dimethyl-l-pyrroline N-oxide (DMPO) adducts Cu(II) alone, Cu(II)/H2O2, Cu(II)/peroxymonosulfate (PMS),...
Hydroxylation of C25 C–H bonds (referring to sterols) is great importance in vivo for metabolizing sterols and vitamin Ds. The biocatalytic hydroxylation restricted by the selectivity activity enzymes due inertness these bulky compounds. Herein, we employed fungal unspecific peroxygenase from Agrocybe aegerita (AaeUPO) as catalyst develop efficient selective AaeUPO variants through protein engineering. After three rounds evolution using semirational design, 2 variants, G195A/G241V/G318V...
Wavelength-controlled dynamic processes are mostly based on light-triggered isomerization or the cleavage/formation of molecular connections. Control over metathesis reactions by different light wavelengths, which would be useful in controllable chemistry, has rarely been studied. Taking advantage bond energies disulfide and diselenide bonds, we have developed a wavelength-driven exchange reaction between disulfides diselenides, underwent under UV to produce Se-S bonds. When irradiated with...
Surface and interface states of noble metal nanoparticles (MNPs), closely related to the catalytic performance, have been great concern academics in field catalysis. The property MNPs was usually regulated through introducing modifier effects metal–support effects, common nature these strategies involved either construction steric hindrance on surface or regulation electronic state MNPs, which inspired us employ metal–organic frameworks (MOFs) as a support due their tailorable...
Metal-organic frameworks (MOFs) are an intriguing class of porous crystalline inorganic-organic hybrid materials. The fabrication oriented, thin film MOFs is expected to open novel avenues traditional applications and serve myriad advanced technologies. Here, a facile spray-assisted miscible liquid-liquid interface (MLLI) synthetic strategy carried out reported under mild condition that utilizes for the rapid controllable large-area free-standing MOF films. methodology can employ various...
Bimetallic organic frameworks (Bi-MOFs) have been recognized as one of the most ideal precursors to construct metal oxide semiconductor (MOS) composites, owing their high surface area, various chemical structures, and easy removal sacrificial MOF scaffolds through calcination. Herein, we synthesized Zn/Ni Bi-MOF for first time via a facile ion exchange postsynthetic strategy, formed three-dimensional framework consisting infinite one-dimensional chains that is unattainable direct...
The proton dissociation degrees and dielectric properties of carriers doped COFs with neutral, polar, Lewis base positively charged sites are investigated to get better understanding structure–conductivity relationship.
A facile one-step solvothermal strategy has been developed for the <italic>in situ</italic> growth of ternary MOF nanoarrays onto Ni foam, which exhibits superior electrocatalytic activity and stability electrochemical 5-hydroxymethylfurfural oxidation.
Precise and real-time detection of hydrogen peroxide (H2O2) is particularly necessary in pharmaceutical, industrial, military applications because the strong oxidability H2O2. Here, an electrocatalytic active film with Au nanoparticles (Au NPs) embedded a metal–organic framework (UiO-66) was situ prepared on surface electrode for H2O2 detection. The size electrochemical activity nanoparticles/UiO-66 could be controlled by manipulating electrodeposition conditions. Since NPs are encapsulated...
Hydrogen spillover is the migration of activated hydrogen atoms from a metal particle onto surface catalyst support, which has made significant progress in heterogeneous catalysis. The phenomenon been well researched on oxide supports, yet its occurrence, detection method and mechanism non-oxide supports such as metal-organic frameworks (MOFs) remain controversial. Herein, we develop facile strategy for efficiency enhancement various MOFs with aid water molecules. By encapsulating platinum...
Several thermally activated delayed fluorescence (TADF) materials have been studied and developed to realize high-performance organic light-emitting diodes (OLEDs). However, TADF macrocycles not sufficiently investigated owing the synthetic challenges, resulting in limited exploration of their luminescent properties corresponding highly efficient OLEDs. In this study, a series is synthesized using modularly tunable strategy by introducing xanthones as acceptors phenylamine derivatives...
Abstract Electrocatalytic oxidation of glycerol, an oversupplied byproduct the biodiesel industry, into high‐valued chemicals is alluring to diminishing current dependence on fossil energy. Formic acid important glycerol product that serves as a high‐energy‐density fuel and crucial precursor for fine chemical industry while developing electrocatalyst efficiently convert formic remains challenge. Herein, Cu‐doped nickel phosphide (Cu x Ni 2– P) electrocatalyst, achieving formate productivity...