- Conducting polymers and applications
- Analytical Chemistry and Sensors
- Advanced Memory and Neural Computing
- Organic Electronics and Photovoltaics
- Neuroscience and Neural Engineering
- Gas Sensing Nanomaterials and Sensors
- Diamond and Carbon-based Materials Research
- Advanced Chemical Physics Studies
- Molecular Junctions and Nanostructures
- nanoparticles nucleation surface interactions
- Semiconductor materials and devices
- Advanced Sensor and Energy Harvesting Materials
- Photoreceptor and optogenetics research
- Fullerene Chemistry and Applications
- Quantum, superfluid, helium dynamics
- Electrochemical sensors and biosensors
- Spectroscopy and Laser Applications
- Advanced Chemical Sensor Technologies
- Thin-Film Transistor Technologies
- ZnO doping and properties
- Metal and Thin Film Mechanics
- Porphyrin and Phthalocyanine Chemistry
- Nanowire Synthesis and Applications
- Ion-surface interactions and analysis
- Quantum Dots Synthesis And Properties
Institute of Materials for Electronics and Magnetism
2014-2023
National Research Council
2003-2022
Fondazione Bruno Kessler
2016
University of Parma
2015-2016
Clemson University
2016
Seoul National University
2016
National Institute of Advanced Industrial Science and Technology
2016
Colorado State University
2016
University of Portsmouth
2016
Universidad del Noreste
2016
Pentacene stands out as a model molecule among organic semiconductors due to its ability form well-ordered films that show high field effect mobility. We discuss the processes involved in pentacene film growth, emphasizing differences with respect inorganic films. The influence of growth parameters such substrate nature and temperature, deposition rate, kinetic energy molecular beam on structure morphology are discussed. Finally, we overview recent attempts nucleation draw attention role...
Organic electrochemical transistors (OECTs) are attracting a great deal of interest for biosensing and bioelectronics applications. However, their device physics is not yet well-understood. In this paper, we focus on the effect gate electrode material response OECTs. We studied OECTs made from conducting polymer poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate), which utilized halide electrolytes. demonstrate that Ag electrodes show larger current modulation compared to Pt...
This perspective deals with the coupling of ionic and electronic transport in organic devices, focusing on electrolyte-gated transistors. These include field-effect transistors (EG-OFETs) electrochemical (OECTs). EG-OFETs, based molecules polymers, can be operated at low electrical bias (about 1 V or below) permit unprecedented charge carrier densities within transistor channel. OECTs aqueous environment as efficient ion-to-electron converters, thus providing an interface between worlds...
Selective detection of bioanalytes in physiological fluids, such as blood, sweat or saliva, by means low-cost and non-invasive devices, is crucial importance to improve diagnosis prevention healthcare. To be really useful everyday life a sensing system needs handy, non-invasive, easy read possibly wearable. Only sensor that satisfies these requirements could eligible for applications healthcare condition monitoring. Herein an organic electrochemical transistor has been investigated simple,...
A single natural cotton fiber has been functionalized with poly(3,4-ethylenedioxythiophene) doped poly(styrene sulfonate) (PEDOT:PSS) conductive polymer by a simple soaking process and used as channel of an organic electrochemical transistor (OECT), directly interfaced liquid electrolyte in contact Ag wire gate. The device shows stable reproducible current modulation demonstrated to be very effective for sensing NaCl concentration water. OECT results low cost device, which is attractive...
Memristors are widely considered as promising elements for the efficient implementation of synaptic weights in artificial neural networks (ANNs) since they resistors that keep memory their previous conductive state. Whereas demonstrations simple (e.g., a single-layer perceptron) based on memristors already exist, more complicated is challenging and has yet to be reported. In this study, we demonstrate linearly nonseparable combinational logic classification (XOR task) using network...
Drought stress imposes a major constraint over crop yield and can be expected to grow in importance if the climate change predicted comes about. Improved methods are needed facilitate management via prompt detection of onset stress. Here, we report use an vivo OECT (organic electrochemical transistor) sensor, termed as bioristor, context drought response tomato plant. The device was integrated within plant’s stem, thereby allowing for continuous monitoring physiological status throughout its...
We use a seeded supersonic molecular beam to control the kinetic energy of pentacene (${\mathrm{C}}_{22}{\mathrm{H}}_{14}$) during deposition and growth on Ag(111). Highly ordered thin films are grown at low substrate temperatures ($\ensuremath{\sim}200\text{ }\mathrm{K}$) energies few electron volts, as shown by He diffraction x-ray reflectivity spectra. In contrast, thermal molecules yields only amorphous films. Growth room or higher temperature substrates poorer quality irrespective...
Abstract The in vivo monitoring of key plant physiology parameters will be a enabler precision farming. Here, biomimetic textile-based biosensor, which can inserted directly into tissue is presented: the device able to monitor, and real time, variations solute content sap. biosensor has no detectable effect on plant’s morphology even after six weeks continuous operation. sap electrolyte concentration growing tomato revealed circadian pattern variation. potential detect signs abiotic stress,...
We demonstrate the label-free and selective detection of interleukin-6 (IL-6), a key cell-signaling molecule in biology medicine, by integrating an OECT with immuno-affinity regenerated cellulose membrane. The objective membrane is to increase local concentration IL-6 at sensing electrode and, thereby, enhance device response for concentrations falling within physiological range cytokines. gate functionalized oligo(ethylene glycol)-terminated self-assembled alkanethiolate monolayer (SAM)...
Abstract Functional coupling live neurons through artificial synapses is the primary requirement for their implementation as prosthetic devices or in building hybrid networks. Here, first evidence of unidirectional, activity dependent, two brain slices via organic memristive (OMD) demonstrated. ODM a polymeric electrochemical element, which has terminals connection electrical circuits and displays hysteresis rectifying features. OMD characterized by nonlinear relationships determined...
The development of innovative nanosystems opens new perspectives for multidisciplinary applications at the frontier between materials science and nanomedicine. Here we present a novel hybrid nanosystem based on cytocompatible inorganic SiC/SiOx core/shell nanowires conjugated via click-chemistry procedures with an organic photosensitizer, tetracarboxyphenyl porphyrin derivative. We show that this is efficient source singlet oxygen cell oxidative stress when irradiated 6 MV X-Rays low doses...
A hybrid bio-organic electrochemical transistor based on the<italic>Physarum polycephalum</italic>cell, showing a multifunctional operation (transistor and memristive-like response), has been demonstrated.
We investigate and optimize the Aerosol Jet Printing of PEDOT:PSS by studying role parameters determining final quality printed features. thin films organic materials requires a high control in deposition process to morphology/structure that determine electrical functional performance devices. studied aerosol jet lines semiconductive polymer on flexible Kapton substrates. choose focus ratio, defined as ratio between sheath carrier gas flow rates, main parameter best characterizes hence...
Abstract Rapid Prototyping (RP) promises to induce a revolutionary impact on how the objects can be produced and used in industrial manufacturing as well everyday life. Over time standard technique 3D Stereolithography (SL) has become fundamental technology for RP Additive Manufacturing (AM), since it enables fabrication of from cost-effective photocurable resin. Efforts obtain devices more complex than just mere aesthetic simulacre, have been spent with uncertain results. The...
The design of electrodes based on conductive polymers in brain-machine interface technology offers the opportunity to exploit variably manufactured materials reduce gliosis, indeed most common brain response chronically implanted neural electrodes. In fact, use polymers, finely tailored their physical-chemical properties, might result with improved adaptability tissue and increased charge-transfer efficiency. Here we interfaced poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)...