A5068076124- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Advanced Photocatalysis Techniques
- Advanced Nanomaterials in Catalysis
- TiO2 Photocatalysis and Solar Cells
- Metalloenzymes and iron-sulfur proteins
- Luminescence Properties of Advanced Materials
- Metal-Organic Frameworks: Synthesis and Applications
- Electrocatalysts for Energy Conversion
- Catalytic Processes in Materials Science
- Surface Modification and Superhydrophobicity
- Metal complexes synthesis and properties
- Covalent Organic Framework Applications
- Adsorption and biosorption for pollutant removal
- Copper-based nanomaterials and applications
- Advancements in Battery Materials
- Advanced ceramic materials synthesis
- Gas Sensing Nanomaterials and Sensors
- Hydrogen Storage and Materials
- Mesoporous Materials and Catalysis
- Advanced Sensor and Energy Harvesting Materials
- Nanocluster Synthesis and Applications
- Aerogels and thermal insulation
- Supercapacitor Materials and Fabrication
- Solid-state spectroscopy and crystallography
Yunnan University
2015-2024
Liaoning Shihua University
2016-2024
Chinese PLA General Hospital
2024
Huaqiao University
2021-2024
Sichuan Agricultural University
2019-2024
Science and Technology Department of Sichuan Province
2024
Ministry of Education of the People's Republic of China
2015-2024
The Affiliated Yongchuan Hospital of Chongqing Medical University
2024
Chongqing Medical University
2024
Hebei Agricultural University
2024
The rhodamine B dye was used to sensitize a Pt@UiO-66(Zr) metal–organic framework for visible-light driven photocatalytic hydrogen production from triethanolamine aqueous solution.
We demonstrated that embedding of CdS on MOFs could significantly increase the photocatalytic efficiency for visible light-driven hydrogen production.
Through in situ nucleation and growth of α-MnO2 nanorods on graphene nanosheets (GNs), a nanorod/GN hybrid was synthesized employed as the catalyst for non-aqueous lithium oxygen (Li–O2) batteries. The α-MnO2/GN showed excellent catalytic property. It demonstrated that performance ORR OER not only associated with morphology size particles but also their combination graphene. developed synthetic strategy can be applied to prepare analogous MOx/GN hybrids used Li–O2 batteries other energy...
Soybean [Glycine max (L.) Merr.] stalk-based biochar was prepared using oxygen-limited pyrolysis. We evaluated phenanthrene (PHE) and Hg(II) sorption, from single binary component solutions, onto biochar. found that the efficiently removed PHE aqueous solutions. The isotherms for sorption could be described linear Tóth models, respectively, both with high regression coefficients (R(2) > 0.995). When coexisted in an solution, we observed direct competitive each one suppressing another. Our...
The free-standing CuO<sub>x</sub>–Co<sub>3</sub>O<sub>4</sub>@PNCNF anode delivers high specific capacity, rate capability, and cycling performance for lithium-ion batteries.
As the [2Fe]H subsite models of [FeFe]-hydrogenases, a series PNP-chelated and -bridged diiron dithiolate complexes 1a–f 2a–f together with three related monophosphine 3a–c were prepared by selective substitutions all-carbonyl complex Fe2(μ-pdt)(CO)6 (A, pdt = SCH2CH2CH2S) aminodiphosphines (Ph2P)2NR (denoted as PNP) under different reaction conditions. The first UV irradiation toluene solutions A PNP ligands (PNP (Ph2P)2NR; R (CH2)3Me, (CH2)3NMe2, (CH2)3Si(OEt)3, C6H5, C6H4OMe-p,...
As a further exploration of the asymmetrically substituted diiron models for active site [FeFe]-hydrogenases, two new types small bite-angle aminodiphosphine [(Ph2P)2NR; denoted as PNP in this study]-chelated N-phenyl-aza- and ethanedithioate complexes Fe2(μ-xdt)(CO)4{κ2-(Ph2P)2NR} (1a–1e) (2a–2e), respectively, were successfully synthesized by carbonyl substitution reactions all-carbonyl Fe2(μ-xdt)(CO)6 (xdt = SCH2N(Ph)CH2S (adtNPh) SCH2CH2S (edt)) with (PNP (Ph2P)2NR, R CMe3, CH2CHMe2,...
Solar-driven photocatalytic H 2 O production with water and is an environmentally friendly process for producing , important chemical.
Abstract Accurate identifying and in‐depth understanding of the defect sites in a working nanomaterial could hinge on establishing specific defect‐activity relationships. Yet, atomically precise coinage‐metal nanoclusters (NCs) possessing surface vacancy defects are scarce primarily owing to challenges synthesis isolation such defective NCs. Herein we report mixed‐ligand strategy synthesizing an intrinsically chiral metal‐deficient copper hydride‐rich NC [Cu 57 H 20 (PET) 36 (TPP) 4 ] + ( Cu...
The construction of efficient enzyme mimetics for the hydrolysis peptide bonds in proteins is challenging due to high stability and importance proteases biology industry. Metal-organic frameworks (MOFs) consisting infinite crystalline lattices with metal clusters organic linkers may provide opportunities protease mimic which has remained unknown. Herein, we report that Cu2(C9H3O6)4/3 MOF (which well known as HKUST-1 denoted Cu-MOF here), possesses an intrinsic mimicking activity similar...
Diiron dithiolate complexes have received special attention because of their structural similarity to the active site [FeFe]-hydrogenases, which are most efficient and fastest catalysts for generation dihydrogen in nature. Recently, we established a novel way prepare phosphine-substituted diiron aza- oxadithiolate complexes. Reaction Fe2(μ-SCH2OH)2(CO)6 several phosphine ligands L (L = PPh3, PPh2(2-C5H4N), P(C6H4-4-CH3)3) affords intermediate Fe2(μ-SCH2OH)2(CO)5L, while situ reacts with...
Abstract Though metal-organic frameworks (MOFs) have inspired potential applications in biomedicine, cytotoxicity studies of MOFs been relatively rare. Here we demonstrate for the first time that an easily available MOF, Fe-MIL-101, possesses intrinsic activity against human SKOV3 ovarian cancer cells and suppress proliferation (IC 50 = 23.6 μg mL −1 ) normal mouse embryonic fibroblasts (BABL-3T3, IC 78.3 cells. It was more effective than typical anticancer drugs such as artesunate (ART,...
The MoS<sub>2</sub>–SnO<sub>2</sub> heterostructures are encapsulated into carbon nanofibers <italic>via</italic> a simple and scalable process. binder-free robust structure exhibit high reversible capacity, long-term cycling stability, excellent rate capability.
Photocatalytic hydrogen peroxide (H 2 O ) production from water and has received considerable attention.
ZnIn2S4, a novel two-dimensional visible light-responsive photocatalyst, has attracted much attention in the photocatalytic evolution of H2 under light irradiation due to its attractive intrinsic photoelectric properties and geometric configuration. However, ZnIn2S4 still severe charge recombination, which results moderate performance. Herein, we report successful synthesis 2D/2D ZnIn2S4/Ti3C2 nanocomposites by facile one-step hydrothermal method. The efficiency hydrogen was also evaluated...
We take advantage of the folic acid conjugated iron-based metal–organic frameworks (Fe-MIL-101) without any surface modification to design a simple and sensitive colorimetric assay detect cancer cells based on its intrinsic peroxidase-like activity over broad pH range.
Maggots (larvae of Lucilia sericata) have shown therapeutic effects on refractory wounds infected with bacteria, yet the bacterial killing mechanisms are unclear. Herein, we report isolation and purification an antibacterial protein from maggots (MAMP). MAMP demonstrated inhibitory activity against both standard strains clinically isolated antibiotic-resistant Staphylococcus aureus in vitro. The topical use effectively decreased viability S. promoted wound healing mouse skin infection model....