A5101646754- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Organic Light-Emitting Diodes Research
- Asymmetric Hydrogenation and Catalysis
- Metal-Organic Frameworks: Synthesis and Applications
- Lanthanide and Transition Metal Complexes
- Cancer Immunotherapy and Biomarkers
- Porphyrin and Phthalocyanine Chemistry
- Organometallic Complex Synthesis and Catalysis
- Molecular Sensors and Ion Detection
- Domain Adaptation and Few-Shot Learning
- Nanomaterials for catalytic reactions
- Video Analysis and Summarization
- Face recognition and analysis
- Synthesis and Biological Evaluation
- Semiconductor materials and devices
- Crystal structures of chemical compounds
- Immunotherapy and Immune Responses
- Electrocatalysts for Energy Conversion
- Ear and Head Tumors
- Magnetic properties of thin films
- Luminescence and Fluorescent Materials
- Soft tissue tumors and treatment
- Monoclonal and Polyclonal Antibodies Research
- Curcumin's Biomedical Applications
Huazhong University of Science and Technology
2009-2025
Tongji Hospital
2023-2025
Zhejiang Lab
2024
Second Affiliated Hospital & Yuying Children's Hospital of Wenzhou Medical University
2024
Wenzhou Medical University
2023-2024
Ezhou Central Hospital
2024
Nanjing University
2023
Collaborative Innovation Center of Advanced Microstructures
2023
Energy Research Institute
2023
Shanghai Harbour Engineering Design & Research Institute
2019-2022
This review critically evaluates advancements in multifunctional hydrogels, particularly focusing on their applications osteoarthritis (OA) therapy. As research evolves from traditional natural materials, there is a significant shift towards synthetic and composite known for superior mechanical properties enhanced biodegradability. spotlights novel such as injectable microneedle technology, responsive which have revolutionized OA treatment through targeted efficient therapeutic delivery....
Abstract Polynuclear copper( I ) complexes with bridging bis(dicyclohexylphosphino)methane (dcpm) and iodide ligands, [Cu 2 (CH 3 CN) ](BF 4 ( 1 ), [(CuI) ] 5 were prepared their structures determined by X‐ray crystal analysis. The shortest CuCu distance found in these is 2.475(1) Å for . Powdered samples of , display intense long‐lived phosphorescence λ max at 460, 626, 590, 456 nm emission quantum yields 0.26, 0.11, 0.12, 0.56 room temperature, respectively. In the solid state, displays...
The first bis(BF2) core complex containing a 1,8-naphthyridin derivative (1,2-bis(5,7-dimethyl-1,8-naphthyridin-2-yl)hydrazine) and with yellow-green emission as well high quantum yield was synthesized structurally characterized, the compound exhibits two-photon absorption excited fluorescence properties.
The structure-activity relationship (SAR) between toxicity and the types of linking ketones C7 bridged monocarbonyl curcumin analogs (MCAs) was not clear yet. In pursuit effective less cytotoxic chemotherapeutics, we conducted a SAR analysis using various diketene skeletons C7-bridged MCAs, synthesized cyclic MCAs containing identified low-toxicity cyclopentanone scaffold an o-methoxy phenyl group, assessed their anti-gastric cancer activity safety profile. Most compounds exhibited potent...
Osteoarthritis is a chronic degenerative joint disease marked by chondrocyte senescence and extracellular matrix degradation. Vaccarin, flavonoid with anti-inflammatory antioxidant properties, has not been previously investigated for its therapeutic potential in osteoarthritis. To evaluate the of Vaccarin osteoarthritis elucidate underlying mechanisms. This study utilized vitro cultures RNA sequencing to identify relevant pathways, followed validation at genetic, protein, metabolic levels...
Given labeled data in a source domain, unsupervised domain adaptation has been widely adopted to generalize models for unlabeled target whose distributions are different. However, existing works inapplicable face recognition under privacy constraints because they re-quire sharing of sensitive images between domains. To address this problem, we propose federated do-main recognition, FedFR. FedFR jointly optimizes clustering-based and learning elevate performance on the domain. Specif-ically,...
Abstract The selective hydrogenation of nitrile groups to primary amines is challenging owing their high ability produce secondary and tertiary amines. Herein, we report an efficient system for the nitro catalyzed by Ni 2 P nanoparticles in aqueous H 3 NBH solution under ambient conditions. exhibits catalytic selectivity toward generating amines, resulting good isolated yields. A combination experiments theoretical calculations shows that composite interactions among species on catalyst...
Condensation of Ph2PH and paraformaldehyde with 2-amino-7-methyl-1,8-naphthyridine gave the new flexible tridentate ligand 2-[N-(diphenylphosphino)methyl]amino-7-methyl-1,8-naphthyridine (L). Reaction L [Cu(CH3CN)4]BF4 and/or different ancillary ligands in dichloromethane afforded N,P chelating or bridging luminescent complexes [(L)2Cu2](BF4)2, [(μ-L)2Cu2(PPh3)2](BF4)2 [(L)Cu(CNN)]BF4 (CNN = 6-phenyl-2,2′-bipyridine), respectively. Complexes [(L)2Pt]Cl2, [(L)2Pt](ClO4)2 [(L)Pt(CNC)]Cl (CNC...
Intensely luminescent 1,8-naphthyridine-BF2 complexes 1-9 containing terminal bidentate N^N^O and/or N^C^O groups are synthesized and structurally characterized by X-ray diffraction, electrospray ionization mass spectrometry, (1)H (19)F NMR spectroscopy elemental analysis. Complexes 1-4 from 2-acetamino-1,8-naphthyridine derivatives a facile route. Selective bonding modes the chemical stability of 5 6 obtained reacting BF3·Et2O with 1,8-naphthyridine bearing dual-functional (N^C^O N^N^O)...
A series of platinum(II) complexes bearing a chromophore–acceptor dyad obtained by reacting 4-(p-bromomethylphenyl)-6-phenyl-2,2′-bipyridine or 4′-(p-bromomethylphenyl)-2,2′:6′,2′′-terpyridine with pyridine, 4-phenylpyridine, 4,4′-bipyridine, 1-methyl-4-(pyridin-4′-yl)pyridinium hexafluorophosphate respectively, were synthesized. Their photophysical properties, emission quenching studies Pt nanoparticles and methyl viologen, electrochemical properties photoinduced electron-transfer reactions...
The Neural Calcium Sensor1 (NCS1) is a crucial protein that binds to Ca2+ and believed play role in regulating tumor invasion cell proliferation. However, the of NCS1 immune infiltration cancer prognosis still unknown. Our study aimed explore expression profile, pattern, prognostic value, biological function, potential compounds targeting using public databases. High was detected by histochemical staining LIHC (Liver hepatocellular carcinoma), BRCA (Breast invasive KIRC (Kidney renal clear...
A series of 1,8-naphthyridine derivatives containing vinyl, 2-(2-acetylamino-pyridine-6-ethylene)-4-methyl-7-acetylamino-1,8-naphthyridine (L1), 2-(2-acetylamino-pyridine-6-ethylene)-1,8-naphthyridine (L2), 2-(2-acetylamino-pyridinyl-6-ethylene)-4-methyl-7-hydroxyl-1,8-naphthyridine (L3), 2-(2-diacetylamino-pyridinyl-3-ethylene)-7-diacetylamino-1,8-naphthyridine (L4), and 7-(2-diacetylamino-pyridinyl-3-ethylene)-4′-acetyl-pyrrolo[1′,5′-a]-1,8-naphthyridine (L5), as well complexes...
The selective one- and two-electron reduction of azo-pyridine azo-1,8-naphthyridine with anionic CH3COO− by the Kolbe reaction has been established for first time, mechanisms are presented.
Two novel facial-capping tris-naphthyridyl compounds, 2-chloro-5-methyl-7-((2,4-dimethyl-1,8-naphthyridin-7(1H)-ylidene)(2,4-dimethyl-1,8-naphthyridin-7-yl))methyl-1,8-naphthyridine (L(1)) and 2-chloro-7-((2-methyl-1,8-naphthyridin-7(1H)-ylidene)(2-methyl-1,8-naphthyridin-7-yl))methyl-1,8-naphthyridine (L(2)), as well their Cu(i) Pb(ii) complexes, [CuL(a)(PPh(3))]BF(4) (1) (PPh(3) = triphenylphosphine, L(a)...