A5100773400- X-ray Diffraction in Crystallography
- Crystallization and Solubility Studies
- Advanced Battery Materials and Technologies
- Advancements in Battery Materials
- Advanced battery technologies research
- Metal-Organic Frameworks: Synthesis and Applications
- Conducting polymers and applications
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
- Advanced Battery Technologies Research
- Covalent Organic Framework Applications
- Mycotoxins in Agriculture and Food
- Organic and Molecular Conductors Research
- Solar Thermal and Photovoltaic Systems
- Particle Accelerators and Free-Electron Lasers
- Particle accelerators and beam dynamics
- Solar-Powered Water Purification Methods
- Genetic and phenotypic traits in livestock
- Statistical Methods and Inference
- Plant Pathogens and Fungal Diseases
- Nuclear reactor physics and engineering
- Robotic Path Planning Algorithms
- Power Systems and Renewable Energy
- Superconducting Materials and Applications
- Genetic Associations and Epidemiology
Affiliated Hospital of Qingdao University
2025
Qingdao University
2025
University of South China
2025
Huazhong University of Science and Technology
2018-2024
Institute of Advanced Manufacturing Technology
2023-2024
Wuhan National Laboratory for Optoelectronics
2020-2024
Zhengzhou University
2022-2024
Wenzhou University
2023-2024
Wuhan Institute of Technology
2023-2024
Kunming Medical University
2022-2024
Abstract Aqueous zinc‐ion batteries (ZIBs) are promising for next‐generation energy storage. However, the reported electrode materials ZIBs facing shortcomings including low capacity and unsatisfactory cycling stability etc. Herein, hexaazatrinaphthalene‐quione (HATNQ) is aqueous ZIBs. The HATNQ electrodes delivered an ultrahigh (482.5 mAh g −1 at 0.2 A ) outstanding cyclability of >10 000 cycles 5 . sets a new record organic cathodes in high performances ascribed to rich C=O C=N groups...
Abstract The performance of Li anodes is extremely affected by the solvation ions, leading to preferential reduction sheath and subsequent formation fragile solid–electrolyte interphase (SEI), dendrites, low coulombic efficiency (CE). Herein, we propose a novel strategy regulate sheath, through introduction intermolecular hydrogen bonds with both anions salt solvent small amount additives. addition such reduced LUMO energy level in electrolyte, promoted robust SEI, free molecules, enhanced...
Redox organic electrode materials (OEMs) have attracted extensive attention for batteries due to the possibility be designed with high performance. However, practical application of OEMs requires rigor criteria such as low cost, recyclability, scalability and performance etc. hence seems still far away. Here, we demonstrate an OEM aqueous batteries. Quantification charge storage confirmed protons fast reaction kinetics, thereby enabling at mass loading. As a result, laminated pouch cells...
Conjugated coordination polymers (CCPs), which possess long-range planar π-d conjugation, are fascinating for various applications because they inherit the merits of both metal-organic frameworks (MOFs) and conducting polymers. However, only one-dimensional (1D) two-dimensional (2D) CCPs have been reported so far. The synthesis three-dimensional (3D) is challenging even seems theoretically infeasible conjugation implies 1D or 2D structure. Besides, redox activity conjugated ligands makes...
Abstract The heavy reliance of lithium-ion batteries (LIBs) has caused rising concerns on the sustainability lithium and transition metal ethic issue around mining practice. Developing alternative energy storage technologies beyond become a prominent slice global research portfolio. play vital role in shaping future landscape storage, from electrified mobility to efficient utilization renewable energies further large-scale stationary storage. Potassium-ion (PIBs) are promising given its...
Three iridium(III)-based metal–organic frameworks (MOFs), namely [Cd3{Ir(ppy-COO)3}2(DMF)2(H2O)4]·6H2O·2DMF (1), [Cd3{Ir(ppy-COO)3}2(DMA)2(H2O)2]·0.5H2O·2DMA (2), and [Cd3{Ir(ppy-COO)3}2(DEF)2(H2O)2]·8H2O·2DEF (3) (ppy-COOH = methyl-3-(pyridin-2-yl)benzoic acid, DMF N,N-dimethylformamide, DMA N,N-dimethylacetamide, DEF N,N-diethylformamide), have been synthesized characterized. Single-crystal structural determinations reveal that compounds 1–3 are isostructural, showing a three-dimensional...
Abstract In search of magneto‐optic materials, the mononuclear compounds Ln III (depma)(NO 3 ) (hmpa) 2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss crystallinity. Dy compound switches from a single‐ion to single‐molecule magnet with doubling spin reversal barrier energy and yellow‐green blue‐white emission. is reversed by heating 100 °C or partially on light irradiating 254 nm. results suggest that lanthanide...
Organic electrode materials have exhibited good electrochemical performance in batteries, but their voltages and rate capabilities still require improvement to meet the increasing demand for batteries with high energy power density. Herein, we design synthesize a branched dihydrophenazine-based polymer (p-TPPZ) as cathode material dual-ion (DIBs) through delicate molecular design. Compared linear (p-DPPZ, theoretical capacity of 209 mAh g–1), p-TPPZ possessed higher 233 g–1 lower highest...
The structural designability of organic electrode materials makes them attractive for symmetric all-organic batteries (SAOBs) by virtue different plateaus. However, quite a few works have reported and it is still challenging to develop high-performance material SAOBs. Herein, small molecule, 2,3,7,8-tetraaminophenazine-1,4,6,9-tetraone (TAPT), rich C=O C=N groups ensure the high capacity at both plateaus C=O/C-O C=N/C-N redox reactions, which are hence utilized as cathodic anodic active...
Organic electrode materials have attracted a lot interest in batteries recent years. However, most of them still suffer from low performance such as potential, slow reaction kinetics, and short cycle life. In this work, we report strategy fabricating donor-acceptor (D-A) conjugated polymers for facilitating the charge transfer therefore accelerating kinetics by using copolymer (p-TTPZ) dihydrophenazine (PZ) thianthrene (TT) proof-of-concept. The D-A polymer p-type cathode could store anions...
Abstract Aqueous zinc‐ion batteries (ZIBs) have attracted extensive interest for the next‐generation batteries, which, however, are facing great challenges due to poor reversibility of zinc (Zn) anodes and side reactions water decomposition. Herein, we demonstrated a strategy that solvation sheath Zn ions could be facilely regulated by supramolecular coordination chemistry adding small amounts cyclodextrins (CDs) and, hence, inhibited products, widened electrochemical window, facilitated...
Abstract Aqueous Zn‐ion batteries (AZIBs) are considered as promising candidates for the next‐generation large‐scale energy storage, which, however, is facing challenge of instable Zn anodes. The anion pivotal in stability anodes, which not being paid enough attention to. Herein, modulation anions reported using Hofmeister series supramolecular chemistry to boost It found that right‐side (e.g., OTf − ) can enhance 2+ transference number, increase Coulombic efficiency, facilitate uniform...
Abstract Organic electrodes have gained great interest for batteries. Conducting polymers the merits of high conductivity, and hence are attempted as electrode materials in batteries soon their discoveries. However, conducting showe poor electrochemical performance baring vague charge storage mechanisms. Here, a strategy is reported to reveal mechanisms by constructing isomers using polypyridines proof‐of‐concept. Polypyridines rarely studied its redox activity still not clear. The results...
Triple-negative breast cancer (TNBC) is a highly aggressive subtype of characterized by an extremely poor prognosis. Photoimmunotherapy has emerged as promising strategy for the treatment TNBC. This approach works selectively destroying tumor cells, releasing tumor-associated antigens, activating immune system, and effectively inhibiting proliferation metastasis. However, majority current phototheranostic approaches are hindered limited tissue penetration in first near-infrared (NIR-I)...
Histone acetyltransferases (HATs) help regulate fungal development and the production of secondary metabolites. In this study, we determined that HAT AflGcnE influenced morphogenesis aflatoxin biosynthesis in Aspergillus flavus. We observed localized to nucleus cytoplasm during conidial germination stages, while it was located mainly hyphal stage. Deletion AflgcnE inhibited growth A. flavus decreased hydrophobicity cell surface. The ΔAflgcnE mutant exhibited a lack asexual sporulation unable...
Conjugated coordination polymers (CCPs) with extended π-d conjugation, which can effectively promote long-range delocalization of electrons and enhance conductivity, are superior to traditional metal-organic frameworks (MOFs) attracted great attention for potential applications in chemical sensors, electronics, energy conversion/storage devices, etc. However, the precise construction CCPs is still challenging due complex uncontrollable reactions CCPs. Herein, two different framework...
Abstract Aqueous zinc‐ion batteries (ZIBs) are promising for next‐generation energy storage. However, the reported electrode materials ZIBs facing shortcomings including low capacity and unsatisfactory cycling stability etc. Herein, hexaazatrinaphthalene‐quione (HATNQ) is aqueous ZIBs. The HATNQ electrodes delivered an ultrahigh (482.5 mAh g −1 at 0.2 A ) outstanding cyclability of >10 000 cycles 5 . sets a new record organic cathodes in high performances ascribed to rich C=O C=N groups...
Abstract Organic electrode materials have attracted tremendous attention for potassium‐ion batteries (PIBs). Whereas, high‐performance anodes are scarcely reported. Herein, a novel hexaazatriphenylene potassium carboxylate (HAT‐COOK) is proposed as anode PIBs. The rich CN/CO bonds guarantee the high theoretical capacity. It also demonstrated HAT‐COOK more compatible with water‐soluble binders than hydrophobic fluoride binders, forming homogenous film, maintaining structural integrity, and...
Abstract Artificial control and engineering of metal–organic framework (MOF) crystals with defects can endow them suitable properties for applications in gas storage, separation, catalysis. A series defective iridium‐containing MOFs, [Zn 4 (μ ‐O)(Ir‐A) 2(1− x ) (Ir‐B) 2 ] (ZnIr‐MOF‐d ), were synthesized by doping heterostructured linker Ir‐BH 3 into the parent (ZnIr‐MOF), which Ir‐AH represents [Ir(ppy‐COOH) (ppyCOOH=3‐(pyridin‐2‐yl)benzoic acid) is (2‐pyPO H)] H =2‐pyridylphosphonic acid)....