A5003163965- Crystallization and Solubility Studies
- X-ray Diffraction in Crystallography
- Catalytic C–H Functionalization Methods
- Asymmetric Hydrogenation and Catalysis
- Crystallography and molecular interactions
- Axial and Atropisomeric Chirality Synthesis
- Cyclopropane Reaction Mechanisms
- Asymmetric Synthesis and Catalysis
- Catalytic Cross-Coupling Reactions
- Chemical Synthesis and Analysis
- Chemical Reactions and Isotopes
- Fluorine in Organic Chemistry
- Synthesis and Catalytic Reactions
- Organometallic Complex Synthesis and Catalysis
Robert Bosch (Germany)
2021
Micron (United States)
2021
Micron Biomedical (United States)
2021
Harm Reduction Services
2021
École Polytechnique Fédérale de Lausanne
2017-2020
Charles Humbert 8
2017-2018
Mild complexations of chiral cyclopentadienes with rhodium(<sc>i</sc>) and iridium(<sc>i</sc>) precursors enable user-friendly <italic>in situ</italic> complex formation for catalytic applications.
Abstract The creation of new chiral ligands capable providing high stereocontrol in metal‐catalyzed reactions is crucial modern organic synthesis. production bioactive molecules as single enantiomers increasingly required, and asymmetric catalysis with metal complexes constitutes one the most efficient synthetic strategies to access optically active compounds. Herein we offer a historical overview on development derivatives ubiquitous cyclopentadienyl ligand (Cp X ), detail their successful...
Stable pre-ligands and common metal salts provide,<italic>via</italic>β-carbon elimination, access to Cp-metal complexes suitable for<italic>in situ</italic>catalyst preparation.
A Cp*Rh(III)-catalyzed C–H/C–C bond activation sequence of cyclopropyl hydroxamates has been developed. The three-component process allows trapping the intermediate rhodacycle with diazomalonates and an alcohol nucleophile to provide access synthetically valuable α-alkoxylated γ-lactams trans diastereoselectivity.
CycloparaphenylenesIn their Communication on page 13529, Michal Juríc ˇek et al. describe a neutral open-shell carbon nanoring and show that its reactivity is result of steric electronic effects the cycloparaphenylene framework.